Synthesis of polyfunctionalized dihydro-2-oxypyrroles catalyzed by 1,2,3,5-tetrakis(carbazol-9-yl)-4,6-dicyanobenzene (4CzIPN) as a novel donor-acceptor fluorophore [PDF]
Scientific Reports, 2022 We developed a green radical synthesis method for polyfunctionalized dihydro-2-oxypyrroles based on the Michael–Mannich cyclocondensation of amines, dialkyl acetylenedicarboxylates, and formaldehyde.
Farzaneh Mohamadpour
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Gram-scale photosynthesis of polyfunctionalized dihydro-2-oxypyrroles using 3DPAFIPN as a halogenated dicyanobenzene-based photosensitizer via a consecutive visible-light-induced electron transfer process [PDF]
Frontiers in ChemistryBackgroundTypically, organic dyes show lower excited state lifetimes, a key hindrance in the development of efficient photoredox processes. Due to their distinctive qualities and efficiency, a particular class of organic chromophores has drawn ...
Farzaneh Mohamadpour, Ali Mohammad Amani
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A Modular Biosensor Platform for the Detection of Plastic Monomers and the Engineering of Promiscuous Amidases Toward Challenging Substrates [PDF]
Advanced ScienceStable chemical bonds dictate the properties of industrial chemicals and materials. Particularly the persistence of synthetic polymers like polyurethanes (PUs) contributes to the global issues of waste accumulation and environmental pollution.
Ina Somvilla +12 more
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Efficient synthesis of polyfunctionalized carbazoles and pyrrolo[3,4-c]carbazoles via domino Diels–Alder reaction [PDF]
Beilstein Journal of Organic Chemistry, 2021 The p-TsOH-catalyzed Diels–Alder reaction of 3-(indol-3-yl)maleimides with chalcone in toluene at 60 °C afforded two diastereoisomers of tetrahydropyrrolo[3,4-c]carbazoles, which can be dehydrogenated by DDQ oxidation in acetonitrile at room temperature ...
Ren-Jie Fang +4 more
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Easy Access to Polyfunctionalized Chiral Decalins [PDF]
ACS Omega, 2020 An unexpected ring expansion that converts hydrindanes into decalins via an unprecedented dyotropic reaction involving a mesylate group has been observed, and this paved the way for easy access to polyfunctionalized chiral decalins. These polyfunctionalized chiral decalins can be very useful building blocks for the synthesis of the thia analogues of ...
Hugo Santalla +4 more
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Antioxidants, 2022 Nowadays, most stroke patients are treated exclusively with recombinant tissue plasminogen activator, a drug with serious side effects and limited therapeutic window. For this reason, and because of the known effects of oxidative stress on stroke, a more
Daniel Diez-Iriepa +8 more
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Anomeric Amides: Valuable Reagents in Synthetic Organic Chemistry. [PDF]
Angew Chem Int Ed EnglEnabling late‐stage transformations and skeletal editing, anomeric amides have recently emerged as powerful synthetic tools. Due to their unique properties, anomeric amides have been employed in reactions ranging from amination to halogenation. This minireview provides an overview of recent progress in using anomeric amides across a variety of ...
Garg A, Vigier J, Lebel H, Besset T.
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Synthesis of Polyfunctionalized 4H-Pyrans [PDF]
Journal of Chemistry, 2013 Amberlyst A21 catalyzed one-pot three-component coupling of aldehyde and malononitrile with active methylene compounds such as acetylacetone and ethyl acetoacetate for the synthesis of pharmaceutically important polyfunctionalized 4H-pyrans has been ...
Manisha Bihani +2 more
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Direct Access to Acylboranes via Formal Condensation of Carboxylic Acids with Ligated Boranes. [PDF]
Angew Chem Int Ed EnglA nickel‐catalyzed, radical‐based C(acyl)–B cross‐coupling strategy has been developed for the efficient synthesis of bench‐stable, phosphonite‐ligated acylborane compounds from readily available carboxylic acids. This methodology not only provides access to acylboranes with diverse reactivity profiles but also establishes a versatile platform for the ...
Cai CY +5 more
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Selective, Oxygen-Tunable, and Metal-Free Functionalization of Polyethylene Through Dual-Mode Nitrosation and Carbonylation. [PDF]
Angew Chem Int Ed EnglA metal‐free nitrosation process enables direct C–H functionalization of polyethylene (PE) with high selectivity, producing either oxime‐ or carbonyl‐functionalized polymers. Using t‐BuONO under visible light or thermal conditions, the process operates in both lab‐scale and industrial settings.
Cluzeau L +4 more
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