Results 61 to 70 of about 888 (170)

Cycloaddition reactions of conjugated azoalkenes [PDF]

open access: yes, 2012
An overview of the use of 2H-azirines, conjugated nitrosoalkenes and conjugated azoalkenes bearing phosphorus substituents in addition and cycloaddition reactions is presented, focused on strategies for the synthesis of aminophosphonate and ...
Lemos, A.
core  

Thermal and Photoinduced Radical Cascade Annulation using Aryl Isonitriles: An Approach to Quinoline‐Derived Benzophosphole Oxides

open access: yesAngewandte Chemie International Edition, Volume 63, Issue 30, July 22, 2024.
The synthesis of quinoline‐based benzophosphole oxides from ortho‐alkynylated aromatic phosphine oxides and aryl isonitriles is presented. These π‐extended benzophosphole oxides exhibit interesting photophysical and electrochemical properties. Abstract Herein, we present a radical cascade addition cyclization sequence to access quinoline‐based ...
Shyam Kumar Banjare   +6 more
wiley   +1 more source

Photoassisted Synthesis of Enantiopure Alkaloid Mimics Possessing Unprecedented Polyheterocyclic Cores [PDF]

open access: yesJournal of the American Chemical Society, 2013
Enantiopure alkaloid mimics are synthesized via high yielding intramolecular cycloadditions of photogenerated azaxylylenes tethered to pyrroles, with further growth of molecular complexity via post-photochemical transformations of primary photoproducts.
N N Bhuvan, Kumar   +2 more
openaire   +2 more sources

Pd(II)-Catalyzed [4 + 2] Heterocyclization Sequence for Polyheterocycle Generation [PDF]

open access: yesOrganic Letters, 2018
A new Pd(II)-catalyzed cascade sequence for the formation of polyheterocycles, from simple starting materials, is reported. The sequence is applicable to both indole and pyrrole substrates, and a range of substituents are tolerated. The reaction is thought to proceed by a Pd(II)-catalyzed C-H activated Heck reaction followed by a second Pd(II ...
Elizabeth L. Glaisyer   +2 more
openaire   +4 more sources

Enhancing the Photocatalytic Activity via Direct Covalent Functionalization in Single‐Walled Carbon Nanotubes

open access: yesAdvanced Functional Materials, Volume 34, Issue 14, April 3, 2024.
The control on the direct functionalization of single‐walled carbon nanotubes with the organophotocatalyst PTH allowed the creation of hybrid materials with enhanced charge transfer properties able to overcome homogeneous counterparts in the photoreductive debromination of aromatic halides with a robust character toward the stability during operation ...
José Luis Nova‐Fernández   +8 more
wiley   +1 more source

Determination of diffusion coefficients in polypyrrole thin films using a current pulse relaxation method [PDF]

open access: yes
The current pulse E sub oc relaxation method and its application to the determination of diffusion coefficients in electrochemically synthesized polypyrrole thin films is described. Diffusion coefficients for such films in Et4NBF4 and MeCN are determined
Martin, Charles R.   +2 more
core   +1 more source

Visible‐Light‐Driven Cyclizations

open access: yesAdvanced Synthesis &Catalysis, Volume 366, Issue 4, Page 635-697, February 20, 2024.
Abstract In recent years, the interest to develop cyclizations promoted by visible light has been gaining a lot of attention due to its sustainability aspect. In this review, we summarize the most important advances in this period by describing the methods used to generate different ring sizes, while focusing on the mechanistic details of these ...
Emilia Oueis, Mirella Elkadi, Ramon Rios
wiley   +1 more source

Pd-Catalyzed de Novo Assembly of Diversely Substituted Indole-Fused Polyheterocycles [PDF]

open access: yes, 2019
Here we describe a facile, tandem synthetic route for indolo[3,2-c]quinolinones, a class of natural alkaloid analogues of high biological significance. A Ugi four-component reaction with indole-2-carboxylic acid and an aniline followed by a Pd-catalyzed ...
Butera, Roberto   +6 more
core   +1 more source

New secondary batteries utilizing electronically conductive polymer cathodes [PDF]

open access: yes
The objectives are to optimize the transport rates in electronically conductive polypyrrole films by controlling the morphology of the film and to assess the utility of these films as cathodes in a lithium/polypyrrole secondary battery.
Martin, Charles R., White, Ralph E.
core   +1 more source

Ferrocén-szubsztituált heterociklusok és származékaik szintézise, szerkezetigazolása és komplex spektroszkópiai vizsgálata = Synthesis, structure determination and complex spectroscopic study of ferrocene-substituted heterocycles and their derivatives [PDF]

open access: yes, 2007
Új, mono- és poliheterociklusokkal egyszeresen és többszörösen szubsztituált ferrocénszármazékokat állítottunk elő. Szerkezetüket komplex nagyműszeres vizsgálatokkal (IR, MS, röntgendiffrakció, multinukleáris NMR) derítettük fel.
Csámpai, Antal   +4 more
core  

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