Cycloaddition reactions of conjugated azoalkenes [PDF]
An overview of the use of 2H-azirines, conjugated nitrosoalkenes and conjugated azoalkenes bearing phosphorus substituents in addition and cycloaddition reactions is presented, focused on strategies for the synthesis of aminophosphonate and ...
Lemos, A.
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The synthesis of quinoline‐based benzophosphole oxides from ortho‐alkynylated aromatic phosphine oxides and aryl isonitriles is presented. These π‐extended benzophosphole oxides exhibit interesting photophysical and electrochemical properties. Abstract Herein, we present a radical cascade addition cyclization sequence to access quinoline‐based ...
Shyam Kumar Banjare +6 more
wiley +1 more source
Photoassisted Synthesis of Enantiopure Alkaloid Mimics Possessing Unprecedented Polyheterocyclic Cores [PDF]
Enantiopure alkaloid mimics are synthesized via high yielding intramolecular cycloadditions of photogenerated azaxylylenes tethered to pyrroles, with further growth of molecular complexity via post-photochemical transformations of primary photoproducts.
N N Bhuvan, Kumar +2 more
openaire +2 more sources
Pd(II)-Catalyzed [4 + 2] Heterocyclization Sequence for Polyheterocycle Generation [PDF]
A new Pd(II)-catalyzed cascade sequence for the formation of polyheterocycles, from simple starting materials, is reported. The sequence is applicable to both indole and pyrrole substrates, and a range of substituents are tolerated. The reaction is thought to proceed by a Pd(II)-catalyzed C-H activated Heck reaction followed by a second Pd(II ...
Elizabeth L. Glaisyer +2 more
openaire +4 more sources
The control on the direct functionalization of single‐walled carbon nanotubes with the organophotocatalyst PTH allowed the creation of hybrid materials with enhanced charge transfer properties able to overcome homogeneous counterparts in the photoreductive debromination of aromatic halides with a robust character toward the stability during operation ...
José Luis Nova‐Fernández +8 more
wiley +1 more source
Determination of diffusion coefficients in polypyrrole thin films using a current pulse relaxation method [PDF]
The current pulse E sub oc relaxation method and its application to the determination of diffusion coefficients in electrochemically synthesized polypyrrole thin films is described. Diffusion coefficients for such films in Et4NBF4 and MeCN are determined
Martin, Charles R. +2 more
core +1 more source
Visible‐Light‐Driven Cyclizations
Abstract In recent years, the interest to develop cyclizations promoted by visible light has been gaining a lot of attention due to its sustainability aspect. In this review, we summarize the most important advances in this period by describing the methods used to generate different ring sizes, while focusing on the mechanistic details of these ...
Emilia Oueis, Mirella Elkadi, Ramon Rios
wiley +1 more source
Pd-Catalyzed de Novo Assembly of Diversely Substituted Indole-Fused Polyheterocycles [PDF]
Here we describe a facile, tandem synthetic route for indolo[3,2-c]quinolinones, a class of natural alkaloid analogues of high biological significance. A Ugi four-component reaction with indole-2-carboxylic acid and an aniline followed by a Pd-catalyzed ...
Butera, Roberto +6 more
core +1 more source
New secondary batteries utilizing electronically conductive polymer cathodes [PDF]
The objectives are to optimize the transport rates in electronically conductive polypyrrole films by controlling the morphology of the film and to assess the utility of these films as cathodes in a lithium/polypyrrole secondary battery.
Martin, Charles R., White, Ralph E.
core +1 more source
Ferrocén-szubsztituált heterociklusok és származékaik szintézise, szerkezetigazolása és komplex spektroszkópiai vizsgálata = Synthesis, structure determination and complex spectroscopic study of ferrocene-substituted heterocycles and their derivatives [PDF]
Új, mono- és poliheterociklusokkal egyszeresen és többszörösen szubsztituált ferrocénszármazékokat állítottunk elő. Szerkezetüket komplex nagyműszeres vizsgálatokkal (IR, MS, röntgendiffrakció, multinukleáris NMR) derítettük fel.
Csámpai, Antal +4 more
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