Results 61 to 70 of about 6,869 (206)

Ecology and evolution of pyrazines in insects

Biological Reviews, EarlyView.
ABSTRACT Chemical communication is the oldest and most widespread form of signalling among and within organisms. Among the many compounds involved in such communication, pyrazines – nitrogen‐containing heterocyclic molecules – are especially intriguing due to their widespread occurrence across the tree of life, from bacteria and fungi to insects and ...
Zowi Oudendijk, Niklas Wahlberg, Johanna Mappes   +2 more
wiley   +1 more source

Simultaneous detection of 12 pyrazines in Guizhou sauce-flavor Baijiu by SPE-GC-MS/MS [PDF]

Zhongguo niangzao
A method was established for the simultaneous determination of 12 pyrazines in Guizhou sauce-flavor (Jiangxiangxing) Baijiu by solid phase extraction (SPE) pretreatment combined with gas chromatography-tandem mass spectrometry (GC-MS/MS).
YANG Jinchuan, HANG Jialing, BAI Xuemei, ZHANG Jimin
doaj   +1 more source

Versatile Palladium‐Catalyzed C‐H Arylation of Fluoroarenes with 2‐Chloropyridine Derivatives

Chemistry – A European Journal, EarlyView.
Direct C─H arylation of fluoroarenes with 2‐chloropyridines is enabled by a simple Pd/SPhos system in isopropyl acetate. The method uses inexpensive reactants and shows broad scope and high yields. DFT computations explain reactivity and selectivity.
Federico Belnome, Péter P. Fehér, András Stirling, Csongor G. Németh, Tamás Hergert, György M. Keserű, Péter Ábrányi‐Balogh   +6 more
wiley   +1 more source

Pyrazines Attract Catocheilus Thynnine Wasps

Insects, 2014
Five previously identified semiochemicals from the sexually deceptive Western Australian hammer orchid Drakaea livida, all showing electrophysiological activity in gas chromatography–electroantennogram detection (EAD) studies, were tested in field ...
Bjorn Bohman, Rod Peakall
doaj   +1 more source

Synthesis of a π‐Extended Phenazine Diimide Derivative and Characterization of Its Closed‐Shell Reduced States

Chemistry – A European Journal, EarlyView.
In this work, the synthesis and characterization of novel π‐extended phenazine diimides is reported. The derivatives undergo differential reduction to a dihydrophenazine or Meisenheimer form depending on the reaction conditions employed. The outcome of this work highlights the paramount importance of structural design in determining the nature of the ...
Francesco Rigodanza, Beatrice Bartolomei, Ilaria Crea, Paolo Costa, Nicola Demitri, Marcella Bonchio, Maurizio Prato, Jacopo Dosso   +7 more
wiley   +1 more source

Dual Ligand‐Enabled Nondirected C─H Olefination of (Hetero)Arenes for the Synthesis of Clickable Derivatives

Chemistry – A European Journal, EarlyView.
We report an efficient method for late‐stage installation of “clickable” alkyne groups into diverse (hetero)arenes. Using a dual‐ligand palladium catalyst that combines an NASA ligand with an N‐heterocycle, an acrylate unit bearing a terminal alkyne can be introduced via nondirected C─H activation.
Tommaso Braga, Maria Hergert, Manuel van Gemmeren   +2 more
wiley   +1 more source

Changes of pyrazines, physicochemical indicators and microbial community of fermented grains during stacking fermentation of sauce-flavor Baijiu and correlation analysis [PDF]

Zhongguo niangzao
In order to explore the formation rules of pyrazines in fermented grains during the stacking fermentation of sauce-flavor (Jiangxiangxing) Baijiu, the changes in pyrazines, microbial communities and physicochemical indicators in fermented grains during ...
LONG Yafei, RAO Wei, TANG Lin, ZHONG Yuan, DUAN Qijun, LONG Shenggang, WU Baolin, ZHANG Qihang, LI Lihong*
doaj   +1 more source

On the Role of Linker Fluorination in the Adsorption‐Induced Structural Response of CeIV‐Based Metal‐Organic Frameworks

Chemistry – A European Journal, EarlyView.
The effect of the degree of fluorination of the organic linker on the adsorption behavior of MIL‐140A(Ce) is systematically investigated with a combination of experimental techniques. Cooperative adsorption is switched off in less fluorinated frameworks, as a result of reduced steric hindrance around the adsorption sites.
Francesca Nerli, Virginia Guiotto, Francesca Nardelli, Andrea Giovanelli, Linda Bizzarro, Federico Zizzi, Matteo Signorile, Marco Geppi, Lucia Calucci, Valentina Crocellà, Marco Lessi, Marco Taddei   +11 more
wiley   +1 more source

“Reversible I2 Uptake Induces Record‐High Spin‐Crossover Hysteresis in a Fe(II) Hofmann‐Type MOF”

Chemistry – A European Journal, EarlyView.
Reversible iodine uptake in a flexible Fe(II) Hofmann‐type MOF [Fe(pz)Pd(CN)4] induces record‐wide SCO hysteresis. Gas‐phase I2 acts as internal chemical pressure, stabilizing both high‐spin and LS states without altering the framework, providing a general strategy for tunable bistability in coordination networks.
Mario Pacheco, Higinio Maqueda‐Márquez, Annena Jesuman, Ana Belén Gaspar   +3 more
wiley   +1 more source

Revue sur les analogies et les différences relevées entre un cône de houblon et une baie de raisin : arômes soufrés et azotés

Biotechnologie, Agronomie, Société et Environnement, 2017
Similarities and differences between hop cones and grape berries: sulfur and nitrogen aromas. A review. Introduction. Similarities can be found between the flavors of hop cones and grapes.
Kankolongo Cibaka, ML., Gros, J., Collin, S.   +2 more
doaj