Results 51 to 60 of about 18,189 (198)

Direct α-Imination of N-Acyl Pyrazoles with Nitrosoarenes [PDF]

open access: yes, 2019
Unprecedented α-imino N-acyl pyrazoles were efficiently and selectively prepared through the 1,5,7-triazabicyclo[4.4.0]dec-5-ene (TBD)-catalyzed reaction of nitrosoarenes with N-acyl pyrazoles via an N-nitroso aldol reaction/dehydration sequence.
Overgaard J.   +5 more
core   +1 more source

Synthesis of 4-functionalized pyrazoles via oxidative thio- or selenocyanation mediated by PhICl2 and NH4SCN/KSeCN

open access: yesBeilstein Journal of Organic Chemistry
A series of 4-thio/seleno-cyanated pyrazoles was conveniently synthesized from 4-unsubstituted pyrazoles using NH4SCN/KSeCN as thio/selenocyanogen sources and PhICl2 as the hypervalent iodine oxidant.
Jialiang Wu   +6 more
doaj   +1 more source

Synthesis of Novel Pyrazole Derivatives and Their Tumor Cell Growth Inhibitory Activity

open access: yesMolecules, 2019
To find novel antitumor agents, a series of 1H-benzofuro[3,2-c]pyrazole derivatives 4a-e were designed and synthesized. The treatment of 6-methoxybenzofuran-3(2H)-one 3 with LiHMDS in anhydrous tetrahydrofuran (THF) followed by reaction with 3-substitued
Ying-Jie Cui   +3 more
doaj   +1 more source

Pyrazoles as Key Scaffolds for the Development of Fluorine-18-Labeled Radiotracers for Positron Emission Tomography (PET)

open access: yesMolecules, 2020
The need for increasingly personalized medicine solutions (precision medicine) and quality medical treatments, has led to a growing demand and research for image-guided therapeutic solutions.
Pedro M. O. Gomes   +2 more
doaj   +1 more source

Regioselective Preparation of Saturated Spirocyclic and Ring-Expanded Fused Pyrazoles [PDF]

open access: yes, 2016
Saturated bicyclic pyrazoles represent an important class of biologically active molecules, but their preparation can be hampered by labor-intensive synthesis of required starting materials.
David C. Blakemore (1748281)   +3 more
core   +1 more source

Rhenium(Iv) Complexes with Pyrazole and Substituted-pyrazoles

open access: yes, 1989
Department of Chemistry,Jadavpur University. Calcutta-700 082 Manuscript received 10 February 1988, revised 26 September 1988, accepted 14 December 1988 IN this paper we report rhenium(Iv) complexes of the type Re2 O2 Cl4,L4, where L=pyrazole (Pz), 3-methylpyrazole (MePz), 3,5-dimethylpyrazole (DmPz), 3,4,5-trimethylpyrazole (TmPz) and 1,3,4,5 ...
SHYMAL ROY CHOWDHURY   +2 more
openaire   +2 more sources

Filling the Gap: Chemistry of 3,5-Bis(trifluoromethyl)-1H-pyrazoles [PDF]

open access: yes, 2012
Pyrazoles represent important building blocks for the preparation of bioactive compounds and a large variety of materials, due to their rich coordination chemistry.
Monticelli D   +5 more
core   +1 more source

5-(2,3-Dichlorophenyl)-3-(4-methoxyphenyl)-1-phenyl-4,5-dihydro-1H-pyrazole

open access: yesIUCrData, 2017
In the racemic title compound, C22H18Cl2N2O, the dihedral angles between the central dihydropyrazole ring (r.m.s. deviation = 0.018 Å) and the pendant methoxyphenyl, phenyl and dichlorophenyl rings are 3.96 (9), 15.90 (9) and 66.65 (9)° respectively ...
D. M. Lokeshwari   +6 more
doaj   +1 more source

Selective synthesis of 4-(sulfonyl)-methyl-1H-pyrazoles and (E)-4,5-dihydro-1H-pyrazoles from N-allenic sulfonylhydrazones [PDF]

open access: yes, 2014
National Natural Science Foundation of China [21272190]; PCSIRT in University; NFFTBS [J1210014]Selective synthesis of 4-(sulfonyl)-methyl-1H-pyrazoles and (E)-4,5-dihydro-1H-pyrazoles from N-allenic sulfonylhydrazones with sulfonyl group migrations has ...
Xiao, Yu-Wei   +7 more
core  

Reactions with Hydrazonoyl Halides. 31. Synthesis of Some New Pyrrolidino[3,4-c]pyrazolines, Pyrazoles, and Pyrazolo[3,4-d]pyridazines

open access: yesMolecules, 2000
Pyrrolidino[3,4-c]pyrazoline and pyrazole derivatives were synthesized via reactions of a substituted hydrazonoyl bromide with N-arylmaleimides and active methylene reagents, respectively. Synthesized pyrazoles were reacted with hydrazine hydrate to give
Nagla A. Ahmed   +3 more
doaj   +1 more source

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