Covalent Organic Functionalization of Graphene Nanosheets and Reduced Graphene Oxide via 1,3-Dipolar Cycloaddition of Azomethine Ylide [PDF]
Organic functionalization of graphene is successfully performed via 1,3-dipolar cycloaddition of azomethine ylide in the liquid phase. The comparison between 1-methyl-2-pyrrolidinone and N,N-dimethylformamide as dispersant solvents, and between sonication and homogenization as dispersion techniques, proves N,N-dimethylformamide and homogenization as ...
arxiv +1 more source
Synthesis of a New Chiral Pyrrolidine [PDF]
The synthesis of a new chiral pyrrolidine has been performed using 2,3-O-isopropylidene-D-erythronolactol as a suitable starting material.
Mari Fe. Flores+7 more
openaire +4 more sources
[(Pyrrolidin-1-yl)carbothioylsulfanyl]methyl pyrrolidine-1-carbodithioate [PDF]
The title compound, C(11)H(18)N(2)S(4), was unexpectedly obtained during studies on the reactivity of the complex tris-(acac-κ(2)O,O')gallium(III) (acac is acetyl-acetonate) with C(4)H(8)NCS(2)H in dichloro-methane. The title compound shows disordered two pyrrolidine rings with major and minor occupancies of 0.546 (4) and 0.454 (4).
Wei-Lung Chou+4 more
openaire +4 more sources
Pyrrolidine dithiocarbamates of Pd(II) [PDF]
The dithioester (CH2)4NCS2CH3 (PyDTM, 1-pyrrolidinecarbodithioate methyl ester) has been prepared by reaction of the parent ammonium salt NH4PyDT (PyDT=(CH2)4NCS2 with methyl iodide in water/ethanol. The reaction of PyDTM with PdCl2 allowed to synthesize either (PdCl2(PyDTM)), in which the ligand is chelated by both sulfur atoms, or(PdCl2(PyDTM)2), in ...
Faraglia, Guiseppina+2 more
openaire +6 more sources
(Z)-1-Benzyl-5-(4-bromophenyl)-5-hydroxy-4-(2-oxomorpholin-3-ylidene)pyrrolidine-2,3-dione
The reaction of 8-(4-bromobenzoyl)-3,4-dihydro-1H-pyrrolo[2,1-c][1,4]oxazine-1,6,7-trione with benzylamine in acetonitrile at room temperature afforded a good yield of (Z)-1-benzyl-5-(4-bromophenyl)-5-hydroxy-4-(2-oxomorpholin-3-ylidene)pyrrolidine-2,3 ...
Nikita A. Tretyakov, Andrey N. Maslivets
doaj +1 more source
Photophysical Properties of BODIPY-derivatives for the Implementation of Organic Solar Cells: A Computational Approach [PDF]
Solar cells based on organic compounds are a proven emergent alternative to conventional electrical energy generation. Here, we provide a computational study of power conversion efficiency optimization of BODIPY-derivatives by means of their associated open circuit voltage, short-circuit density, and fill factor.
arxiv +1 more source
The title compound, C34H38ClN5O2, has spiro links connecting the pyrrolidine ring and indole residue, as well as the piperidine and pyrrolidine rings.
I. S. Ahmed Farag+4 more
doaj +1 more source
Design, synthesis, conformational analysis and nucleic acid hybridisation properties of thymidyl pyrrolidine-amide oligonucleotide mimics (POM) [PDF]
Pyrrolidine-amide oligonucleotide mimics (POM) 1 were designed to be stereochemically and conformationally similar to natural nucleic acids, but with an oppositely charged, cationic backbone.
Cooper, M.A.+5 more
core +1 more source
Stabilization of colloidal palladium particles by a block copolymer of polystyrene and a block containing amide sidegroups [PDF]
A block copolymer of polystyrene and poly(tert-butylmethacrylate) was prepared by anionic polymerization. The ester groups of the poly(tert-butylmethacrylate) were hydrolyzed, after wich the remaining carboxyl groups were reacted with pyrrolidine.
Hempenius, M.+3 more
core +2 more sources
The aim of this study was to investigate the in vitro cellular activity of novel spiroisoxazoline type compounds against normal and cancer cell lines from lung tissue (Hs888Lu), neuron-phenotypic cells (SH-SY5Y), neuroblastoma (SH-SY5Y), human ...
Nigar Najim+4 more
doaj +1 more source