A modular continuous‐flow platform enables the Pd‐catalyzed carbonylative N‐aroylation of sulfoximines using carbon monoxide (CO) generated on demand from carbon dioxide (CO2) via solid oxide electrolysis cell (SOEC). The integration of a heterogeneous palladium catalyst and a biomass‐derived solvent provides a safe, scalable, and sustainable route to ...
Giada Moroni +8 more
wiley +1 more source
Copper- and Silver-Catalyzed Reactions of Active Methylene Isocyanides: Facile Access to Highly Substituted Five- and Six-Membered Heterocycles. [PDF]
George J, Oh K.
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Near‐infrared fluorescent pH indicators based on perylenediimide were constructed in a modular receptor–spacer–fluorophore–spacer–receptor format with heterocyclic amino moieties at the bay positions. Counterintuitively, the dibrominated intermediate with two heavy atoms is more emissive than the heterocyclic compounds.
Luke Camenzuli +4 more
wiley +1 more source
Stereocontrolled four-carbon homologation of vicinally functionalized allylic pyrrolidines to highly customized azonines bearing remote benzylic stereocenters. [PDF]
Beng TK, Johnsen A, Gitonga A, Kaur J.
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Monosubstituted N‐arylhydroxylamines represent a unique subclass of hydroxylamines that act as pivotal intermediates in redox transformations and as versatile platforms for further synthetic transformations. They serve as key building blocks in the synthesis of architecturally complex heterocycles and other valuable organic compounds.
Michael G. Kallitsakis +2 more
wiley +1 more source
Ketone Oximes as NO<sub>2</sub> Radical Precursors for Regioselective Iodo-Nitrosylative Cyclization of Unactivated 1,6-Enynes. [PDF]
Mutra MR +4 more
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Recent advances of azomethine ylides for the synthesis of natural and synthetic bioactive pyrrolidines and spiropyrrolidines. [PDF]
Paira P +4 more
europepmc +1 more source
Electronic Activation Enables the Borylation of Alkyl C-H Bonds in Saturated Nitrogen Heterocycles. [PDF]
D'Angelo KA +6 more
europepmc +1 more source
Improved Bicyclic Pyrrolidine Analogues Inhibit <i>Toxoplasma gondii</i> Growth In Vitro and Cure Infection In Vivo. [PDF]
Uddin T +8 more
europepmc +1 more source
Fused-Linked and Spiro-Linked N-Containing Heterocycles. [PDF]
Moskalik MY, Shainyan BA.
europepmc +1 more source

