Asymmetric Addition and Cycloaddition Reactions with Ylidene-Five-Membered Heterocycles [PDF]
Five-membered heterocycles bearing an exocyclic double bond have been successfully used as substrates in asymmetric addition and cycloaddition reactions.
Blay Llinares, Gonzalo+5 more
core +1 more source
Ultra‐low LOD H2O2 Sensor Based on Synergistic Nernst Potential Effect
Due to the synergistic effect of ENernst,H2O2${E}_{\mathrm{Nernst},\ {\mathrm{H}}_{2}{\mathrm{O}}_{2}}$ and ENernst,H+${E}_{\mathrm{Nernst},\ {\mathrm{H}}^{+}}$, the proposed sensors in this study can achieve ultralow H2O2 detection limit as low as 1.8 × 10−12 M based on the stacked PEDOT: BTB/PEDOT: PSS semiconducting layer.
Zhaoqun Wang+12 more
wiley +1 more source
The silver trifluoromethanesulfonate (AgTFMS) simultaneously forms metallic Ag and abundant LiF on the Li metal surface after dissolution in carbonate‐based electrolyte, whereas lithium trifluoromethanesulfonate (LiTFMS) only generates LiF‐rich solid‐electrolyte interphase (SEI).
Jong Hun Sung+8 more
wiley +1 more source
Palladium-Catalyzed Construction of Quaternary Stereocenters by Enantioselective Arylation of γ-Lactams with Aryl Chlorides and Bromides [PDF]
Herein, we report the first Pd‐catalyzed enantioselective arylation of α‐substituted γ‐lactams. Two sets of conditions were developed for this transformation, allowing for the use of either aryl chlorides or bromides as electrophiles.
Bachman, Shoshana+7 more
core +1 more source
ChemInform Abstract: Functionalized Pyrrolidinones Derived from (S)‐Pyroglutamic Acid.
AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
Beard, M+7 more
openaire +4 more sources
Thermally Cured Sulfonated para‐PBI as Ion Solvating Membrane for Use in Water Electrolysis
The cMS‐PBI membrane is designed to be free of the known breaking points which limit the lifetime of membranes in alkaline electrolysis systems. As supported by high conductivity and 6 months ex situ stability test, the cMS‐PBI ion solvating membrane can substitute anion exchange membranes and thus can reduce the cost of green hydrogen by increasing ...
Asridin Dayan+5 more
wiley +1 more source
Pramanicin analog induces apoptosis in human colon cancer cells: critical roles for Bcl-2, Bim, and p38 MAPK signaling [PDF]
Pramanicin (PMC) is an antifungal agent that was previously demonstrated to exhibit antiangiogenic and anticancer properties in a few in vitro studies. We initially screened a number of PMC analogs for their cytotoxic effects on HCT116 human colon cancer
Başağa, Hüveyda+5 more
core +1 more source
Non-noble metal-catalysed carbonylative transformations [PDF]
The dissertation is mainly concerned with non-noble metal-catalyzed carbonylative reactions. More specifically, copper, iron and manganese catalysed carbonylation reactions are presented. In all the above mentioned areas systematic catalyst optimization
Li, Yahui (gnd: 1161758267)
core +1 more source
Photocatalytic Generation of a Ground‐State Electron Donor Through Water Activation
This study presents catalytically generated phosphine oxide radical anions, derived from commercial phosphines and water as potent single‐electron reductants capable of reducing electron‐rich aryl chlorides at potentials as low as −3.3 V (vs. SCE). Cyclic voltammetry studies and DFT calculations offer insights into these P‐based ground‐state electron ...
Maxim‐Aleksa Wiethoff+2 more
wiley +1 more source
Objective: To study the optical properties of nanocomposites as well as antibacterial activity. Method: The experimental study was conducted at the University of Babylon, College of Science and College of Education for Pure Sciences, Babylon, Iraq, from
Sroor Fadhil Obaid, Raheem Kadhim
doaj +1 more source