Benzimidazole-functionalized fluorescent probe for rapid detection of 2,4,6-trinitrophenol and Ag+ in semiaqueous medium [PDF]
In this study, a simple fluorescent chemosensor with good fluorescence properties was synthesized, and was used to develop a sensitive and selective sensor, for the determination of 2,4,6-trinitrophenol (TNP) and Ag+ in THF/H2O medium, based on the ...
Wang Bin +4 more
doaj +1 more source
Diabetes reversal by inhibition of the low-molecular-weight tyrosine phosphatase. [PDF]
Obesity-associated insulin resistance plays a central role in type 2 diabetes. As such, tyrosine phosphatases that dephosphorylate the insulin receptor (IR) are potential therapeutic targets.
Aleshin, Alexander E +22 more
core +2 more sources
Quinoline-2-carbaldehyde [PDF]
The title compound, C(10)H(7)NO, crystallizes with two almost planar mol-ecules (A and B) in the asymmetric unit (r.m.s. deviations = 0.018 and 0.020 Å). In the crystal, the A mol-ecules are linked by weak C-H⋯O inter-actions, thereby generating C(9) [001] chains. The B mol-ecules do not exhibit any directional bonding inter-actions.
Martin O. Onani, William M. Motswainyana
openaire +3 more sources
Carbon-13 n.m.r. investigation on the nitrogen methylation of the mono- and diazanaphthalenes [PDF]
The 13C n.m.r. spectra of the N-methylated mono- and diazanaphthalenes have been recorded and analysed. It has been shown that N-methylation as well as N-protonation in cinnoline occur predominantly at the -nitrogen atom.
Ham, Dirk M.W. van den +2 more
core +2 more sources
In the title compound, C(9)H(8)N(2)O(2)S, the sulfamoyl NH(2) group is involved in intra-molecular N-H⋯N and inter-molecular N-H⋯O hydrogen bonding. In the crystal, molecules are linked via pairs of N-H⋯O hydrogen bonds, forming inversion dimers, which are further associated through π-π stacking inter-actions between the quinoline benzene rings ...
Marciniec, Krzysztof +3 more
openaire +2 more sources
Ultrasonic treated sludge for accelerating quinoline biodegradation
In this work,ultrasound was used for treating sludge,and released organics was used as electron donors for accelerating quinoline biodegradation.Flask experimental results showed that quinoline removal rates are proportional to the biomass of treated and
Wang Youke +4 more
doaj +1 more source
Palladium-catalyzed difluoromethylation of heteroaryl chlorides, bromides and iodides. [PDF]
A palladium-catalyzed difluoromethylation of a series of heteroaryl chlorides, bromides and iodides under mild conditions is described. A wide range of heteroaryl halides such as pyridyl, pyrimidyl, pyrazyl, funanyl, thienyl, pyazolyl, imidazolyl ...
Gu, Yang +4 more
core +1 more source
Hydrogen-Bonding Interactions in Luminescent Quinoline-Triazoles with Dominant 1D Crystals
Quinoline-triazoles 2-((4-(diethoxymethyl)-1H-1,2,3-triazol-1-yl)methyl)quinoline (1), 2-((4-(m-tolyl)-1H-1,2,3-triazol-1-yl)methyl)quinoline (2) and 2-((4-(p-tolyl)-1H-1,2,3-triazol-1-yl)methyl)quinoline (3) have been prepared with CuAAC click reactions
Shi-Qiang Bai +2 more
doaj +1 more source
A Complex Stereochemical Relay Approach To The Antimalarial Alkaloid Ocimicide A1. Evidence For A Structural Revision [PDF]
Ocimicide A1 (1) and the semisynthetic derivative ocimicide A2 (2) are highly potent antimalarial agents efficacious against chloroquine-sensitive and -resistant Plasmodium falciparum strains with IC50 values in the nanomolar and picomolar range ...
Herzon, S. B. +4 more
core +2 more sources
Isolation and Reactivity of a Square‐Planar Trisamido Silane
We report the synthesis and comprehensive characterisation of a square‐planar Si(+IV) hydride supported by an unsymmetric, trianionic and dearomatised N,N,N‐pincer ligand. This system enables element–ligand cooperative reactivity as an alternative to silicon‐centred redox chemistry, illuminating a largely unexplored regime in high‐valent silicon ...
David M. J. Krengel +5 more
wiley +2 more sources

