Results 11 to 20 of about 851,331 (355)
AbstractSynthese und Reaktionen von 1‐Azirinen werden untersucht.
Vasu Nair, Ki Hyup Kim
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Imaging the Photochemical Ring-Opening of 1,3-Cyclohexadiene by Ultrafast Electron Diffraction [PDF]
The ultrafast photoinduced ring-opening of 1,3-cyclohexadiene constitutes a textbook example of electrocyclic reactions in organic chemistry and a model for photobiological reactions in vitamin D synthesis. Here, we present direct and unambiguous observation of the ring-opening reaction path on the femtosecond timescale and sub-{\AA}ngstr\"om length ...
Centurion, M.+22 more
arxiv +5 more sources
Supersymmetry and the Hartmann Potential of Theoretical Chemistry [PDF]
The ring-shaped Hartmann potential $ V = \eta \sigma^{2} \epsilon_{0} \left( \frac{2 a_{0}}{r} - \frac{\eta a_{0}^{2}}{r^{2} sin^{2} \theta} \right) $ was introduced in quantum chemistry to describe ring-shaped molecules like benzene. In this article, the supersymmetric features of the Hartmann potential are discussed.
Blado, Gardo Garnet
arxiv +4 more sources
An unexpected ring formation in morphine chemistry
Reaction of (7R)-N-benzyl-N-nor-7-bromoneopinone dimethyl acetal (2) with primary or secondary amines (RNH2, R1R2NH) resulted in 9-amino-substituted hasubanan derivatives; in particular, modification of the 9-(2-hydroxyethyl)amino derivative in subsequent steps gave products 8 with a 9-(oxazolidin-2'-one-3'-yl) substituent.
Wilhelm Fleischhacker+3 more
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Sol-Gel Chemistry by Ring-Opening Polymerization [PDF]
ABSTRACTSol-gel processing of materials is plagued by shrinkage during polymerization of the alkoxide monomers and processing (aging and drying) of the resulting gels. We have developed a new class of hybrid organic-inorganic materials based on the solventless ring-opening polymerization (ROP) of monomers bearing the 2,2,5,5-tetramethyl-2,5 ...
Kamyar Rahimian, Douglas A. Loy
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Chemistry of Small Ring Compounds. Part. I
Shinya Nishida, Takashi Tsuji
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Silabenzene Incorporated Covalent Organic Frameworks [PDF]
Covalent organic frameworks (COFs) are a promising material for various applications such as gas storage/separation, catalysis, and energy storage, besides offering a confined space for chemical reaction. The introduction of unconventional elements into their frame structures and expanding their structural scope remains a major challenge in COF ...
arxiv +1 more source
We combine operando diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) with on-line mass spectrometry (MS) to study the correlation between the oxidation state of titania-supported IrO2 catalysts (IrO2@TiO2) and their catalytic activity
Phillip Timmer+3 more
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