Results 1 to 10 of about 167,233 (404)

Stereochemistry and Vitalism [PDF]

open access: greenNature, 1898
ALTHOUGH Prof. Japp has already replied to the criticisms which have appeared in NATURE on his address to the Chemical Section of the British Association, we should be glad, in view of the interest taken in the matter, and also because we have been investigating externally compensated and optically active compounds for some years past, if you could ...
Kipping, F. Stanley, Pope, William J.
  +21 more sources

Stereocontrolled synthesis and nuclear magnetic resonance analysis of boranophosphate/phosphate chimeric oligonucleotides [PDF]

open access: yesRoyal Society Open Science
This report describes the stereoselective synthesis of boranophosphate/phosphate (PB/PO) chimeric oligodeoxynucleotides (ODNs) and the nuclear magnetic resonance (NMR) analysis of oligomers containing PB linkages.
Kiyoshi Kakuta   +4 more
doaj   +2 more sources

THE STEREOCHEMISTRY OF FUMAGILLIN [PDF]

open access: greenProceedings of the National Academy of Sciences, 1962
D. Stanley Tarbell, John R. Turner
openaire   +4 more sources

Stereochemistry of N-Acyl-5H-dibenzo[b,d]azepin-7(6H)-ones

open access: yesMolecules, 2023
The stereochemical properties of N-acyl-5H-dibenzo[b,d]azepin-7(6H)-ones (2a–c), which inhibit potassium channels in T cells, were examined by freezing their conformational change due to 4-methyl substitution.
Arisa Chiba   +8 more
doaj   +1 more source

A unique bacteriohopanetetrol stereoisomer of marine anammox [PDF]

open access: yes, 2020
Anaerobic ammonium oxidation (anammox) is a major process of bioavailable nitrogen removal from marine systems. Previously, a bacteriohopanetetrol (BHT) isomer, with unknown stereochemistry, eluting later than BHT using high performance liquid ...
Alex Charlton, E.   +14 more
core   +4 more sources

Synthesis of New C-3 Substituted Kynurenic Acid Derivatives

open access: yesMolecules, 2020
The application of kynurenic acid (KYNA) as an electron-rich aromatic system in the modified Mannich reaction has been examined. The extension possibility of the reaction was tested by using amines occurring in a number of bioactive products, such as ...
Bálint Lőrinczi   +3 more
doaj   +1 more source

Substrate control in stereoselective lanthionine biosynthesis. [PDF]

open access: yes, 2015
Enzymes are typically highly stereoselective catalysts that enforce a reactive conformation on their native substrates. We report here a rare example in which the substrate controls the stereoselectivity of an enzyme-catalysed Michael-type addition ...
Houk, KN   +3 more
core   +4 more sources

Diels–Alder reaction of β-fluoro-β-nitrostyrenes with cyclic dienes

open access: yesBeilstein Journal of Organic Chemistry, 2021
The Diels–Alder reaction of β-fluoro-β-nitrostyrenes with cyclic 1,3-dienes was investigated. A series of novel monofluorinated norbornenes was prepared in up to 97% yield.
Savva A. Ponomarev   +7 more
doaj   +1 more source

Solvent-Free C-3 Coupling of Azaindoles with Cyclic Imines

open access: yesMolecules, 2019
By direct coupling 7-azaindole and cyclic imines, such as 3,4-dihydroisoquinoline, 6,7-dihydrothieno[3,2-c]pyridine, 3,4-dihydro-β-carboline, and 4,5-dihydro-3H-benz[c]azepine, new 3-substituted 7-azaindole derivatives have been synthesized.
Khadija Belasri   +2 more
doaj   +1 more source

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