Results 1 to 10 of about 167,233 (404)
Stereochemistry and Vitalism [PDF]
ALTHOUGH Prof. Japp has already replied to the criticisms which have appeared in NATURE on his address to the Chemical Section of the British Association, we should be glad, in view of the interest taken in the matter, and also because we have been investigating externally compensated and optically active compounds for some years past, if you could ...
Kipping, F. Stanley, Pope, William J.
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Stereocontrolled synthesis and nuclear magnetic resonance analysis of boranophosphate/phosphate chimeric oligonucleotides [PDF]
This report describes the stereoselective synthesis of boranophosphate/phosphate (PB/PO) chimeric oligodeoxynucleotides (ODNs) and the nuclear magnetic resonance (NMR) analysis of oligomers containing PB linkages.
Kiyoshi Kakuta+4 more
doaj +2 more sources
THE STEREOCHEMISTRY OF FUMAGILLIN [PDF]
D. Stanley Tarbell, John R. Turner
openaire +4 more sources
Stereochemistry of N-Acyl-5H-dibenzo[b,d]azepin-7(6H)-ones
The stereochemical properties of N-acyl-5H-dibenzo[b,d]azepin-7(6H)-ones (2a–c), which inhibit potassium channels in T cells, were examined by freezing their conformational change due to 4-methyl substitution.
Arisa Chiba+8 more
doaj +1 more source
A unique bacteriohopanetetrol stereoisomer of marine anammox [PDF]
Anaerobic ammonium oxidation (anammox) is a major process of bioavailable nitrogen removal from marine systems. Previously, a bacteriohopanetetrol (BHT) isomer, with unknown stereochemistry, eluting later than BHT using high performance liquid ...
Alex Charlton, E.+14 more
core +4 more sources
Synthesis of New C-3 Substituted Kynurenic Acid Derivatives
The application of kynurenic acid (KYNA) as an electron-rich aromatic system in the modified Mannich reaction has been examined. The extension possibility of the reaction was tested by using amines occurring in a number of bioactive products, such as ...
Bálint Lőrinczi+3 more
doaj +1 more source
Substrate control in stereoselective lanthionine biosynthesis. [PDF]
Enzymes are typically highly stereoselective catalysts that enforce a reactive conformation on their native substrates. We report here a rare example in which the substrate controls the stereoselectivity of an enzyme-catalysed Michael-type addition ...
Houk, KN+3 more
core +4 more sources
Diels–Alder reaction of β-fluoro-β-nitrostyrenes with cyclic dienes
The Diels–Alder reaction of β-fluoro-β-nitrostyrenes with cyclic 1,3-dienes was investigated. A series of novel monofluorinated norbornenes was prepared in up to 97% yield.
Savva A. Ponomarev+7 more
doaj +1 more source
Solvent-Free C-3 Coupling of Azaindoles with Cyclic Imines
By direct coupling 7-azaindole and cyclic imines, such as 3,4-dihydroisoquinoline, 6,7-dihydrothieno[3,2-c]pyridine, 3,4-dihydro-β-carboline, and 4,5-dihydro-3H-benz[c]azepine, new 3-substituted 7-azaindole derivatives have been synthesized.
Khadija Belasri+2 more
doaj +1 more source