Results 11 to 20 of about 71,659 (279)

The Stereochemistry of Ketoreduction [PDF]

open access: yesChemistry & Biology, 2005
In this issue of Chemistry & Biology, Leadlay and coworkers [1] report overproduction of a number of ketoreductase domains from modular polyketide synthases.
Caffrey, Patrick
core   +4 more sources

Stereochemistry and Total Synthesis of Neonorhalichondrin B [PDF]

open access: yes, 2023
The first total synthesis of neonorhalichondrin B has been completed and the previously undetermined left half sidechain stereochemistry has been elucidated.
Rachelle, Quach   +2 more
core   +2 more sources

STEREOCHEMISTRY AND MECHANISM OF CHLOROPALLADATION OF ACETYLENES

open access: yes, 1995
The stereochemistry of chloropalladation of acetylenes has been studied. Chloropalladation adducts from terminal acetylenes were trapped in situ by reaction with either allyl chloride or 1,3-cyclohexadiene.
BACKVALL, JE,   +2 more
core   +8 more sources

Stereochemistry-Tunable Isocyanide-Based Polymerization

open access: yes, 2021
Regulation of stereochemistry is one of the most important research focuses in synthetic polymer chemistry; however, this area should be further developed.
Tianyu Cheng   +11 more
core   +1 more source

Stereochemistry-Controlled Mechanical Properties and Degradation in 3D-Printable Photosets

open access: yes, 2021
Stereochemistry provides an appealing handle by which to control the properties of small molecules and polymers. While it is established that stereochemistry in linear polymers affects their bulk mechanical properties, the application of this concept to ...
Anissa L. Khalfa (11570389)   +5 more
core   +1 more source

Recent Advances in Stereochemistry Reveal Classification Shortcomings [PDF]

open access: yes, 2020
We contend that the Polytope model utilized by IUPAC to specify stereoisomerism for species MLn with n > 3 should be universally applied. Such application recently led to the synthesis of isolable compounds displaying a new fundamental form of isomerism,
Peter J., Canfield   +3 more
core   +1 more source

May the Force (Field) Be with You: On the Importance of Conformational Searches in the Prediction of NMR Chemical Shifts

open access: yesMarine Drugs, 2022
NMR data prediction is increasingly important in structure elucidation. The impact of force field selection was assessed, along with geometry and energy cutoffs.
Cristina Cuadrado   +2 more
doaj   +1 more source

Advancing peptide siRNA-carrier designs through L/D-amino acid stereochemical modifications to enhance gene silencing

open access: yesMolecular Therapy: Nucleic Acids, 2021
The 599 peptide has been previously shown to effectively deliver small interfering RNAs (siRNAs) to cancer cells, inducing targeted-oncogene silencing, with a consequent inhibition of tumor growth. Although effective, this study was undertaken to advance
Charles E. Holjencin   +10 more
doaj   +1 more source

Stereochemistry of the Brivaracetam Diastereoisomers [PDF]

open access: yesChirality, 2016
AbstractThe stereochemistry of all four stereoisomers of brivaracetam was determined using vibrational circular dichroism (VCD) spectroscopy. By comparing experimentally obtained VCD spectra and computationally simulated ones, the absolute configurations can be confidently assigned without prior knowledge of their relative stereochemistry.
Qiu, Shi   +5 more
openaire   +3 more sources

[1,3]/[1,4]-Sulfur atom migration in β-hydroxyalkylphosphine sulfides

open access: yesBeilstein Journal of Organic Chemistry, 2020
β-Hydroxyalkylphosphine sulfides undergo [1,3]- or [1,4]-sulfur atom phosphorus-to-carbon migration in the presence of Lewis or Brønsted acids. The direction of sulfur atom migration depends on the type of acid used for the reaction. In the presence of a
Katarzyna Włodarczyk   +2 more
doaj   +1 more source

Home - About - Disclaimer - Privacy