Results 161 to 170 of about 177,307 (324)

Total Synthesis and Complete Stereochemical Assignment of Amphirionin‐5, a Potent Natural Osteoblasts Proliferator

open access: yesChemistryEurope, EarlyView.
The convergent total synthesis of a candidate diastereomer of amphirionin‐5 was accomplished in 22 steps via the coupling of the C1‐C16 enone segment and the C17‐C28 aldehyde segment using Stetter reaction. The overall stereochemistry of amphirionin‐5 was fully assigned, based on the comparison of spectroscopic and chiroptical data between the ...
Yusuke Ogura   +7 more
wiley   +1 more source

Stereochemistry-aware string-based molecular generation. [PDF]

open access: yesPNAS Nexus
Tom G   +4 more
europepmc   +1 more source

Stereochemistry of Endogenous Palmitic Acid Ester of 9-Hydroxystearic Acid and Relevance of Absolute Configuration to Regulation.

open access: yesJournal of the American Chemical Society, 2017
A. T. Nelson   +6 more
semanticscholar   +1 more source

Introducing the Cis‐2,3‐Bis(trifluoromethyl)cyclopropyl Chemotype: Late‐Stage Installation and Stereoelectronic Properties

open access: yesChemistryEurope, EarlyView.
The cis‐2,3‐bis(trifluoromethyl)cyclopropyl chemotype is introduced. The steric demand of this motif is intermediate between that of the heptafluoroisopropyl and prefluorotertbutyl groups; yet, it induces significantly less lipophilicity than these due to its facial polarity.
Daniel Gaviña   +5 more
wiley   +1 more source

Stereochemistry of the dTDP-glucose oxidoreductase reaction.

open access: hybrid, 1977
Carl E. Snipes   +4 more
openalex   +1 more source

Bottom-Up Elucidation of Glycosidic Bond Stereochemistry.

open access: yesAnalytical Chemistry, 2017
C. Gray   +15 more
semanticscholar   +1 more source

Bioorthogonal Chemistry in Biomolecule Quantification: A Review of Reactions and Strategies

open access: yesChemistry – A European Journal, EarlyView.
This review summarizes the application of catalyst‐free bioorthogonal reactions: Staudinger ligation, strain promoted azide alkyne cycloaddition, inverse electron‐demand Diels–Alder, and 2‐cyanobenzothiazole cysteine condensation in the semi‐quantitative and quantitative analysis of biomolecules.
Mingze Yang, Shiqi Wang
wiley   +1 more source

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