Results 161 to 170 of about 63,316 (301)

Singlet machine learning photodynamics reveal competing inversion paths of methylated cyclooctatetrathiophene. [PDF]

Chem Sci
Salguero C, Lopez SA.
europepmc   +1 more source

STEREOCHEMISTRY AND KINETICS IN THE HYDROLYSIS OF EPIMERIC PHOSPHATE TRIESTERS.

, 1980
STEREOCHEMISTRY AND KINETICS IN THE HYDROLYSIS OF EPIMERIC PHOSPHATE ...
ROBERT LEE. ROWELL (7957202)
core  

The tryptophan prenyltransferase ComQ from Bacillus subtilis 168 can prenylate daptomycin at Trp1

The FEBS Journal, EarlyView.
ComQ168 from Bacillus subtilis 168 catalyzes C‐terminal tryptophan farnesylation of ComX to generate a competence‐inducing pheromone. Recombinant ComQ168 also modifies cyclic peptides, including Daptomycin, likely at the N‐terminal tryptophan. Structural modeling highlights a C‐terminal binding region, supporting substrate promiscuity and establishing ...
Yanli Xu, Maximilian J. L. J. Fürst, Oscar P. Kuipers   +2 more
wiley   +1 more source

Influence of molecular shape and hydrogen bonding on glycolipid self-assembly into thermotropic gyroid phases. [PDF]

Chem Sci
Das S, Zheng C, Lodge TP, Siepmann JI, Calabrese MA, Reineke TM.   +5 more
europepmc   +1 more source

Cryo‐EM structure of GH43 β‐Xylosidase from Enterobacter cloacae provides insights into substrate specificity and the role of an auxiliary domain in enzymatic activity

The FEBS Journal, EarlyView.
Xylan, the second most abundant plant cell wall polysaccharide, is degraded by β‐xylanases and β‐xylosidases. Here, we present the 2.65 Å cryo‐EM structure of Enterobacter cloacae β‐xylosidase (EcXyl43, GH43) and the 2.4 Å X‐ray structure of its inactive F507A mutant.
Lorenzo Briganti, Andre Schutzer Godoy, Caio Cesar Mello Capetti, Rafaela Sachetto Fernandes, Vanessa O. A. Pellegrini, Ornella M. Ontañon, Eleonora Campos, Rodrigo V. Portugal, Igor Polikarpov   +8 more
wiley   +1 more source

Syntheses of all stereoisomers of aptosimon (9-oxosesamin) and their effects on plant growth regulation and diacylglycerol acyltransferase inhibition. [PDF]

J Pestic Sci
Okada M, Iwata A, Nishiwaki H, Mori S, Yamauchi S.   +4 more
europepmc   +1 more source

Synthesis and reactivity of silylmethylcyclopropanes

, 2011
PhDSubstituted tetrahydrofurans (THFs) are common structural motifs found in natural products. The biological activity and structural complexity of these compounds makes their efficient construction with controlled regio- and stereochemistry a ...
Dunn, Jonathan
core  

Benign by design: A paradigm shift in cosmetic ingredient development

International Journal of Cosmetic Science, EarlyView.
Benign by design strategies enable the creation of biodegradable cosmetic ingredients, reducing environmental persistence while maintaining the intended biological activity. This work compiles design rules and tools to guide the development of more sustainable molecules for the cosmetics industry.
Sandra Mota, Klaus Kümmerer, Isabel Martins de Almeida, Emília Sousa   +3 more
wiley   +1 more source

A novel stereochemistry retention mechanism in the S_N2 reaction. [PDF]

Nat Commun
Song Z, Gao H, Xie J.
europepmc   +1 more source

Barley HvBODYGUARD1 controls cuticular specialisations regulated by SHINE transcription factors

New Phytologist, EarlyView.
Cuticle defects result from defective HvBDG1 alleles. Summary Land plants secrete a protective outer cuticular layer with diverse functions. Barley (Hordeum vulgare L.) develops two cuticular specialisations: the β‐diketone rich wax bloom on vegetative tissues and an adherent grain surface which sticks to the hulls, leading to barley's distinctive ...
Trisha McAllister, Chiara Campoli, Linsan Liu, Tansy Chia, S. Ronan Fisher, Richard Horsnell, Alan R. Prescott, Jennifer Shoesmith, Mhmoud Eskan, Alasdair Iredale, Mirjam Nuter, Luke Ramsay, Micha M. Bayer, Linda Milne, Miriam Schreiber, Yogeswari Rajarathinam, Vanessa Wahl, Robbie Waugh, James Cockram, Sarah M. McKim   +19 more
wiley   +1 more source