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Stereochemistry and Vitalism [PDF]
ALTHOUGH Prof. Japp has already replied to the criticisms which have appeared in NATURE on his address to the Chemical Section of the British Association, we should be glad, in view of the interest taken in the matter, and also because we have been investigating externally compensated and optically active compounds for some years past, if you could ...
W. M. STRONG
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Stereochemistry-Controlled Mechanical Properties and Degradation in 3D-Printable Photosets
Stereochemistry provides an appealing handle by which to control the properties of small molecules and polymers. While it is established that stereochemistry in linear polymers affects their bulk mechanical properties, the application of this concept to ...
Matthew L Becker, Andrew P Dove
exaly +2 more sources
Lipids have fundamental roles in the structure, energetics, and signaling of cells and organisms. The recent discovery of fatty acid esters of hydroxy fatty acids (FAHFAs), lipids with potent antidiabetic and anti-inflammatory activities, indicates that ...
Dionicio Siegel+2 more
exaly +2 more sources
Stereochemistry of the Brivaracetam Diastereoisomers. [PDF]
The stereochemistry of all four stereoisomers of brivaracetam was determined using vibrational circular dichroism (VCD) spectroscopy. By comparing experimentally obtained VCD spectra and computationally simulated ones, the absolute configurations can be ...
Shi Qiu+5 more
semanticscholar +5 more sources
Stereochemistry of post-transition metal oxides: revision of the classical lone pair model
The chemistry of post transition metals is dominated by the group oxidation state N and a lower N-2 oxidation state, which is associated with occupation of a metal s(2) lone pair, as found in compounds of Tl(I), Pb(II) and Bi(III).
Aron Walsh+2 more
exaly +2 more sources
The resolution of the acute inflammatory response is governed by phagocytes actively clearing apoptotic cells and pathogens. Biosynthesis of the specialized pro-resolving mediators (SPMs) is pivotal in the resolution of inflammation via their roles in ...
Stephania Libreros+6 more
semanticscholar +1 more source
Stereochemistry of N-Acyl-5H-dibenzo[b,d]azepin-7(6H)-ones
The stereochemical properties of N-acyl-5H-dibenzo[b,d]azepin-7(6H)-ones (2a–c), which inhibit potassium channels in T cells, were examined by freezing their conformational change due to 4-methyl substitution.
Arisa Chiba+8 more
doaj +1 more source
A unique bacteriohopanetetrol stereoisomer of marine anammox [PDF]
Anaerobic ammonium oxidation (anammox) is a major process of bioavailable nitrogen removal from marine systems. Previously, a bacteriohopanetetrol (BHT) isomer, with unknown stereochemistry, eluting later than BHT using high performance liquid ...
Alex Charlton, E.+14 more
core +4 more sources