Results 21 to 30 of about 174,911 (284)

Stereochemistry [PDF]

open access: yesAnnual Reports on the Progress of Chemistry, 1904
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openaire   +4 more sources

Mannich base-connected syntheses mediated by ortho-quinone methides

open access: yesBeilstein Journal of Organic Chemistry, 2018
This article provides an overview about specifically modified Mannich reactions where the process involves an ortho-quinone methide (o-QM) intermediate.
Petra Barta   +2 more
doaj   +1 more source

RDChiral: An RDKit Wrapper for Handling Stereochemistry in Retrosynthetic Template Extraction and Application

open access: yesJournal of Chemical Information and Modeling, 2019
There is a renewed interest in computer-aided synthesis planning, where the vast majority of approaches require the application of retrosynthetic reaction templates.
Connor W. Coley, W. Green, K. Jensen
semanticscholar   +1 more source

X-ray Diffraction, Electronic Circular Dichroism, and Quantum Mechanics (TD-DFT) Investigations on 4 Dehydroxyaltersolanol A, a Secondary Metabolite from Endophytic Fungus Nigrospora oryzae [PDF]

open access: yesResearch Journal of Pharmacognosy
Background and objectives: A tetrahydro anthraquinone derivative, 4-dehydroxyaltersolanol A, has been obtained from Nigrospora oryzae, which was isolated from Uncaria borneensis Havil as an endophytic fungus.
Fatimah Bebe Mohamed Hussain   +8 more
doaj   +1 more source

New Antibacterial Diterpenoids from the South China Sea Soft Coral Klyxum molle

open access: yesMarine Drugs, 2023
Fifteen new diterpenoids, namely xishaklyanes A-O (1–15), along with three known related ones (16–18), were isolated from the soft coral Klyxum molle collected from Xisha Islands, South China Sea.
Jia-Dong Yu   +5 more
doaj   +1 more source

May the Force (Field) Be with You: On the Importance of Conformational Searches in the Prediction of NMR Chemical Shifts

open access: yesMarine Drugs, 2022
NMR data prediction is increasingly important in structure elucidation. The impact of force field selection was assessed, along with geometry and energy cutoffs.
Cristina Cuadrado   +2 more
doaj   +1 more source

Structure and stereochemistry of the base excision repair glycosylase MutY reveal a mechanism similar to retaining glycosidases. [PDF]

open access: yes, 2015
MutY adenine glycosylases prevent DNA mutations by excising adenine from promutagenic 8-oxo-7,8-dihydroguanine (OG):A mismatches. Here, we describe structural features of the MutY active site bound to an azaribose transition state analog which indicate a
Cao, Sheng   +6 more
core   +2 more sources

The Stereochemistry of Ketoreduction [PDF]

open access: yesChemistry & Biology, 2005
In this issue of Chemistry & Biology, Leadlay and coworkers report overproduction of a number of ketoreductase domains from modular polyketide synthases. These discrete enzymes allow the stereochemistry of polyketide ketoreduction to be studied in isolation.
openaire   +3 more sources

Contribution of the Chemistry Institutes to the Early Development of Stereochemistry

open access: yesCHIMIA, 2009
This article is a translation from German of a paper submitted by Kurt Hermann to the University of Zurich Prize committee in 1968, with additional editing by Jay Siegel.
Kurt Hermann
doaj   +1 more source

Stereochemistry of Chiral 2-Substituted Chromanes: Twist of the Dihydropyran Ring and Specific Optical Rotation

open access: yesMolecules, 2023
Chiral 2-substituted chromanes are important substructures in organic synthesis and appear in numerous natural products. Herein, the correlation between specific optical rotations (SORs) and the stereochemistry at C2 of chiral 2-substituted chromanes was
Bei-Bei Yang   +5 more
doaj   +1 more source

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