Results 271 to 280 of about 166,370 (359)

A Radical Cascade with Double Intramolecular Hydrogen Atom Transfer for the Generation of Bisfunctionalized Cyclopentanes from Linear Alkynes

Angewandte Chemie, Volume 138, Issue 5, 28 January 2026.
A radical cascade process involving the activation of two aliphatic C–H bonds in a series of five elementary steps converts readily available terminal alkynes into functionalized cyclopentylmethyl arylsulfones. The methodology delivers flexible synthetic intermediates and was applied to the preparation of diquinanes and triquinanes possessing a rare ...
Lise Benoist, Éléonore Barbier, Mariam Sangare, Philippe Renaud, Fabrice Dénès   +4 more
wiley   +2 more sources

DFT Benchmarking for [Fe^II]‑(Alkyl/Alkylidene/Acetylide) Complexes. [PDF]

ACS Omega
da Silva LS, Soares FS, de Souza AA, Sá É.   +3 more
europepmc   +1 more source

Stereoselectivity in the Synthesis of 5'-Alkylated Nicotines

, 1986
Makoto Shibagaki, Hajime Matsushita, Hajime Kaneko   +2 more
openalex   +1 more source

Exploring the influence of lid region residues on fatty acid selectivity in a lipase originating from Rhizopus oryzae

The FEBS Journal, Volume 293, Issue 3, Page 878-893, February 2026.
Lipases are vital in modifying lipid substrates across industries such as food, cosmetics, and pharmaceuticals. Among their features, fatty acid selectivity is particularly important for industrial applications. Rhizopus oryzae lipase (ROL) stands out for its high selectivity and broad applicability.
Zehui Dong, Majid Haddad Momeni, Kim Olofsson, Eva Nordberg Karlsson   +3 more
wiley   +1 more source

Harnessing Photoenzymatic Systems for Intermolecular C–H Fluorination

Angewandte Chemie, Volume 138, Issue 5, 28 January 2026.
Despite the remarkable versatility of enzymes for catalyzing complex organic transformations under mild aqueous conditions, no biocatalytic system has been reported for intermolecular C–H fluorination. A radical photoenzymatic approach is introduced that leverages a designed de novo protein scaffold with an unnatural amino acid to achieve precise ...
Yu Zhou, Danielle Lawson, Zihan Zhang, Yunling Deng, Hejun Deng, Connor J. O'Dea, Zachariah A. Page, Yi Lu   +7 more
wiley   +2 more sources

Computational rational design of unspecific peroxygenase for C-H oxidation. [PDF]

Sci Adv
Gao R, Fu X, Li Z, Wang Z, Li G, Ge J, Hollmann F, Wang Z, Lou WY, Wu X.   +9 more
europepmc   +1 more source

Enhanced Selectivity of Chalcogen Bonding over Halogen Bonding Catalyzed C-glycosylation Through Differentiated Intermediate Activation. [PDF]

Angew Chem Int Ed Engl
Guo H, Loh CCJ.
europepmc   +1 more source

Chiral Monoamidines as Effective Organocatalysts for the Stereoselective Synthesis of Oxindoles under Homogeneous and Heterogeneous Conditions. [PDF]

J Org Chem
Toldo S, Poletti L, Di Carmine G, De Risi C, Massi A, Ragno D.   +5 more
europepmc   +1 more source

Thiophene Derivatives as Versatile Precursors for (Hetero)Arene and Natural Product Synthesis

Angewandte Chemie International Edition, Volume 65, Issue 5, 28 January 2026.
Hidden but Powerful: Thiophenes and their saturated analogues have been demonstrated to be versatile C4‐building blocks that can be rapidly applied to natural product synthesis and the construction of functionalized (hetero)arenes. This minireview aims to provide a concise overview of the strategies and implementations of these sulfur‐containing ...
Anna Keimer, Franz‐Lucas Haut
wiley   +1 more source

Stereoselective analysis of thioridazine and its major metabolites: a kinetic study of biotransformation by fungi

, 2006
Keyller Bastos Borges
openalex   +1 more source