Results 41 to 50 of about 1,739 (182)
Synthesis of N-Substituted Sulfamate Esters from Sulfamic Acid Salts by Activation with Triphenylphosphine Ditriflate [PDF]
A general approach to access sulfamate esters through preparation of sulfamic acid salts, subsequent activation with triphenylphosphine ditriflate, and nucleophilic trapping is disclosed. The method proceeds in modest to excellent yields to incorporate nucleophiles derived from aliphatic alcohols and phenols.
J. Miles Blackburn +5 more
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Citation: 'sulfamic acids' in the IUPAC Compendium of Chemical Terminology, 3rd ed.; International Union of Pure and Applied Chemistry; 2006. Online version 3.0.1, 2019. 10.1351/goldbook.S06091 • License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International for individual terms.
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Self‐Healing Materials from Electronically Integrated Microscopic Robots
Submillimeter robots can use electronically controlled electrodeposition to assemble into a material structure. The resulting aggregate possesses ultralow density, high strength‐to‐weight ratio, and can heal from damage. Further afield, these results clear a path to materials that organize or adapt by directing matter and information at the microscale.
Lucas C. Hanson +2 more
wiley +1 more source
Decoding Urease Inhibition: A Comprehensive Review of Inhibitor Scaffolds
Representative functional groups known for urease inhibition are reviewed within diverse scaffolds using structure–activity analyses to identify features associated with high inhibitory activity. Urease is a metalloenzyme produced by a wide range of organisms and plays a critical role in nitrogen microbial metabolism by catalyzing the hydrolysis of ...
Nuno Martinho, Natália Aniceto
wiley +1 more source
Insufficient hole injection in the quantum dot emission layer is the primary challenge limiting the performance of blue devices. Herein, a bilateral ligands modification strategy is proposed to enhance the hole injection efficiency on the basis of improving the hole transport efficiency, effectively improves the carrier recombination efficiency, with ...
Yanfang Ren +5 more
wiley +1 more source
Human carbonic anhydrase IX (hCA IX) is a zinc(II)-dependent metalloenzyme that plays a critical role in the conversion of carbon dioxide and water to protons and bicarbonate.
Matthias Bache +12 more
doaj +1 more source
A Sulfonative rearrangement of N-Aryl Sulfamates to para-Sulfonyl Anilines [PDF]
Yifei Zhou, Alan M. Jones
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Sulfatases: Catalytic Mechanism, Substrate Preferences, and Carbohydrate‐Based Inhibitor Design
Sulfatases are a class of enzymes that can cleave sulfates from heparan sulfate and modulate many of their biological activities. In this review, following a general introduction on sulfatase, their enzymatic mechanism and substrate scope are discussed.
Morgan Mayieka +3 more
wiley +1 more source
Oxidative Cyclization of Sulfamates onto Pendant Alkenes
This communication discloses the first examples of aza-Wacker cyclizations of sulfamate esters. Within the realm of related cyclization reactions, this protocol is differential in that it forms six-membered rings in good yield and uses catalytic amounts of palladium(0) rather than palladium(II) salts.
Anand H. Shinde, Shyam Sathyamoorthi
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