Results 111 to 120 of about 57,645 (308)

Cathodic Cleavage of ortho-Alkyl Substituted Alkyl Aryl Sulfones. [PDF]

open access: bronze, 1977
Bo Lamm   +6 more
openalex   +1 more source

Introducing the Cis‐2,3‐Bis(trifluoromethyl)cyclopropyl Chemotype: Late‐Stage Installation and Stereoelectronic Properties

open access: yesChemistryEurope, EarlyView.
The cis‐2,3‐bis(trifluoromethyl)cyclopropyl chemotype is introduced. The steric demand of this motif is intermediate between that of the heptafluoroisopropyl and prefluorotertbutyl groups; yet, it induces significantly less lipophilicity than these due to its facial polarity.
Daniel Gaviña   +5 more
wiley   +1 more source

Formation of disulfonated poly(arylene ether sulfone) thin film desalination membranes plasticized with poly(ethylene glycol) by solvent-free melt extrusion

open access: green, 2016
Hee Jeung Oh   +7 more
openalex   +2 more sources

From Two‐Electron to Four‐Electron System: Electrolyte Regulation for Advanced Aqueous Zn–I2 Batteries

open access: yesCarbon Energy, EarlyView.
This review systematically summarizes recent progress in electrolyte‐regulated aqueous Zn–I2 batteries (AZIBs). It outlines the fundamentals of AZIBs along with their main challenges, and then analyzes electrolyte‐engineering strategies that improve both two‐ and four‐electron reactions.
Yucong Wang   +10 more
wiley   +1 more source

A Review on Applications and Challenges of Fullerenes in Proton Exchange Membranes

open access: yesCarbon Energy, EarlyView.
This review is devoted to the analysis of the use of fullerenes and their functionalized derivatives to improve the efficiency of proton exchange membranes. The synthetic methods, structure, properties, and proton transfer mechanisms of fullerene‐containing membranes are discussed in detail. Promising areas of scientific research are discussed, and key
Ruslan Usmanov, Alexander Pozdnyakov
wiley   +1 more source

Iron-catalyzed fluoroalkylative alkylsulfonylation of alkenes via radical-anion relay

open access: yesNature Communications
Transition metal-catalyzed reductive difunctionalization of alkenes with alkyl halides is a powerful method for upgrading commodity chemicals into densely functionalized molecules.
Xiaoya Hou, Hongchi Liu, Hanmin Huang
doaj   +1 more source

Methyl on the Bridge: 2‐Methyl Propellane as Precursor for 1,3‐Substituted 2‐Methylated Bicyclo[1.1.1]Pentanes

open access: yesChemistry – A European Journal, EarlyView.
The synthesis of 2‐methyl propellane and its conversion to various 1,2‐ and 1,2,3‐di‐ and trisubstituted bicyclopentanes is reported. Abstract Bicyclo[1.1.1]pentanes (BCPs) have emerged as isosteric replacements for mono‐ and para‐substituted benzene rings in medicinal and materials applications, involving substitution at the BCP bridgehead (1,3 ...
Sean R. Verschaeve   +4 more
wiley   +1 more source

AgBF4‐Induced Site‐Selective Synthesis of 4‐Sulfonylindoles in Au‐Catalyzed Cyclization‐Sulfonyl Migration Reactions

open access: yesChemistry – A European Journal, EarlyView.
Site‐selective synthesis 4‐suflonylindoles was achieved by a cyclization‐rearrangement strategy by π‐Lewis acidic gold catalysts and the aid of silver cocatalyst. Particularly, the use of 3 equivalents of AgBF4 to SPhosAuCl is crucial for C4‐selective migration of the sulfonyl group.
Itaru Nakamura   +2 more
wiley   +1 more source

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