Results 171 to 180 of about 114,347 (402)

Polyimide adhesives [PDF]

open access: yes
A process of preparing aromatic polyamide-acids for use as adhesives is described. An equimolar quantity of an aromatic dianhydride is added to a stirred solution of an aromatic diamine in a water or alcohol-miscible ether solvent to obtain a viscous ...
Bell, V. L.   +2 more
core   +1 more source

“On Water” Photochemistry: Visible‐Light‐Induced Synthesis of Diaryl Sulfides by Nitrogen Extrusion

open access: yesChemistryEurope, EarlyView.
This study demonstrates an efficient and versatile blue light‐mediated synthesis of dissymmetric diaryl sulfides by nitrogen photoextrusion from diarylazo sulfides. The reaction is carried out “on water” without the need for (photo)catalysts or additives.
Hawraz Ibrahim M. Amin   +4 more
wiley   +1 more source

Iron-catalyzed fluoroalkylative alkylsulfonylation of alkenes via radical-anion relay

open access: yesNature Communications
Transition metal-catalyzed reductive difunctionalization of alkenes with alkyl halides is a powerful method for upgrading commodity chemicals into densely functionalized molecules.
Xiaoya Hou, Hongchi Liu, Hanmin Huang
doaj   +1 more source

Aziridination of Olefins by a Copper Phenanthroline Catalyst

open access: yesChemistryEurope, EarlyView.
A redox‐active Cu(I)‐photocatalyst is evaluated for the aziridination of alkenes. Especially styrenes and electron‐rich 1,3‐dienes are found to be suitable substrates, allowing short reaction times (10 min) at low catalyst loading (1 mol%). The activation of the copper(I) complex by light is compared to the process in the dark. The direct aziridination
Onnicha Khaikate   +5 more
wiley   +1 more source

Synthesis of Oligo‐Sulfonimidates by Exponential Growth via Sulfur‐Phenolate Exchange Reactions

open access: yesChemistryEurope, EarlyView.
A highly flexible iterative exponential growth strategy is used in combination with the sulfur‐phenolate exchange reaction to develop sequence‐defined oligosulfonimidates (16 mer). Combining this with sulfur‐fluorine exchange‐based iterative step growth, a bespoke 20 mer (Mw = 8.5 kDa) can be synthesized.
Yu Han   +5 more
wiley   +1 more source

THE HYDROLYSIS OF BIOTIN SULFONE

open access: hybrid, 1942
Donald B. Melville   +2 more
openalex   +1 more source

Methyl on the Bridge: 2‐Methyl Propellane as Precursor for 1,3‐Substituted 2‐Methylated Bicyclo[1.1.1]Pentanes

open access: yesChemistry – A European Journal, EarlyView.
The synthesis of 2‐methyl propellane and its conversion to various 1,2‐ and 1,2,3‐di‐ and trisubstituted bicyclopentanes is reported. Abstract Bicyclo[1.1.1]pentanes (BCPs) have emerged as isosteric replacements for mono‐ and para‐substituted benzene rings in medicinal and materials applications, involving substitution at the BCP bridgehead (1,3 ...
Sean R. Verschaeve   +4 more
wiley   +1 more source

Home - About - Disclaimer - Privacy