Results 51 to 60 of about 60,682 (387)

Urea–hydrogen peroxide prompted the selective and controlled oxidation of thioglycosides into sulfoxides and sulfones

open access: yesBeilstein Journal of Organic Chemistry, 2017
A practical method for the selective and controlled oxidation of thioglycosides to corresponding glycosyl sulfoxides and sulfones is reported using urea–hydrogen peroxide (UHP). A wide range of glycosyl sulfoxides are selectively achieved using 1.5 equiv
Adesh Kumar Singh   +4 more
doaj   +1 more source

Membrane-free selective oxidation of thioethers with water over a nickel phosphide nanocube electrode

open access: yesCell Reports Physical Science, 2021
Summary: Developing a membrane-free oxidation reaction, especially using water as the oxygen source, to generate high-value chemicals with high selectivity for replacing low-value O2 over a cost-effective catalyst is significant.
Shuyan Han   +6 more
doaj   +1 more source

Iodine-Mediated Difunctionalization of Imidazopyridines with Sodium Sulfinates: Synthesis of Sulfones and Sulfides.

open access: yesJournal of Organic Chemistry, 2018
Novel iodine-induced sulfonylation and sulfenylation of imidazopyridines have been described using sodium sulfinates as the sulfur source. This strategy enables highly selective difunctionalization of imidazo[1,2-a]pyridine to access sulfones and ...
Yu-Jing Guo   +7 more
semanticscholar   +1 more source

THE DANGERS OF SULFONAL [PDF]

open access: yesThe Journal of Nervous and Mental Disease, 1891
n ...
openaire   +1 more source

Acetoacetate based thermosets prepared by dual-Michael addition reactions [PDF]

open access: yes, 2019
A novel set of dual-curable multiacetoacetate-multiacrylate-divinyl sulfone ternary materials with versatile and manipulable properties are presented.
Fernández Francos, Xavier   +3 more
core   +2 more sources

Deciphering the Origin of Higher Shell Coordination on Single Iron Catalysts for Resilient Modulating Persulfate Oxidation Into Singlet Oxygen Pathway

open access: yesAdvanced Functional Materials, Volume 35, Issue 12, March 18, 2025.
This study reveals that higher shell S coordination can effectively modulate the spin state of FeN4 site via long‐range electronic interactions, giving rise to the oriented generation of singlet oxygen from peroxymonosulfate activation. Abstract Precise manipulation of coordination structure of single‐atom sites and establishment of schematic ...
Liang Zhang   +8 more
wiley   +1 more source

Influence of Sulfoxide Group Placement on Polypeptide Conformational Stability. [PDF]

open access: yes, 2019
The synthesis of a homologous series containing five new nonionic sulfoxide containing polypeptides was described. Sulfoxide groups bestowed water solubility for all homologues, which allowed their use as a model for study of helix-coil transitions in ...
Bahrun, Ehab   +2 more
core  

Highly-functionalised difluorinated cyclohexane polyols via the Diels–Alder reaction : regiochemical control via the phenylsulfonyl group [PDF]

open access: yes, 2005
A difluorinated dienophile underwent cycloaddition reactions with a range of furans to afford cycloadducts whichcould be processed regio- and stereoselectively via episulfonium ions, generated by the reaction between their alkenyl groups and ...
Crowley, Patrick J   +5 more
core   +1 more source

Ideal Molecular Sieving with a Dense MOF for Helium Upgrading with Highly Diffusion Selective Mixed Matrix Membranes

open access: yesAdvanced Functional Materials, EarlyView.
The separation of Helium gas from natural gas is challenging but highly important. MIL‐116(Ga), a “non‐porous” metal–organic framework is used as a molecular sieve to separate He from CH4. Druse‐like MIL‐116(Ga) particles are integrated into polysulfone mixed matrix membranes.
Ayisha Komal   +10 more
wiley   +1 more source

Potential peptidic proteasome inhibitors by incorporation of an electrophilic trap based on amino acid derived α-substituted sulfonyl fluorides [PDF]

open access: yes, 2017
Peptido sulfonyl fluoride derivatives were designed and synthesized containing a substituent on the alpha position (αPSFs) with respect to the sulfonyl fluoride electrophilic trap.
Brouwer, Arwin J.   +3 more
core   +1 more source

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