Results 101 to 110 of about 33,864 (335)

Fibrous Pb(II)‐Based Coordination Polymer Operable as a Photocatalyst and Electrocatalyst for High‐Rate, Selective CO2‐to‐Formate Conversion

open access: yesAdvanced Functional Materials, EarlyView.
A coordination polymer [Pb(tadt)]n prepared by a microwave‐assisted solvothermal method selectively reduces CO2 into formate under visible light with a high apparent quantum yield of ≈25% at 400 nm. It can function as a pre‐catalyst, along with conductive Ketjen Black, to form an active PbCO3/Pb3(CO3)2(OH)2 mixture that exhibits a high Faradaic ...
Chomponoot Suppaso   +8 more
wiley   +1 more source

Time‐Controlled Dual Targeting to Program Systemic and Intercellular Transfer of Therapeutic Effects

open access: yesAdvanced Functional Materials, EarlyView.
Aspirin‐liposomes loaded onto monocytes enable inflammation‐triggered targeting and efficient hand‐over of aspirin to inflamed cells. Monocytes uptake a significant portion of aspirin‐liposomes, prolonging therapeutic action. This approach enhances anti‐inflammatory effects through intercellular transfer, demonstrating a translational strategy for ...
Seung Eun Yu   +6 more
wiley   +1 more source

Enantioseparation of Alkylaryl Sulfoxides Using Capillary Zone Electrophoresis [PDF]

open access: yes, 1999
Alkylaryl sulfoxides possess a chiral sulfur atom easily identifiable by capillary zone electrophoresis (CZE). Separation of chiral alkylaryl sulfoxides has already been accomplished by modified method of CZE known as micellar electrokinetic ...
Snyder, Chad
core   +1 more source

Versatile C(sp2)−C(sp3) ligand couplings of sulfoxides for the enantioselective synthesis of diarylalkanes [PDF]

open access: yes, 2016
The reaction of chiral (hetero)aryl benzyl sulfoxides with Grignard reagents affords enantiomerically pure diarylalkanes in up to 98% yield and greater than 99.5% enantiomeric excess.
Aggarwal   +72 more
core   +2 more sources

Wetting of Surface Grafted Hydrophilic‐b‐Hydrophobic Block Copolymer Brushes

open access: yesAdvanced Functional Materials, EarlyView.
The wetting properties of surface grafted diblock copolymer brushes are influenced by the thickness of the hydrophilic bottom block and the hydrophobic top block. The surface adapts in presence of water and the contact angles of the bottom block shine through. Abstract The wetting of diblock copolymer brushes by water is studied.
Benjamin Leibauer   +7 more
wiley   +1 more source

Unlocking High‐Performance in All‐Organic Solar Cells by the Development of Organic Electrodes with No Acid and High‐Temperature Treatment and the Effective Preparation Thereof on Organic Multilayer Films

open access: yesAdvanced Functional Materials, EarlyView.
The developed all‐organic solar cells achieve a power conversion efficiency of 8.7%, more than double the previous record. In addition, bioplastic substrates are used to produce environmentally friendly solar cells with an efficiency of 8.6%. These results are achieved by developing high‐performance organic electrodes without acid doping or high ...
Keiju Hashida   +12 more
wiley   +1 more source

Ring Contracting Sulfur Extrusion from Oxidized Phenothiazine Ring Systems

open access: yesMolecules, 2008
Lithium, used in conjunction with sodium metal, produces a high yield of carbazole when reacted with phenothiazine-5-oxide or phenothiazine-5,5-dioxide.
Seth H. Berg, Steven C. Farmer
doaj   +1 more source

Post-functionalization of dibenzothiophene to functionalized biphenyls via a photoinduced thia-Baeyer-Villiger oxidation

open access: yesNature Communications, 2020
The development of thia-Baeyer-Villiger reactions has been elusive so far due to competitive oxidation of sulfoxides to sulfones. Here, the authors show a thia-Baeyer-Villiger-type oxidations converting dibenzothiophene derivatives into sulfinic esters ...
Xiaofeng Ma   +4 more
doaj   +1 more source

Low temperature dielectric relaxation study of aqueous solutions of diethylsulfoxide

open access: yes, 2014
In the present work, dielectric spectra of mixtures of diethylsulfoxide (DESO) and water are presented, covering a concentration range of 0.2 - 0.3 molar fraction of DESO.
Gabrielyan, L.   +3 more
core   +1 more source

Investigation of the chemoselective and enantioselective oxidation of α-thio-β-chloroacrylamides [PDF]

open access: yes, 2008
Investigation of the chemoselective and enantioselective oxidation of α-thio-β-chloroacrylamides is described. The α-thio-β-chloroacrylamides can be selectively oxidized to either the racemic sulfoxide or the sulfone very efficiently.
Chopra, Jay   +4 more
core   +1 more source

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