A new type of coordination polymer has been discovered while looking for high‐performance, insensitive secondary explosives. This polymer made of scarce imidoyl azide structures, demonstrates interesting pyrotechnic characteristics like a density greater than 2.00 g.cm−3 and great insensitivity towards thermal and mechanical stresses.
Lucas Blanck+4 more
wiley +1 more source
Diving into the Shielding Surfaces: Construction of Atropisomeric Axes via Multicomponent Reactions
We successfully designed and synthesized a diverse library of atropisomeric molecular systems using a scaffold hopping strategy based on the GBB‐3CR. Structural and computational analyses revealed key CH⋅⋅⋅π and π⋅⋅⋅π interactions, aromatic shielding effects, and conformational dynamics, providing insights into their potential biological relevance ...
Michael Fragkiadakis+5 more
wiley +1 more source
Recent Advances in the α‐Hydrazination (α‐Amination) of Carbonyl Compounds
In recent years, notable progress has been achieved in the α‐hydrazination (α‐amination) of carbonyl compounds, especially in the direct asymmetric electrophilic α‐hydrazination with dialkyl azodicarboxylates. This review summarizes all the methods that appeared over the past decade, categorized based on the type of the reactive chiral intermediate ...
Dina Scarpi+2 more
wiley +1 more source
Fluorinated Organic Porous Materials
Fluorine is in many aspects unique among the elements, and its incorporation into organic molecules can dramatically change their physical and chemical properties.
Zhenglin Zhang, Ognjen Š. Miljanić
doaj +1 more source
A Facile Synthesis of 2,5-Disubstituted Tetrazoles by the Reaction of Phenylsulfonylhydrazones with Arenediazonium Salts [PDF]
Suketaka Ito+3 more
openalex +1 more source
The Formation of Tin-Nitrogen Bonds. V. The Selective 1-Substitution Reaction of Tetrazoles by the Reaction of 5-Substituted 2-(Tri-n-butylstannyl)tetrazoles with Methyl Iodide, Methylp-Toluenesulfonate, Dimethyl Sulfate, and Ethyl Bromoacetate [PDF]
Tyûzô Isida+4 more
openalex +1 more source
Supramolecular chemistry provides possibilities in organic synthesis by harnessing dynamic environments of crystalline solids for controlled covalent bond formation, highlighting potential as a form of supramolecular matter for precise molecular synthesis.
Changan Li, Leonard R. MacGillivray
wiley +1 more source
ZNCL2/ALCL3/SILICA (ZAS) AS AN EFFECTIVE HETEROGENEOUS CATALYST FOR THE SYNTHESIS OF 5-RYLOXYTETRAZOLES [PDF]
A simple and efficient method for preparation of 5-aryloxy tetrazoles (3a-h) from arylcyanates (1a-h) with using ZnCl2/AlCl3/silica (ZAS) as an effective heterogeneous catalyst in solvent free are described with excellent yields and high purity. The rate
F. Khamooshi, B. H. K. Jhaleh
doaj
c. Steroidal tetrazoles: ring B fused tetrazoles in the cholestane series [PDF]
MS Ahmad, ZH Chaudhry, PN Khan
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The Reaction between 5-(p-Toluenesulfonamido)tetrazole and p-Toluenesulfonyl Chloride. [PDF]
Kai Jensen+5 more
openalex +1 more source