A Synthetic Route Toward Tetrazoles: The Thermolysis of Geminal Diazides
A new synthetic route toward the tetrazole core is described, which is based on a general fragmentation pattern that was found in a range of compounds featuring geminal diazido units.
K. Holzschneider +3 more
semanticscholar +1 more source
Back to the Electrofuture: Named Reactions Powered by Electroorganic Syntheses
Bridging classical named reactions with modern electroorganic chemistry, this review presents how electrochemical strategies can revive and reinterpret historically significant transformations, highlighting their emerging potential as sustainable alternatives in contemporary organic synthesis.
Debajit Maiti +4 more
wiley +1 more source
Intramolecular [3+2] Cycloaddition of Fused Azolo-Azepanes from Azido Monosaccharides Derivatives [PDF]
Síntesis de bicíclicos compuestos empleando epoxiamidas como material de partida. Obtención de tetrazolo azepanos con posible actividad biológica.Universidad de Málaga.
Calvo-Losada, Saturnino +3 more
core
A facile route for the synthesis of novel S-linked 1,3,5-triazine tethered peptidomimetics [PDF]
An efficient one-pot synthesis of Nα-protected S-linked 1,3,5-triazine tethered peptidomimetics is described. The protocol involves a three-component condensation reaction employing Nα-protected amino alkyl isothiouronium salt, formaldehyde and amino ...
Basavaprabhu, . +3 more
core +1 more source
We synthesized photocaged, clickable and isotope‐labeled “magic spot” Nucleotides and delivered them into Escherichia coli comparing different approaches. Light‐controlled release inside living cells enabled tracking of their conversion from pppGpp to ppGpp by capillary electrophoresis mass spectrometry and revealed their impact on the growth rate of a
Christoph Popp +12 more
wiley +1 more source
Metal-assisted reactions. Part 25. Heterogeneous and homogeneous catalytic transfer hydrogenolysis of allyloxytetrazoles to yield alkenes or alkanes [PDF]
Transfer hydrogenolysis of 5-allyloxy- 1-phenyltetrazoles using either a heterogeneous or a homogeneous palladium catalyst and a hydrogen donor leads to cleavage of the allyloxy C-O bond to yield an alkane or an alkene and 1-phenyltetrazolone, depending ...
Cristiano, Maria Lurdes Santos +2 more
core +1 more source
Sodium azide or trimethylsilylazide react with N,N-dimethylphosgenimonium chloride by monosubstitution yielding N,N-dimethyl-azidochloromethylen-imonium chloride which can be isolated.
H.G. Viehe, P. George
doaj +1 more source
MMP-13 Selective α-sulfone Hydroxamates: a Survey of P1\u27 Heterocyclic Amide Isosteres [PDF]
Seeking compounds preferentially potent and selective for MMP-13, we reported in the preceding Letter on a series of hydroxamic acids with a flexible benzamide tail groups.(1a) Here, we replace the amide moiety with non-hydrolyzable heterocycles in an ...
Barta, Thomas E. +3 more
core
Controlled Delivery and Light‐Induced Release of Magic Spot Nucleotides in Escherichia coli
We synthesized photocaged, clickable and isotope‐labeled “magic spot” Nucleotides and delivered them into Escherichia coli comparing different approaches. Light‐controlled release inside living cells enabled tracking of their conversion from pppGpp to ppGpp by capillary electrophoresis mass spectrometry and revealed their impact on the growth rate of a
Christoph Popp +12 more
wiley +1 more source
ChemInform Abstract: Synthesis of Boc‐Amino Tetrazoles Derived from α‐Amino Acids [PDF]
ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option ...
Nagendra, G. +2 more
core +1 more source

