Results 91 to 100 of about 80,380 (385)

Nitrirung des Thiophens [PDF]

open access: yesBerichte der deutschen chemischen Gesellschaft, 1884
n ...
Meyer, Victor, Stadler, Otto
openaire   +2 more sources

Microstructural Evolution Dominates the Changes in the Thermal Conductivity of Conjugated Polymers Upon Doping

open access: yesAdvanced Functional Materials, EarlyView.
The relationship between the doping induced microstructure and thermal conductivity changes is elucidated for conjugated polymers. Eight conjugated polymers with different doping systems are studied, showing varied thermal conductivity responses based on structural order.
Jiali Guo   +13 more
wiley   +1 more source

Hindered aryl bromides for regioselective palladium-catalysed direct arylation at less favourable C5-carbon of 3-substituted thiophenes

open access: yesBeilstein Journal of Organic Chemistry, 2014
The use of the congested aryl bromide 2-bromo-1,3-dichlorobenzene as coupling partner allows to modify the regioselectivity of the arylation of 3-substituted thiophene derivatives in favour of carbon C5.
Rongwei Jin   +2 more
doaj   +1 more source

3,5-Bis(4-dodecylthiophen-2-yl)-4H-1,2,6-thiadiazin-4-one

open access: yesMolbank, 2012
3,5-Dichloro-4H-1,2,6-thiadiazin-4-one 1 reacts with (4-dodecylthiophen-2-yl)trimethylstannane 4 (2.2 equiv.) and Pd(Ph3P)2Cl2 (5 mol%) in acetonitrile at ca. 82 °C to give 3,5-bis(4-dodecylthiophen-2-yl)-4H-1,2,6-thiadiazin-4-one 5 in 93% yield.
Panayiotis A. Koutentis   +1 more
doaj   +1 more source

Rhodium Thiavinyl Carbenes from 1,2,3-Thiadiazoles Enable Modular Synthesis of Multisubstituted Thiophenes.

open access: yesOrganic Letters, 2016
The rhodium-catalyzed transannulation reaction between 1,2,3-thiadiazoles and alkynes, proceeding via intermediacy of the previously unknown Rh thiavinyl carbene, toward a highly efficient and regioselective synthesis of up to fully substituted ...
D. Kurandina, V. Gevorgyan
semanticscholar   +1 more source

Polar Diels-Alder Reactions using Heterocycles as Electrophiles. Influence of Microwave Irradiation [PDF]

open access: yes, 2015
In this work we studied a series of polar Diels-Alder reactions using different heterocycles derivatives acting as electrophiles joint to dienes of different nucleophilicity, analyzing the effect of the microwave irradiation in these processes. We employ
Della Rosa, Claudia Daniela   +3 more
core   +1 more source

Enhancing Mechanical Deformability of Rigid Conjugated Polymers through Functional Additive‐Induced Persistence Length Modulation

open access: yesAdvanced Functional Materials, EarlyView.
This study demonstrates a molecular strategy to enhance the stretchability of conjugated polymers by incorporating plasticizing molecular additives (PMAs). PMAs reduce the persistence length and promote chain entanglement, enabling deformable thin films with preserved electrical performance. A systematic analysis combining rheology, neutron scattering,
Sein Chung   +11 more
wiley   +1 more source

Synthesis of pyrrolizines by intramolecular capture of 1,4-dipolar intermediates in reactions of enamines with dimethyl acetylenedicarboxylate [PDF]

open access: yes, 1981
Solvent polarity and reaction temperature strongly influence the reactions of dimethyl acetylenedicar-boxylate (DMAD) with 1-pyrrolidinyl enamines of acyclic and cyclic ketones. Whereas DMAD and 1-[1-phenyl-2-(phenylthio)ethenyl]pyrrolidine (3) give only
Harkema, S.   +5 more
core   +3 more sources

Sensing of Chloride Ions in Sweat by Means of Printed Extended‐Gate Organic Electrochemical Transistors

open access: yesAdvanced Functional Materials, EarlyView.
In this work, a platform based on an Extended‐Gate OECT is successfully developed and tailored for the detection of physiologically relevant chloride ion concentrations in artificial eccrine sweat. Leveraging the extended‐gate architecture, a high‐performance OECT based on inkjet‐printed pg2T‐TT is coupled with an inkjet‐printed Ag/AgCl electrode ...
Cristiano Bortolotti   +7 more
wiley   +1 more source

Rh(II)-mediated domino [4 + 1]-annulation of α-cyanothioacetamides using diazoesters: A new entry for the synthesis of multisubstituted thiophenes

open access: yesBeilstein Journal of Organic Chemistry, 2017
A new approach towards the synthesis of multisubstituted thiophenes is elaborated based on Rh(II)-catalyzed domino reactions of acyclic diazoesters with α-cyanothioacetamides.
Jury J. Medvedev   +5 more
doaj   +1 more source

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