Results 91 to 100 of about 28,423 (282)

Acidogenesis‐Propelled Coordination Transition in Light‐Triggered Fe‐Polyphenol Polymer for Reactive Oxygen Species‐Augmented Antitumor Therapy

Advanced Science, EarlyView.
A novel iron‐polyphenol‐photoacid coordination polymer (FeBPs) is designed to achieve red light‐triggered external acidification and internal coordination regulation, where this light‐controlled acidification induces coordination changes that enhance Fe active site exposure and provide H+ for beneficial Fe3+/Fe2+ conversion, thereby accelerating ROS ...
Ying Wan, Hui Liu, Lin Gao, Guanyu Tan, Kailin Li, Qiwei Tian, Shiping Yang, Lu An   +7 more
wiley   +1 more source

Insect I‐Type Lysozymes Function as Antiviral Proteases by Forming Biomolecular Condensates

Advanced Science, EarlyView.
Upon rice viral infection, the insect vector activates the Toll–MyD88–Dorsal signaling cascade, inducing i‐type lysozyme (Lyz‐I1) expression. Lyz‐I1 functions as an antiviral protease through its conserved catalytic dyad Glu/Asp (E/D), mediating cleavage of viral proteins at specific Lys (K) residues.
Yu Du, Yuqing Xiao, Manman Hu, Jinhua Yang, You Li, Taiyun Wei   +5 more
wiley   +1 more source

Restoring Porosity and Uncovering Flexibility in Pillared 3D‐Linker Metal‐Organic Frameworks

Angewandte Chemie, EarlyView.
This research explores new design approaches towards robust frameworks which retain structural flexibility and porosity after activation. By incorporating bulky 3D‐linkers as anionic pillars with zinc triazolate sheets, moisture‐stable metal‐organic frameworks (MOFs) are synthesized. In situ powder X‐ray diffraction and gas adsorption techniques reveal
Sophie A. Booth, Volodymyr Bon, Connor W. Edwards, G. Paul Savage, Jack D. Evans, Stefan Kaskel, Lauren K. Macreadie   +6 more
wiley   +2 more sources

Coordination‐Locked Engineering to Achieve Narrowband Room Temperature Phosphorescence in Non‐Rare Earth Metal–Organic Frameworks

Advanced Science, EarlyView.
In this contribution, the coordination‐locked phosphorescence amplification (CLPA) strategy is developed to successfully construct the first non‐rare‐earth narrowband RTP MOF crystal, Sr–tbc. In addition, Sr–tbc shows potential applications in high‐resolution afterglow display and multilevel information recognition.
Wenlei Zhang, Jinpeng Li, Mengyao Wang, Yining Zhao, Xi Zhang, Hongfeng Li, Jing Liu, Tianyang Li, Meng Zhang, Fei Chen, Zhongyi Liu, Chao Lu   +11 more
wiley   +1 more source

Synthesis of 5‐(1 ‐naphthylmethyl)‐4‐aryl‐s‐triazole‐3‐thiol/yl‐thioglycolic acids as possible anti‐inflammatory agents [PDF]

, 1978
P Kothari, V. Kishore, Virgil I. Stenberg, Surendra S. Parmar   +3 more
openalex   +1 more source

Solvated Electron‐Driven Stepwise ORR on Na‐Metalated N‐Rich Carbon Nitride for Efficient Photocatalytic H2O2 Production

Advanced Science, EarlyView.
A sodium‐metalated, nitrogen‐rich carbon nitride (PH‐C3N5‐Na) is developed to generate solvated electrons (SEs) under visible‐light irradiation via a eutectic NaCl/LiCl molten salt‐assisted method. The in situ generated SEs drive a stepwise oxygen reduction via •O2−. Thus, an exceptional quantum efficiency of 54.4% (420 nm) is achieved.
Jianan Feng, Weilin Qin, Li Shangguan, Hui Zhang, Jianhua Sun, Shunping Sun, Yu Guo, Weiwei Lei   +7 more
wiley   +1 more source

Computational Study of Ignored Pericyclic Reactions: Rearrangements of 1,2‐Bis(Diazo)Alkanes to 1,2,3,4‐Tetrazines and Subsequent Fragmentations

Angewandte Chemie, EarlyView.
DFT calculations of the 8π‐electrocyclization of 1,2‐bis(diazo)alkanes and of other bis‐1,3‐dipoles reveal that this process can establish a so far ignored route to heterocycles such as 1,2,3,4‐tetrazines. Alternative reaction channels via carbenes or nitrenes leading to fragmentation products are discussed.
Hans‐Ulrich Reissig, Ernst‐Ulrich Würthwein   +1 more
wiley   +2 more sources

The Reaction of 4-Substituted Thiosemicarbazides with Phenyl Isocyanide. 1,3,4-Thiadiazoles and 1,2,4-Triazoles. [PDF]

, 1977
Svend Treppendahl, Palle Jakobsen, Jan-Bjørn Osnes, Povel N. Paus, Farouk S. El‐Feraly, Jan-Erik Berg, Anne‐Marie Pilotti   +6 more
openalex   +1 more source

Vacuum Thermal Evaporation for OLEDs: Fundamentals, Optimization, and Implications for Perovskite LEDs

Advanced Electronic Materials, EarlyView.
Vacuum thermal evaporation (VTE) is the dominant method for manufacturing high‐performance small‐molecule organic light‐emitting diodes (OLEDs). Its mature application in OLEDs offers valuable guidance for emerging perovskite light‐emitting diodes (PeLEDs).
Chenxi Shen, Ying Hu, Siqian Zhou, Ziquan He, Junchao Han, Daquan Zhang, Lei Lu, Xiaoliang Mo, Qianpeng Zhang   +8 more
wiley   +1 more source

Structural Dependence of Catenand Effect: Thermodynamic and Kinetic Modulation of Catenane Coordination Properties via Ring‐size and Exocyclic Substituent Variation

Angewandte Chemie, EarlyView.
By modifying ring size and exocyclic substituents, effects of ligand interlocking on metal coordination features is explored. Through systematic analysis of CuI catenanes, relationship between structural parameters of the interlocked ligands and coordination properties like geometry, stability, and reactivity is established.
Yulin Deng, Zi‐Gang Lu, Samuel Kin‐Man Lai, Man Pang Tang, Xiaoyong Mo, Shan He, David Lee Phillips, Edmund Chun Ming Tse, Ho Yu Au‐Yeung   +8 more
wiley   +2 more sources