Results 41 to 50 of about 4,641 (228)

1H NMR determination of the self-association of an acridine homodimer and its complexation with ethidium bromide in aqueous solution [PDF]

open access: yes, 2006
1H NMR spectroscopy (500MHz) has been used to investigate the self-association in aqueous buffered solution of a bis-intercalator, Acridine Homodimer (AcrH), and its hetero-association with the aromatic dye, Ethidium Bromide (EB).
Barbet   +22 more
core   +1 more source

Deprotonative C(sp3)/C(sp2)–H (Multi)Silylation of (Hetero)Arenes Mediated by NaTMP

open access: yesAngewandte Chemie, EarlyView.
An operationally simple protocol using a strongly basic sodium amide in combination with sterically emcumbered silicon electrophiles enables the deprotonative C–H (multi)silylation of a myriad of (hetero)arenes. Mechanistic investigations highlight the pivotal role of steric and coordination effects in controlling the regioselectivity and efficiency of
David Sánchez‐Roa   +6 more
wiley   +2 more sources

Acridine–Isoxazole and Acridine–Azirine Hybrids: Synthesis, Photochemical Transformations in the UV/Visible Radiation Boundary Region, and Anticancer Activity

open access: yesMolecules
Easy-to-handle N-hydroxyacridinecarbimidoyl chloride hydrochlorides were synthesized as convenient nitrile oxide precursors in the preparation of 3-(acridin-9/2-yl)isoxazole derivatives via 1,3-dipolar cycloaddition with terminal alkynes, 1,1 ...
Ekaterina E. Galenko   +3 more
doaj   +1 more source

Synthesis of new Bis- and Tetra-Acridines

open access: yesMolecules, 2001
A new series of bis- and tetra-acridines has been prepared from 4-(bromomethyl) acridine; some of them exhibited encouraging in vitro cytotoxic activities against murine cell lines.
Jean-Pierre Galy   +3 more
doaj   +1 more source

Comparing Fragmentation Trees from Electron Impact Mass Spectra with Annotated Fragmentation Pathways [PDF]

open access: yes, 2012
Electron impact ionization (EI) is the most common form of ionization for GC-MS analysis of small molecules. This ionization method results in a mass spectrum not necessarily containing the molecular ion peak.
Böcker, S., Hufsky, F.
core   +2 more sources

Crystals as Rockets: Modulation of the Salient Temperature in Cocrystals by Solvent Mixture Composition

open access: yesAngewandte Chemie, EarlyView.
Compositionally engineered mixed solvated cocrystals enable modulation of thermosalient actuation. Guest ratio controls thermosalient temperature and propulsion intensity, providing a tunable platform for designing crystalline systems that exhibit stimuli‐responsive mechanical motion.
Ernesto A. Hernández‐Morales   +5 more
wiley   +2 more sources

Role of the Recombination Zone in Organic Light‐Emitting Devices

open access: yesAdvanced Materials, EarlyView.
This review summarizes the critical role of the recombination zone in organic light‐emitting diodes (OLEDs). We highlight that broadening the recombination zone in OLEDs based on emissive layers with balanced charge transport and high photoluminescence quantum yields provides a promising route toward achieving both long operational lifetime and high ...
Yungui Li, Karl Leo
wiley   +1 more source

Acceptorless Dehydrogenative Polymerization

open access: yesAngewandte Chemie, EarlyView.
Acceptor‐less dehydrogenative polymerization (ADP) enables the atom‐economic step‐growth synthesis of different type of polymers directly from simple alcohols, releasing H2 as the sole by‐product. This review outlines the mechanistic foundations, catalytic systems, and emerging polymer architectures of ADP, highlighting its potential as a sustainable ...
Xin Liu   +2 more
wiley   +2 more sources

Novel acridine-based thiosemicarbazones as ‘turn-on' chemosensors for selective recognition of fluoride anion: a spectroscopic and theoretical study [PDF]

open access: yesRoyal Society Open Science, 2018
New thiosemicarbazide-linked acridines 3a–c were prepared and investigated as chemosensors for the detection of biologically and environmentally important anions. The compounds 3a–c were found selective for fluoride (F−) with no affinity for other anions,
Ibanga Okon Isaac   +9 more
doaj   +1 more source

The gentisic acid-based deep eutectic solvent mediated green synthesis of acridines

open access: yesCatalysis Communications, 2023
A novel gentisic acid-based deep eutectic solvent (ETPPBr/GA-DES) was prepared by mixing of ethyltriphenylphosphonium bromide (ETPPBr) and gentisic acid (GA = 2,5-dihydroxy-benzoic acid), and its structure fully investigated by using the FT-IR, TGA/DTA ...
Hadis Goudarzi   +2 more
doaj   +1 more source

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