Results 1 to 10 of about 104,315 (284)

Metal-free visible-light-enabled vicinal trifluoromethyl dithiolation of unactivated alkenes

open access: yesBeilstein Journal of Organic Chemistry, 2021
The difunctionalization of alkenes involving a trifluoromethylthio group (SCF3) for the conversion of versatile and readily available olefins into structurally more complex molecules has been successfully studied.
Xiaojuan Li   +5 more
doaj   +1 more source

Synthesis of Dibenzylbutane and 9,8′-Neo-Lignans via Cyclometalation of Allylbenzene by EtAlCl2 and Mg in the Presence of Zr ansa-Complexes

open access: yesChemistry Proceedings, 2021
The aim of the research is the development of a one-pot method for the synthesis of lignans, natural compounds that show a wide spectrum of biological activities.
Pavel V. Kovyazin   +3 more
doaj   +1 more source

From‐Neutral‐to‐Neutral Reductive Radical Coupling of Non‐Activated Alcohols and Styrenes

open access: yesChemistryEurope, 2023
A reductive radical coupling reaction between non‐activated aliphatic alcohols and styrenes has been discovered through the use of low‐valent Ti‐mediated C−O bond homolysis.
Dr. Takuya Suga   +2 more
doaj   +1 more source

Alkene-oxo and alkene-alkene coupling on Pt(II) [PDF]

open access: yes, 2021
Tetranuclear Pt(II) oxo-complex [(COD)4Pt4([mu]3-O)2Cl2](BF4)2 (1) (COD = 1,5- cyclooctadiene) was found to readily react with a variety of alkenes (ethylene, norbornene, propylene and cyclopentene). The most significant discovery resulted from the norbornene reaction, which gave platinaoxetane [(COD)2Pt2(OC7H10)Cl]BF4 (4), the first metallaoxetane ...
openaire   +2 more sources

Trifluoromethanesulfonamide vs. Non-Fluorinated Sulfonamides in Oxidative Sulfamidation of the C=C Bond: An In Silico Study

open access: yesMolecules, 2020
A theoretical analysis of the reaction of oxidative sulfamidation of several alkenes was performed in order to explain the various experimental observations and different reactivity of triflamide and non-fluorinated sulfonamides.
Anton V. Kuzmin   +2 more
doaj   +1 more source

Iron(III)-Mediated Rapid Radical-Type Three-Component Deuteration of Quinoxalinones With Olefins and NaBD4

open access: yesFrontiers in Chemistry, 2020
Iron(III)-promoted rapid three-component deuteration of quinoxalinones with olefins and NaBD4 is reported for the first time, which provides a novel, economic, and efficient method for the rapid synthesis of deuterated quinoxalinones.
Wanmei Li   +6 more
doaj   +1 more source

Metal-Free Direct C–H Functionalization of Quinoxalin-2(1H)-Ones to Produce 3-Vinylated Quinoxalin-2(1H)-Ones in the Presence of Alkenes

open access: yesFrontiers in Chemistry, 2021
A novel and efficient C3-H vinylation reaction with quinoxalin-2(1H)-one as the substrate, in the presence of alkenes, under metal-free conditions, is reported herein.
Rongcai Ding   +6 more
doaj   +1 more source

Enantioselective Hydrogenations with Chiral Titanocenes

open access: yesMolecules, 2005
In this review article chiral titanocenes and their application for the enantioselective hydrogenations of different unsaturated compounds are discussed, with a special emphasis on the kinetics and the practicality of the developed systems. The nature of
J. Khinast, A. Panarello, O. Vassylyev
doaj   +1 more source

Analysis of Oleogel Volatile Profile Formation under Ultrasonic Treatment

open access: yesGels, 2023
Under certain conditions, ultrasonic treatment of certain foods and ingredients can contribute to the appearance of an extraneous odor, which is not usual for them, especially in fat-containing products.
Yuliya Frolova   +2 more
doaj   +1 more source

Alternative pathways to α,β-unsaturated ketones via direct oxidative coupling transformation using Sr-doped LaCoO3 perovskite catalyst [PDF]

open access: yesRoyal Society Open Science, 2019
A strontium-doped lanthanum cobaltite perovskite material was prepared, and used as a recyclable and effective heterogeneous catalyst for the direct oxidative coupling of alkenes with aromatic aldehydes to produce α,β-unsaturated ketones.
Khang H. Trinh   +7 more
doaj   +1 more source

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