Hydrosilylation of 1-alkenes with dichlorosilane [PDF]
, 1995 Symmetrically and unsymmetrically substituted diorganodichlorosilanes have been prepared by hydrosilylation with dichlorosilane using two different platinum catalysts, i.e., hexachloroplatinic acid (Speier's catalyst) and a platinum ...
Frey, Holger +4 more
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Thermochemical study of the addition of carbenium ions to alkenes [PDF]
, 1988 Arnett, Edward M. +2 more
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Iodoaminations of Alkenes [PDF]
Synthesis, 2016 The activation of alkenes and their subsequent functionalization is a frequently used methodology in synthetic chemistry. This review highlights recent iodine-mediated aminations and elaborates on the various strategies to bring about regio- or stereoselective transformations.
Pushpak Mizar, Thomas Wirth
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Tethered Silanoxyiodination of Alkenes [PDF]
The Journal of Organic Chemistry, 2021 We present the first examples of tethered silanoxyiodination reactions of allylic alcohols. The products are usefulsilanediol organoiodide synthons and are formed with high regioselectivity and diastereocontrol. The reaction is scalable greater than 10-fold without loss of yield or selectivity.
Ranjeet A. Dhokale +4 more
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Visible-light promoted atom transfer radical addition-elimination (ATRE) reaction for the synthesis of fluoroalkylated alkenes using DMA as electron-donor [PDF]
, 2020 Here, we describe a mild, catalyst-free and operationally-simple strategy for the direct fluoroalkylation of olefins driven by the photochemical activity of an electron donor-acceptor (EDA) complex between DMA and fluoroalkyl iodides.
Gu, Jiwei +5 more
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Alkene-oxo and alkene-alkene coupling on Pt(II) [PDF]
, 2021 Tetranuclear Pt(II) oxo-complex [(COD)4Pt4([mu]3-O)2Cl2](BF4)2 (1) (COD = 1,5- cyclooctadiene) was found to readily react with a variety of alkenes (ethylene, norbornene, propylene and cyclopentene). The most significant discovery resulted from the norbornene reaction, which gave platinaoxetane [(COD)2Pt2(OC7H10)Cl]BF4 (4), the first metallaoxetane ...
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Glycerol as a cheap, safe and sustainable solvent for the catalytic and regioselective β,β-diarylation of acrylates over palladium nanoparticles [PDF]
, 2010 Herein we show that glycerol can be considered as a promising cheap and green solvent for the regioselective β,β-diarylation of alkenes. Whereas this reaction is generally catalyzed under an inert atmosphere by expensive phosphine or carbene-palladium ...
Barrault, Joel +7 more
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Intramolecular carbonickelation of alkenes [PDF]
Beilstein Journal of Organic Chemistry, 2013 The efficiency of the intramolecular carbonickelation of substituted allylic ethers and amines has been studied to evaluate the influence of the groups borne by the double bond on this cyclization. The results show that when this reaction takes place, it affords only the 5-exo-trig cyclization products, viz. dihydrobenzofurans or indoles.
Lhermet, Rudy +2 more
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Recent Advances in the Synthetic and Mechanistic Aspects of the Ruthenium-catalyzed Carbon-heteroatom Bond Forming Reactions of Alkenes and Alkynes [PDF]
, 2011 The group’s recent advances in catalytic carbon-to-heteroatom bond forming reactions of alkenes and alkynes are described. For the C–O bond formation reaction, a well-defined bifunctional ruthenium-amido catalyst has been successfully employed for the ...
Yi, Chae S.
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ChemInform Abstract: The Arene—Alkene Photocycloaddition [PDF]
ChemInform, 2011 AbstractReview: 104 refs.
Streit Ursula, Bochet Christian G
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