Efficient and selective N-alkylation of amines with alcohols catalysed by manganese pincer complexes
Nature Communications, 2016 Hydrogen borrowing is an attractive method for C-N bond formation - avoiding multiple alkylation products and reducing waste - but often is carried out with noble metals.
Saravanakumar Elangovan +5 more
doaj +2 more sources
DNA Alkylation Damage by Nitrosamines and Relevant DNA Repair Pathways
International Journal of Molecular Sciences, 2023 Nitrosamines occur widespread in food, drinking water, cosmetics, as well as tobacco smoke and can arise endogenously. More recently, nitrosamines have been detected as impurities in various drugs.
J. Fahrer, M. Christmann
semanticscholar +1 more source
Journal of the American Chemical Society, 2022 Sulfoximines are increasingly incorporated in agrochemicals and pharmaceuticals, with the two enantiomers of chiral sulfoximines often having profoundly different binding interactions with biomolecules.
Nathaniel S. Greenwood +2 more
semanticscholar +1 more source
Regioselective Reactions of Highly Substituted Arynes [PDF]
, 2010 The fully regioselective reactivity of four new highly substituted silyl aryl triflate aryne precursors in aryne acyl-alkylation, acyl-alkylation/condensation, and heteroannulation reactions is reported.
Bugga, Pradeep +4 more
core +2 more sources
DNA polymerase α (swi7) and the flap endonuclease fen1 (rad2) act together in the s-phase alkylation damage response in S. pombe [PDF]
, 2012 Polymerase α is an essential enzyme mainly mediating Okazaki fragment synthesis during lagging strand replication. A specific point mutation in Schizosaccharomyces pombe polymerase α named swi7-1, abolishes imprinting required for mating-type switching ...
Jacob Z. Dalgaard +5 more
core +2 more sources
TDP1 deficiency sensitizes human cells to base damage via distinct topoisomerase I and PARP mechanisms with potential applications for cancer therapy [PDF]
, 2013 Base damage and topoisomerase I (Top1)-linked DNA breaks are abundant forms of endogenous DNA breakage, contributing to hereditary ataxia and underlying the cytotoxicity of a wide range of anti-cancer agents.
Alagoz +50 more
core +1 more source
Synthesis and structures of O-anthrylmethyl-substituted hexahomotrioxacalix[3]arenes [PDF]
, 2016 O-Alkylation of 7,15,23-tri-tert-butyl-25,26,27-trihydroxy-2,3,10,11,18,19-hexahomo-3,11,19-trioxacalix[3]arene (1H₃) with 9-chloromethylanthracene 5 was carried out under different reaction conditions.
Ikejiri, Yusuke +5 more
core +1 more source
ALKYLATION OF BENZENE WITH LONG CHAIN OLEFINS OVER SOLID-ACID CATALYST
Journal of Engineering, 2009 This investigation is concerned with the linear alkylbenzene production reaction by the alkylation of benzene with long chain olefins C10-C13 over various prepared solid acid catalysts.
Abdul Halim A. K. Mohammed +1 more
doaj +1 more source
Chemical, Electronic, and Electrical Properties of Alkylated Ge(111) Surfaces [PDF]
, 2010 The use of Ge in semiconductor electronics has been constrained by the lack of a simple method of passivating the crystal surface. Toward that end, we have explored the utility of chemically bonded hydrocarbon monolayers.
Brunschwig, Bruce S. +2 more
core +2 more sources
Tunable, Functional Diblock Copolypeptide Hydrogels Based on Methionine Homologs. [PDF]
, 2020 The preparation of new diblock copolypeptide hydrogels derived from homologs of l-methionine, that is, l-homomethionine and l-6-(methylthio)-l-norleucine is described.
Deming, Timothy J +2 more
core +1 more source