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Electrostatic Interactions in Asymmetric Organocatalysis [PDF]

open access: goldAccounts of Chemical Research, 2023
Electrostatic interactions are ubiquitous in catalytic systems and are often decisive in determining reactivity and stereoselectivity. However, a lack of understanding of the fundamental underlying principles has long stymied our ability to fully harness the power of these interactions.
Rajat Maji   +2 more
europepmc   +6 more sources

Do We Need Asymmetric Organocatalysis?

open access: diamondCHIMIA, 2007
Asymmetric organocatalysis is a 'fast lane' of the chemical highway: the progress in the last decade is simply spectacular. This introductory article summarizes basic principles, historical background, and discusses basic catalyst classes and ...
Peter I. Dalko
doaj   +4 more sources

Asymmetric Organocatalysis [PDF]

open access: bronzeChemInform, 2005
AbstractFor Abstract see ChemInform Abstract in Full Text.
Jayasree Seayad, Benjamin List
  +8 more sources

Evolution of design approaches in asymmetric organocatalysis over the last decade

open access: goldTetrahedron Chem, 2023
This perspective intends to cover the vast field of asymmetric organocatalysis and its evolution during the last ten years. This work has evaluated the corresponding timeline of the progression of the field concerning the main synthetic approaches as ...
Nika Melnyk   +3 more
doaj   +2 more sources

Halides as versatile anions in asymmetric anion-binding organocatalysis [PDF]

open access: diamondBeilstein Journal of Organic Chemistry, 2021
This review intends to provide an overview on the role of halide anions in the development of the research area of asymmetric anion-binding organocatalysis.
Lukas Schifferer   +3 more
doaj   +2 more sources

Palladium and Organocatalysis: An Excellent Recipe for Asymmetric Synthesis [PDF]

open access: goldMolecules, 2013
The dual activation of simple substrates by the combination of organocatalysis and palladium catalysis has been successfully applied in a variety of different asymmetric transformations.
Isidro M. Pastor   +3 more
doaj   +2 more sources

Asymmetric organocatalysis involving double activation

open access: yesTetrahedron Chem, 2022
Asymmetric organocatalysis contributed tremendously to the field of organic synthesis since year 2000. Considering the diversity of organocatalysts and their activation modes, chemists developed the double activation strategy, in which two distinct ...
Zhi Chen   +3 more
doaj   +2 more sources

Catalyst design within asymmetric organocatalysis

open access: hybridWIREs Computational Molecular Science, 2022
AbstractThe field of organocatalysis, more specifically asymmetric organocatalysis, is continuously expanding having grown significantly over the recent years. However, despite this exponential expansion, the ability to determine with any degree of certainty the reaction mechanisms of these types of reactions fails to keep within pace.
Íñigo Iribarren   +2 more
openalex   +2 more sources

Asymmetric Organocatalysis—A Game Changer [PDF]

open access: hybridChemistry International, 2022
Abstract This year’s Nobel Prize in Chemistry was awarded to Benjamin List and David MacMillan “for the development of asymmetric organocatalysis.” IUPAC congratulates the laureates for their achievements.

openalex   +2 more sources

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