Results 11 to 20 of about 3,258 (176)

Electrostatic Interactions in Asymmetric Organocatalysis. [PDF]

open access: yesAcc Chem Res, 2023
Electrostatic interactions are ubiquitous in catalytic systems and are often decisive in determining reactivity and stereoselectivity. However, a lack of understanding of the fundamental underlying principles has long stymied our ability to fully harness the power of these interactions.
Maji R, Mallojjala SC, Wheeler SE.
europepmc   +5 more sources

Asymmetric Organocatalysis [PDF]

open access: yesAccounts of Chemical Research, 2004
In the year 2000, Accounts of Chemical Research published a landmark special edition on the timely subject of asymmetric catalysis, edited by Scott Denmark and Erik Jacobsen.
K. N. Houk, Benjamin List
openaire   +3 more sources

Asymmetric organocatalysis [PDF]

open access: yesTetrahedron, 2007
AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
Stefan, Jaroch   +2 more
core   +5 more sources

Non-asymmetric organocatalysis [PDF]

open access: yesChemical Communications, 2012
Asymmetric organocatalysis is now an established methodology for the preparation of chiral compounds. However, these are not the only valuable molecules which can be conveniently obtained. Organocatalytic reactions affording achiral compounds are gaining momentum, opening unexplored pathways in the synthesis of densely functionalized aromatic moieties,
RENZI, POLYSSENA, BELLA, Marco
openaire   +4 more sources

Low-loading asymmetric organocatalysis [PDF]

open access: yesChem. Soc. Rev., 2012
Asymmetric organocatalysis is now recognized as the third pillar of asymmetric synthesis. Recent years have witnessed increasing interest towards the use of highly active and stereoselective organocatalysts. This critical review documents the advances in the development of chiral organocatalysts which are systematically used in ≤3 mol% loading in all ...
GIACALONE, Francesco   +3 more
openaire   +3 more sources

Do We Need Asymmetric Organocatalysis? [PDF]

open access: yesCHIMIA, 2007
Asymmetric organocatalysis is a 'fast lane' of the chemical highway: the progress in the last decade is simply spectacular. This introductory article summarizes basic principles, historical background, and discusses basic catalyst classes and ...
Peter I. Dalko
doaj   +3 more sources

Chiral Brønsted Acids for Asymmetric Organocatalysis [PDF]

open access: yes, 2009
Chiral Brønsted acid catalysis is an emerging area of organocatalysis. Since the pioneering studies of the groups of Akiyama and Terada in 2004 on the use of chiral BINOL phosphates as powerful Brønsted acid catalysts in asymmetric Mannich-type reactions, numerous catalytic asymmetric transformations involving imine activation have been realized by ...
Kampen, D., Reisinger, C., List, B.
openaire   +4 more sources

Evolution of asymmetric organocatalysis: multi- and retrocatalysis [PDF]

open access: yesGreen Chemistry, 2012
The evolution of organocatalysis led to various valuable approaches, such as multicomponent as well as domino and tandem reactions. Recently, organomulticatalysis, i.e., the modular combination of distinct organocatalysts enabling consecutive reactions to be performed in one pot, has become a powerful tool in organic synthesis.
Wende, Raffael C.   +2 more
openaire   +6 more sources

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