Results 21 to 30 of about 415,153 (176)

Cross-trienamines in asymmetric organocatalysis. [PDF]

open access: yesJ Am Chem Soc, 2012
Cross-conjugated trienamines are introduced as a new concept in asymmetric organocatalysis. These intermediates are applied in highly enantioselective Diels-Alder and addition reactions, providing functionalized bicyclo[2.2.2]octane compounds and γ'-addition products, respectively.
Halskov KS   +5 more
europepmc   +3 more sources

Recent Advances in the Enantioselective Radical Reactions

open access: yesMolecules, 2023
The review covers research published since 2017 and is focused on enantioselective synthesis using radical reactions. It describes recent approaches to the asymmetric synthesis of chiral molecules based on the application of the metal catalysis, dual ...
Tomasz Bauer   +2 more
doaj   +1 more source

Asymmetric organocatalysis involving double activation

open access: yesTetrahedron Chem, 2022
Asymmetric organocatalysis contributed tremendously to the field of organic synthesis since year 2000. Considering the diversity of organocatalysts and their activation modes, chemists developed the double activation strategy, in which two distinct ...
Zhi Chen   +3 more
doaj   +1 more source

Recent Advances in Asymmetric Synthesis of Pyrrolidine-Based Organocatalysts and Their Application: A 15-Year Update

open access: yesMolecules, 2023
In 1971, chemists from Hoffmann-La Roche and Schering AG independently discovered a new asymmetric intramolecular aldol reaction catalyzed by the natural amino acid proline, a transformation now known as the Hajos–Parrish–Eder–Sauer–Wiechert reaction ...
Arianna Quintavalla   +2 more
doaj   +1 more source

Organocatalysts for enantioselective synthesis of fine chemicals: definitions, trends and developments

open access: yesScienceOpen Research, 2015
Organocatalysis, that is the use of small organic molecules to catalyze organic transformations, has been included among the most successful concepts in asymmetric catalysis, and it has been used for the enantioselective construction of C–C, C–N, C–O, C ...
Chiara Palumbo
doaj   +5 more sources

Asymmetric organocatalysis at the service of medicinal chemistry. [PDF]

open access: yesISRN Org Chem, 2014
The application of the most representative and up-to-date examples of homogeneous asymmetric organocatalysis to the synthesis of molecules of interest in medicinal chemistry is reported. The use of different types of organocatalysts operative via noncovalent and covalent interactions is critically reviewed and the possibility of running some of these ...
Ricci A.
europepmc   +4 more sources

Reacciones asimétricas organocatalizadas en ausencia de disolvente: una estrategia para hacer más “verde” la organocatálisis

open access: yesEducación Química, 2018
Solvent-free asymmetric organocatalyzed reactions: a strategy towards a greener organocatalysis According with the principles of “green” chemistry, asymmetric organocatalysis aims to become a sustainable strategy to catalyze a wide range of chemical ...
José G. Hernández, Eusebio Juaristi
doaj   +1 more source

Asymmetric Organocatalysis—A Powerful Technology Platform for Academia and Industry: Pregabalin as a Case Study [PDF]

open access: yes, 2022
Enantioselective organocatalysis has quickly established itself as the third pillar of asymmetric catalysis. It is a powerful technology platform, and it has a tremendous impact in both academic and industrial settings.
Pesciaioli F.   +29 more
core   +3 more sources

Cross-trienamines in Asymmetric Organocatalysis

open access: yes, 2015
Cross-conjugated trienamines are introduced as a new concept in asymmetric organocatalysis. These intermediates are applied in highly enantioselective Diels–Alder and addition reactions, providing functionalized bicyclo[2.2.2]­octane compounds and γ ...
Karl Anker Jørgensen (1287900)   +5 more
core   +3 more sources

Magnetic nanoparticle-supported organocatalysis

open access: yesGreen Processing and Synthesis, 2013
Magnetic nanoparticle (MNP)-supported catalysis is a new method to facilitate catalyst separation and reuse. This technique has recently been introduced for organocatalysis.
Huang Yibo, Zhang Wei
doaj   +1 more source

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