Asymmetric synthesis of tri- and tetrasubstituted trifluoromethyl dihydropyranones from alpha-aroyloxyaldehydes via NHC redox catalysis [PDF]
, 2014 We thank the Royal Society for a University Research Fellowship (A.D.S.), and the European Research Council under the European Union’s Seventh Framework Programme (FP7/2007-2013) ERC Grant Agreement No.
Davies, Alyn T. +3 more
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Organocatalysis in total synthesis [PDF]
, 2015 Peer ...
Herrera, Raquel P. +1 more
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Matrix variate and tensor variate Laplace distributions [PDF]
arXiv, 2021 In this article, we define a matrix variate asymmetric Laplace distribution. We prove some properties of the matrix variate asymmetric Laplace distribution. We prove the relationship between the matrix variate asymmetric Laplace distribution and other distributions. We define a matrix variate generalized asymmetric Laplace distribution.
arxiv
Asymmetric organocatalysis involving double activation
Tetrahedron Chem, 2022 Asymmetric organocatalysis contributed tremendously to the field of organic synthesis since year 2000. Considering the diversity of organocatalysts and their activation modes, chemists developed the double activation strategy, in which two distinct ...
Zhi Chen +3 more
doaj
Pursuing Chemical Efficiency by Using Supported Organocatalysts for Asymmetric Reactions under Aqueous Conditions [PDF]
, 2015 Over the past decade, a great effort has been made by the chemical community to improve the efficiency of organic transformations and allow sustainable processes.
Alonso, Diego A. +6 more
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A note on asymmetric hypergraphs [PDF]
arXiv, 2023 A $k$-graph $\mathcal{G}$ is asymmetric if there does not exist an automorphism on $\mathcal{G}$ other than the identity, and $\mathcal{G}$ is called minimal asymmetric if it is asymmetric but every non-trivial induced sub-hypergraph of $\mathcal{G}$ is non-asymmetric. Extending a result of Jiang and Ne\v{s}et\v{r}il, we show that for every $k$-graph, $
arxiv
Organocatalytic Lewis base functionalisation of carboxylic acids, esters and anhydrides via C1-ammonium or azolium enolates [PDF]
, 2014 This tutorial review highlights the organocatalytic Lewis base functionalisation of carboxylic acids, esters and anhydrides via C1-ammonium/azolium enolates.
Morrill, Louis C., Smith, Andrew D.
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Cooperative effects between arginine and glutamic acid in the amino acid catalyzed aldol reaction [PDF]
, 2017 Catalysis of the aldol reaction between cyclohexanone and 4-nitrobenzaldehyde by mixtures of L-Arg and of L-Glu in wet DMSO takes place with higher enantioselectivity (up to a seven-fold enhancement in the anti- aldol for the 1:1 mixture) than that ...
Moyano i Baldoire, Albert +1 more
core +1 more source
Nonlinear SVD with Asymmetric Kernels: feature learning and asymmetric Nyström method [PDF]
arXiv, 2023 Asymmetric data naturally exist in real life, such as directed graphs. Different from the common kernel methods requiring Mercer kernels, this paper tackles the asymmetric kernel-based learning problem. We describe a nonlinear extension of the matrix Singular Value Decomposition through asymmetric kernels, namely KSVD. First, we construct two nonlinear
arxiv
Cluster Preface: Non-Covalent Interactions in Asymmetric Catalysis [PDF]
, 2016 The successful harnessing of non-covalent interactions to activate functional groups and control selectivity in chemical reactions is a relatively recent phenomenon in synthetic chemistry, but one that has delivered ground-breaking results, particularly ...
Phipps, RJ
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