Results 51 to 60 of about 31,425 (239)

Stereodivergent, Diels-Alder-initiated organocascades employing α,β-unsaturated acylammonium salts: scope, mechanism, and application. [PDF]

open access: yes, 2017
Chiral α,β-unsaturated acylammonium salts are novel dienophiles enabling enantioselective Diels-Alder-lactonization (DAL) organocascades leading to cis- and trans-fused, bicyclic γ- and δ-lactones from readily prepared dienes, commodity acid chlorides ...
Abbasov, Mikail E   +3 more
core   +2 more sources

Giant asymmetric second-harmonic generation in bianisotropic metasurfaces based on bound states in the continuum [PDF]

open access: yesarXiv, 2021
Bianisotropy is a powerful concept enabling asymmetric optical response, including asymmetric reflection, absorption, optical forces, light trapping, and lasing. The physical origin of these asymmetric effects can be understood from magnetoelectric coupling and asymmetrical field enhancement.
arxiv  

String Theories on the Asymmetric Orbifolds with Twist-Untwist Intertwining Currents [PDF]

open access: yesProg.Theor.Phys.Suppl.110:261-276,1992, 1992
We give various examples of asymmetric orbifold models to possess intertwining currents which convert untwisted string states to twisted ones, and vice versa, and see that such asymmetric orbifold models are severely restricted. The existence of the intertwining currents leads to the enhancement of symmetries in asymmetric orbifold models.
arxiv   +1 more source

(2R,4R)-2-Hydroxy-4-(2-methoxyphenyl)bicyclo[3.3.1]nonan-9-one

open access: yesActa Crystallographica Section E, 2009
The title compound, C16H20O3, contains a bicyclic ring system with two chiral centers. The crystal structure is stabilized by intermolecular O—H...O hydrogen bonds.
Shuping Luo   +4 more
doaj   +1 more source

Ultra-high-throughput mapping of the chemical space of asymmetric catalysis enables accelerated reaction discovery

open access: yesNature Communications, 2023
The discovery of highly enantioselective catalysts and elucidating their generality face great challenges due to the complex multidimensional chemical space of asymmetric catalysis and inefficient screening methods.
Wenjing Nie   +5 more
doaj   +1 more source

Halides as versatile anions in asymmetric anion-binding organocatalysis

open access: yesBeilstein Journal of Organic Chemistry, 2021
This review intends to provide an overview on the role of halide anions in the development of the research area of asymmetric anion-binding organocatalysis.
Lukas Schifferer   +3 more
doaj   +1 more source

Organocatalytic Enantioselective Henry Reactions [PDF]

open access: yes, 2011
This is an open access article distributed under the Creative Commons Attribution License.A large number of interesting organocatalytic enantioselective protocols have been explored and successfully applied in the last decade.
Herrera, Raquel P.   +2 more
core   +2 more sources

Synergistic Visible Light Nanophotocatalysis and Asymmetric Organocatalysis for the Stereoselective α‐Alkylation of Aldehydes

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
An unprecedent dual catalytic nanophotocatalytic and asymmetric organocatalytic system for the α‐functionalization of aldehydes is developed using carbon nanodots as photosensitizers. The optimized methodology yields the alkylated products with up to 94% yield and up to 98:2 e.r., evidencing the possible recycling of the nanocatalysts.
Antonio Di Sabato   +9 more
wiley   +1 more source

Non-Covalent Organocatalyzed Domino Reactions Involving Oxindoles: Recent Advances

open access: yesMolecules, 2017
The ubiquitous presence of spirooxindole architectures with several functionalities and stereogenic centers in bioactive molecules has been appealing for the development of novel methodologies seeking their preparation in high yields and selectivities ...
Tecla Gasperi   +3 more
doaj   +1 more source

Solvent-Free Enantioselective Organocatalyzed Aldol Reactions [PDF]

open access: yes, 2014
The use of proline as catalyst for the aldol process has given a boost to the development of organocatalysis as a research area. Since then, a plethora of organocatalysts of diverse structures have been developed for this and other organic ...
Bañón Caballero, Abraham   +2 more
core   +2 more sources

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