The efficient synthesis of three-membered rings via photo- and electrochemical strategies. [PDF]
Han X, Zhang N, Li Q, Zhang Y, Das S.
europepmc +3 more sources
Bortrifluorid-katalysierte Umsetzung von 2H-Azirinen und Vinylaziden mit Nitrilen
The reaction of 2H-azirines or vinyl azides with nitriles in the presence of boron trifluoride etherate, to yield the corresponding imidazoles (see table), is described.
Heinz Bader, Hans-Jürgen Hansen
doaj +1 more source
An overview of the use of 2H-azirines, conjugated nitrosoalkenes and conjugated azoalkenes bearing phosphorus substituents in addition and cycloaddition reactions is presented, focused on strategies for the synthesis of aminophosphonate and ...
Américo Lemos
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Synthesis and Antiproliferative Activity of Phosphorus Substituted 4-Cyanooxazolines, 2-Aminocyanooxazolines, 2-Iminocyanooxazolidines and 2-Aminocyanothiazolines by Rearrangement of Cyanoaziridines [PDF]
Several phosphorus-substituted N-acylated cyanoaziridines 2 and N-carbamoylated cyanoziridines 5 were prepared in good to high yields. N-Acylated cyanoaziridines 2 were used, after ring expansion, in an efficient synthesis of oxazoline derivative 3a and ...
Carramiñana Jiménez, Víctor +3 more
core +1 more source
Light-induced synthesis of 2H-azirines and its applications in organic chemistry
2H-azirines have represented versatile building motifs in the domain of organic chemistry owing to their excellent reaction activity induced by the high strain of the three-membered ring species.
Shibo Lin +4 more
doaj +1 more source
Ethyl 2-(Diisopropoxyphosphoryl)-2H-Azirine-3-Carboxylate: Reactions with Activated 1,3-Butadienes [PDF]
The 12th International Electronic Conference on Synthetic Organic Chemistry session General Organic SynthesisEthyl 2-(diisopropoxyphosphoryl)-2H-azirine-3-carboxylate was generated “in situ” and reacted with a number of 1,3-butadienes.
Alves, M. José +3 more
core +1 more source
Stabile Zink-Komplexe von 3-Amino-2H-azirinen
3-Dimethylamino-2,2-dimethyl-2H-azirine (4a), which is known to react easily with Brönsted acids and electrophiles, forms a stable complex 5a with ZnBr2. In contrast to all other reactions of 4a, the three-membered ring in this complex is preserved. The
Kurt Dietliker +3 more
doaj +1 more source
I. The Synthesis, Absolute Configuration, and Stereochemistry of Thermal Decomposition of (+)-3R,5R- and (+)-3R,5S-3-Ethyl-5-Methyl-1-Pyrazoline. II. Mechanistic Investigations of the Thermal Decompositions of 2H-Azirines [PDF]
I. (+)-3R,5R- and (+)-3R,5S-3-ethyl-5-methyl-1-pyrazolines (34T and 34C, respectively) have been prepared in optically active form. Their stereochemistries have been determined by correlation with (-)-R-3-hexanol and (-)-R-2-bromohexane.
Wendling, Larry Allan
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Neuere Methoden zur Ringerweiterung organischer Verbindungen
The actual interest in the construction of cyclic compounds via ring expansion reactions is demonstrated in the first chapter by means of typical examples.
Heinz Heimgartner
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Diverse reactivity of maleimides in polymer science and beyond
This mini‐review provides a thorough overview of maleimide chemistry, highlighting its diverse reactivity in polymer and materials science applications. Abstract Maleimides are remarkably versatile functional groups, capable of participating in homo‐ and copolymerizations, Diels–Alder and (photo)cycloadditions, Michael additions, and other reactions ...
Bruce E Kirkpatrick +2 more
wiley +1 more source

