Results 41 to 50 of about 16,181 (141)

Benzamide‐Directed Hydroarylative Cross‐Couplings Using Minimally Activated Alkenes: Enantioselective Synthesis of Tertiary and Quaternary Stereocenters

open access: yesAngewandte Chemie, EarlyView.
Benzamide‐directed iridium‐catalyzed branched selective and enantioselective C(sp2)‐H additions to minimally activated alkenes give tertiary and quaternary benzylic stereocenters under byproduct‐free conditions. The processes are enabled by a family of SPINOL‐based homochiral diphosphonite ligands.
Timothy P. Aldhous   +9 more
wiley   +2 more sources

Crystal structure and Hirshfeld surface analysis of 3-(cyclopropylmethoxy)-4-(difluoromethoxy)-N-(pyridin-2-ylmethyl)benzamide

open access: yesActa Crystallographica Section E: Crystallographic Communications, 2019
The title compound, C18H18F2N2O3, crystallizes with two independent molecules (A and B) in the asymmetric unit. They differ essentially in the orientation of the pyridine ring with respect to the benzene ring; these two rings are inclined to each other ...
G. Artheswari   +2 more
doaj   +1 more source

3,5-Dibromo-4-carbamoylbenzoic acid 2-propanol monosolvate

open access: yesIUCrData, 2021
In the title solvated crystal, C8H5Br2NO3·C3H8O, the acid molecules form inversion dimers by pairwise N—H...O hydrogen bonds between carbamoyl groups and the carboxyl and carbamoyl groups link to form head-to-tail inversion dimers.
Wayland E. Noland   +3 more
doaj   +1 more source

Synthesis and reactions of 1-amino-1,5,6,10b-tetrahydroimidazo[2,1-a]isoquinolin-2(3H)-ones [PDF]

open access: yes, 2008
1-Amino-1,5,6,10b-tetrahydroimidazo[2,1-a]isoquinolin-2(3H)-ones, as previously unknown ring-annelated isoquinolines with a 3-aminoimidazolidin-4-one scaffold, were selectively prepared upon reacting 2-carbamoylmethyl- or 2-ethoxycarbonylmethyl-3,4 ...
De Kimpe, Norbert   +5 more
core   +2 more sources

τBu₂SiF-Derivatized D₂-Receptor Ligands: The First SiFA-Containing Small Molecule Radiotracers for Target-Specific PET-Imaging [PDF]

open access: yes, 2011
The synthesis, radiolabeling and in vitro evaluation of new silicon-fluoride acceptor (SiFA) derivatized D-2-receptor ligands is reported. The SiFA-technology simplifies the introduction of fluorine-18 into target specific biomolecules for Positron ...
Bartenstein, Peter   +10 more
core   +2 more sources

Structural analysis of 2-iodobenzamide and 2-iodo-N-phenylbenzamide

open access: yesActa Crystallographica Section E: Crystallographic Communications, 2018
The title compounds, 2-iodobenzamide, C7H6INO (I), and 2-iodo-N-phenylbenzamide, C13H10INO (II), were both synthesized from 2-iodobenzoic acid. In the crystal structure of (I), N—H...O and hydrogen bonds form two sets of closed rings, generating dimers ...
Keshab M. Bairagi   +4 more
doaj   +1 more source

New N-acyl Thiourea Derivatives: Synthesis, Standardized Quantification Method and In Vitro Evaluation of Potential Biological Activities

open access: yesAntibiotics, 2023
New N-acyl thiourea derivatives with heterocyclic rings have been synthesized by first obtaining isothiocyanate, which further reacted with a heterocyclic amine, characterized by (FT-IR, NMR spectroscopy and FT-ICR) and tested for their in vitro ...
Roxana Roman   +12 more
doaj   +1 more source

Crystal structure of 2-methyl-N-{[2-(pyridin-2-yl)ethyl]carbamothioyl}benzamide

open access: yesActa Crystallographica Section E: Crystallographic Communications, 2015
In the title compound, C16H17N3OS, a benzoyl thiourea derivative, the planes of the pyridine and benzene rings are inclined to one another by 66.54 (9)°. There is an intramolecular N—H...O hydrogen bond present forming an S(6) ring motif. In the crystal,
Nadiah Ameram, Farook Adam
doaj   +1 more source

2-Ferrocenyl-N-(2-ferrocenylbenzoyl)-N-(4-methyl-2-pyridyl)benzamide [PDF]

open access: yes, 2009
The title compound, [Fe2(C5H5)2(C30H22N2O2)], a 2:1 product of the reaction of 2-ferrocenylbenzoic acid and 2-amino-4-methylpyridine, forms a twisted molecular structure in the solid state due to steric effects from the two benzene rings ortho ...
Alley, Steven   +2 more
core   +3 more sources

Covalent Organic Frameworks for Photocatalysis

open access: yesAdvanced Materials, EarlyView.
This review provides an overview of recent advances in covalent organic frameworks (COFs) for photocatalysis, focusing on sustainable energy applications like water splitting, hydrogen peroxide generation, and CO2 and N2 reduction. It discusses design principles, structure‐function relationships, challenges in COF photocatalysis, and strategies to ...
Bikash Mishra   +6 more
wiley   +1 more source

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