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Recent Advances in Regioselective C–H Bond Functionalization of Free Phenols [PDF]

open access: yesMolecules, 2023
Phenols are important readily available synthetic building blocks and starting materials for organic synthetic transformations, which are widely found in agrochemicals, pharmaceuticals, and functional materials.
Yanan Li   +3 more
doaj   +2 more sources

C–H Bond Functionalization of Amines: A Graphical Overview of Diverse Methods [PDF]

open access: yesSynOpen, 2021
This Graphical Review provides a concise overview of the manifold and mechanistically diverse methods that enable the functionalization of sp3 C–H bonds in amines and their derivatives.
Subhradeep Dutta   +4 more
doaj   +2 more sources

Synthesis of Benzo[4,5]thiazolo[2,3-c][1,2,4]triazole Derivatives via C-H Bond Functionalization of Disulfide Intermediates [PDF]

open access: yesMolecules, 2022
Many nitrogen- and sulfur-containing heterocyclic compounds exhibit biological activity. Among these heterocycles are benzo[4,5]thiazolo[2,3-c][1,2,4]triazoles for which two main synthetic approaches exist.
Luis G. Ardón-Muñoz   +1 more
doaj   +2 more sources

Transition-metal-free electrochemical-induced active C(sp3)-H functionalization

open access: yesGreen Chemistry Letters and Reviews, 2023
Direct C–H bond functionalization is the most effective technique to construct C–X (X = C, N, O, S, etc.), which could simplify the conventional synthesis methods.
Xiaolong Ma   +4 more
doaj   +1 more source

Transition-metal-catalyzed aromatic C–H functionalization assisted by the phosphorus-containing directing groups

open access: yesGreen Synthesis and Catalysis, 2023
Transition-metal-catalyzed C–H bond functionalization has attracted tremendous attention as an increasingly important protocol for the construction of C–C and C–X bonds.
Jian Zhang   +5 more
doaj   +1 more source

C–H bond functionalization reactions enabled by photobiocatalytic cascades

open access: yesGreen Synthesis and Catalysis, 2021
Light may participate in biocatalytic processes either by direct light-induced biocatalysis or by cascading light-induced chemical reactions with biocatalytic ones, which are acknowledged as photocatalysis.
Yuanying Li   +3 more
doaj   +1 more source

Rollover Cyclometalation as a Valuable Tool for Regioselective C–H Bond Activation and Functionalization

open access: yesMolecules, 2021
Rollover cyclometalation constitutes a particular case of cyclometallation reaction. This reaction occurs when a chelated heterocyclic ligand loses its bidentate coordination mode and undergoes an internal rotation, after which a remote C–H bond is ...
Antonio Zucca, Maria I. Pilo
doaj   +1 more source

Co(III) Intermediates in Cobalt-Catalyzed, Bidentate Chelation Assisted C(sp2)-H Functionalizations

open access: yesInorganics, 2023
The C-H bond activation and functionalization is a powerful tool that provides efficient access to various organic molecules. The cobalt-catalyzed oxidative C-H bond activation and functionalization has earned enormous interest over the past two decades.
Aleksandrs Cizikovs, Liene Grigorjeva
doaj   +1 more source

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