Recent advances in C(sp3)–H bond functionalization via metal–carbene insertions
Beilstein Journal of Organic Chemistry, 2016 The recent development of intermolecular C–H insertion in the application of C(sp3)–H bond functionalizations, especially for light alkanes, is reviewed.
Bo Wang, Di Qiu, Yan Zhang, Jianbo Wang
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Methodology of the direct C–H bond functionalization in nitrogen-containing heterocycles [PDF]
, 2013 Предложены два эффективных методологических подхода для проведения прямой функционализациии связи С(sp2)–H в альдонитронах. Палладий(II)-катализироуемое окислительное С–С сочетание с индолами и пирролами приводит к нитронам, содержащим N-оксидную функцию.
Varaksin, M. V. +1 more
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Functionalization of carbon nanotubes with -CHn, -NHn fragments, -COOH and -OH groups
, 2013 We present results of extensive theoretical studies concerning stability, morphology, and band structure of single wall carbon nanotubes (CNTs) covalently functionalized by -CHn(for n=2,3,4),-NHn(for n=1,2,3,4),-COOH and -OH groups. Our studies are based
Majewski, Jacek A. +1 more
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Metal-free alcohol-directed regioselective heteroarylation of remote unactivated C(sp3)–H bonds
Nature Communications, 2018 Direct remote C–H functionalization of aliphatic alcohols via alkoxy radicals is largely unexplored. Here, the authors report the C(sp3)-heteroaryl bond formation in aliphatic alcohols mediated by alkoxy radicals formed with a hypervalent iodine reagent.
Xinxin Wu +8 more
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Chemical functionalization of graphene
, 2009 Experimental and theoretical results on chemical functionalization of graphene are reviewed. Using hydrogenated graphene as a model system, general principles of the chemical functionalization are formulated and discussed.
Boukhvalov, D. W., Katsnelson, M. I.
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Experimental realization of catalytic CH_4 hydroxylation predicted for an iridium NNC pincer complex, demonstrating thermal, protic, and oxidant stability [PDF]
, 2009 A discrete, air, protic, and thermally stable (NNC)Ir(III) pincer complex was synthesized that catalytically activates the CH bond of methane in trifluoroacetic acid; functionalization using NaIO_4 and KIO_3 gives the oxy ...
Ess, Daniel H. +6 more
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Threading Through Macrocycles Enhances the Performance of Carbon Nanotubes as Polymer Fillers
, 2016 In this work we study the reinforcement of polymers by mechanically interlocked derivatives of single-walled carbon nanotubes (SWNTs). We compare the mechanical properties of fibers made of polymers and of composites with pristine single-walled carbon ...
Bernal, M. Mar +8 more
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Acceleration of Nucleophilic CH Activation by Strongly Basic Solvents [PDF]
, 2010 (IPI)Ru(II)(OH)_n(H_2O)_m, 2, where IPI is the NNN-pincer ligand, 2,6-diimidizoylpyridine, is shown to catalyze H/D exchange between hydrocarbons and strongly basic solvents at higher rates than in the case of the solvent alone.
Goddard, William A., III +4 more
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Functionalized adamantane: fundamental building blocks for nanostructure self-assembly
, 2009 We report first principles calculations on the electronic and structural properties of chemically functionalized adamantane molecules, either in isolated or crystalline forms.
Assali, Lucy V. C. +3 more
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Beilstein Journal of Organic Chemistry, 2019 The Pd-catalyzed C–H bond functionalization of lilolidine was investigated. The use of a palladium-diphosphine catalyst associated to acetate bases in DMA was found to promote the regioselective arylation at α-position of the nitrogen atom of lilolidine ...
Hai-Yun Huang +4 more
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