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Base-controlled regio-divergent C–H bond functionalization
Chemical CommunicationsThe choice of appropriate directing groups, catalysts and bases to give different regioisomers from the same precursors can improve the efficiency and atom economy in synthetic organic chemistry, while minimizing costs and expanding chemical space.
Yanlong Luo +10 more
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Cobalt-Catalyzed C-H Bond Functionalization
The ultimate goal of organic synthetic chemistry is to design and synthesize more complex structures from simple molecules. Classic organic synthesis often relies on the manipulations of functional groups. In organic chemistry, the term 'C-H bond functionalization' is used to describe a chemical reaction, in which a C-H bond of a substrate is cleaved ...openaire +1 more source
Ir-Catalyzed Functionalization of C–H Bonds
2010The ability to selectively functionalize C–H bonds holds enormous potential value in virtually every sphere of organic chemistry, from fuels to pharmaceuticals. Transition metal complexes have shown great promise in this context. Iridium provided the first examples of oxidative addition of C–H bonds; this addition is key to iridium’s leading role in ...
Jongwook Choi, Alan S. Goldman
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Metal‐Free Oxidative CC Bond Formation through CH Bond Functionalization
Chemistry – A European Journal, 2015AbstractThe formation of CC bonds embodies the core of organic chemistry because of its fundamental application in generation of molecular diversity and complexity. CC bond‐forming reactions are well‐known challenges. To achieve this goal through direct functionalization of CH bonds in both of the coupling partners represents the state‐of‐the‐art in
Narayan, R., Matcha, K., Antonchick, A.
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Noncovalent Interactions in C–H Bond Functionalization
2019Over the past few decades, direct functionalization/activation of the C–H bond to C–E (E = C, N, O, S, metal, etc.) bonds has become one of the most valuable and straightforward protocols in modern synthetic chemistry. In parallel, controlling the selectivity remains a central challenge in the catalytic functionalization/activation of C–H bond(s) owing
Kamran T. Mahmudov +3 more
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Functionalization and Homologation of C-H Bonds
2013Justin Du Bois of Stanford University developed (J. Am. Chem. Soc. 2010, 132, 10202) a Ru catalyst for the stereoretentive hydroxylation of 1 to 2. John T. Groves of Princeton University effected (J. Am. Chem. Soc. 2010, 132, 12847) equatorial chlorination of the test substrate 3. Kenneth M. Nicholas of the University of Oklahoma found (J. Org.
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Visible Light-Driven Radical-Mediated C–C Bond Cleavage/Functionalization in Organic Synthesis
Chemical Reviews, 2021Jia-Rong Chen, Wen-Jing Xiao
exaly
Activation and Functionalization of C—H Bonds
2004Activation and Functionalization of C-H Bonds explores recent developments in the reaction chemistry of solution-phase transition-metal based systems with simple hydrocarbons and with more complex organic molecules. More than 20 internationally leading research groups contributed to this volume, and their chapters cover such topics as fundamental ...
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Enantioselective Aliphatic C-H Bond Functionalization
Synfacts, 2009T. Katsuki, H. Suematsu
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