Results 111 to 120 of about 27,691 (270)

1,1‐Disubstituted Vinylbromides: Versatile Building Blocks for the Synthesis of Nitrogen‐Containing Heterocycles

European Journal of Organic Chemistry, Volume 29, Issue 23, 16 June 2026.
1,1‐Disubstituted vinylbromides are key intermediates for constructing nitrogen‐containing heterocycles. This review provides an overview of the synthetic applications of 1,1‐disubstituted vinylbromides and summarizes recent developments in reaction methodologies, mechanistic insights, and the structural diversity of N‐heterocyclic compounds accessible
Anne Westermeyer, Jun Fang, Chonghuo Liu, Guillaume Lefèvre, Gérard Guillamot, Phannarath Phansavath, Virginie Ratovelomanana‐Vidal   +6 more
wiley   +1 more source

Synthesis of Novel C‐Acyl‐Glycosyl Sulfonamides via Pd‐Catalyzed Carbonylative Coupling

European Journal of Organic Chemistry, Volume 29, Issue 23, 16 June 2026.
A Pd‐catalyzed carbonylative coupling of 1‐iodo‐glycals with diverse sulfonamides using Mo(CO)6 enables efficient access to C‐acyl‐glycosyl sulfonamides.This robust and versatile strategy delivers novel glycoside derivatives in good to excellent yields, highlighting their potential for drug discovery.
João A. F. Silva, Mônica F. Z. J. Toledo, Flávia Manarin, João H. de Araujo‐Neto, Milene M. Hornink, Hélio A. Stefani   +5 more
wiley   +1 more source

Innovating Electrosynthesis From Metal Electrodeposition to Organic Chemistry: Deep Eutectic Solvents as Efficient and Sustainable Media

ChemSusChem, Volume 19, Issue 11, 15 June 2026.
This review analyzes deep eutectic solvents (DESs) as efficient media for both organic and inorganic electrosynthesis. The improvements in terms of synthetic opportunities and sustainability are discussed, by exploring the multiple roles of DESs as solvents, electrolytes, and promoters, enabling effective and selective electrosynthesis under mild and ...
Cristiana Margarita, Stefano Nejrotti, Alejandro Leal‐Duaso, Marta Feroci, Alessandra Sanson, Claudia Barolo, Matteo Bonomo   +6 more
wiley   +1 more source

Counterion Effects Enable Divergent Pd‐Catalyzed Carbonylative Cyclization of Amide‐Tethered o‐Alkynylphenols

Advanced Synthesis &Catalysis, Volume 368, Issue 11, 3 June 2026.
The catalytic carbonylation of alkynes is a powerful route to heteroaromatic scaffolds, yet achieving regioselectivity remains challenging. Herein, we report a divergent carbonylative cyclization of 2‐alkynylphenol derivatives that affords either coumarins (6‐endo‐dig) or 2‐coumaranones (5‐exo‐dig) by tuning the palladium‐based catalytic system. Pd(OAc)
Aleksandr Voronov, Filippo Sacchelli, Diego Olivieri, Ana Maria Constantin, Paolo Pio Mazzeo, Raffaella Mancuso, Bartolo Gabriele, Carla Carfagna, Riccardo Tarroni, Luca Capaldo, Valerio Morlacci, Nicola Della Ca’   +11 more
wiley   +1 more source

T‐Cell Exhaustion in the Tumor Microenvironment: Subcellular Dysfunction, Pan‐Cancer Characteristics, and Therapeutic Interventions

Advanced Science, Volume 13, Issue 33, 15 June 2026.
This study elucidates the mechanisms of subcellular multidimensional collapse in exhausted T cells. By specifically targeting the nucleus, mitochondria, and endoplasmic reticulum, strategic interventions can effectively remodel the compromised organelle network. This integrated approach drives comprehensive T cell resuscitation, ultimately establishing
Mingxing Wang, Wanhui Dong, Jian Chen, Zhangjie Zhou, Shujuan Fu, Tingting Wu, Haiyan Jiang, Zhiying Wang, Zhixian Zhong, Yi Zhong   +9 more
wiley   +1 more source

Neurocognitive Aging Following Acute Illness: Pathobiology and a Framework for Developing Neurotherapeutic Agents

Brain and Behavior, Volume 16, Issue 6, June 2026.
In this review, we discuss the scientific basis for how neurocognitive aging occurs after critical illness, including sepsis, trauma, and burns, and the clinical need to develop therapies to reduce inflammation, protect the blood–brain barrier, remove senescent cells, and enhance neuroplasticity.
Errin Lawrence, Daniel Fulton, Poppy Brown, Subashini Suresh, Mark Morris, Paraskevi Goggolidou, Sree Chaithanya, Marcus Abbawy, Amelia Wild, Prashant Nasa, Niharika A. Duggal, Fang Gao‐Smith, Zubair Ahmed, Suresh Renukappa, Tonny Veenith   +14 more
wiley   +1 more source

Carboxylated Carbon Nanotube‐Supported Copper‐Indium Bimetallic Catalysts for Electroreduction of CO2 to Dimethyl Carbonate via Membrane‐Free Cascade Electrosynthesis

Carbon and Hydrogen, Volume 28, Issue 2, Page 226-243, June 2026.
A membrane‐free cascade electrocatalytic system with Cu100In50‐(COOH)CNTs converts CO2 to CO and then couples with alcohols to yield DMC (52.3% FE) and DEC (27.8% FE) via carboxyl‐Cu‐In synergistic regulation of intermediate adsorption. ABSTRACT Under the background of the dual carbon strategy, upgrading CO2 electroreduction from C1 products to high ...
Youjia Wang, Xin Ma, Yuxin Tian, Wenchao Wang, Bochen Tian, Yansheng Liu, Junwei Hou   +6 more
wiley   +1 more source

New protein fluorescent labeling methods for carbonylation and S-acylation studies in plants [PDF]

BIO Web of Conferences
Román Andrea, Priego Salvador, Castro Antonio J., Alche Juan De Dios   +3 more
doaj   +1 more source

A Spectral Matching Algorithm Based on the Wasserstein Metric

Journal of Chemometrics, Volume 40, Issue 6, June 2026.
ABSTRACT Through visual inspection, scientists can easily judge the similarity of pairs of spectra from different sources, whether they are experimental measurements, spectra libraries, or spectra calculations. Spectral similarity is recognized when the peak patterns appear similar, even if the peak positions are shifted or the peak amplitudes are ...
Klaus Neymeyr, Baoxin Zhang, Christoph Kubis, Mattis Brinker, Lukas Prestin, Tomass Andersons, Mathias Sawall, Jan Hellwig   +7 more
wiley   +1 more source

Stabilization of Pd Active Sites by Defective NaY Zeolite Framework for Enhanced Stability in Dimethyl Carbonate Synthesis

EcoEnergy, Volume 4, Issue 3, June 2026.
A tailored‐defect strategy employing sequential high‐temperature calcination and acetylacetone treatment was developed to generate framework defects in NaY zeolite while preventing the formation of strong acid sites. These defects facilitate electron transfer from Pd to the zeolite framework and stabilize the Pd2+ active sites, thereby conferring ...
Chunzheng Wang, Rongyan Mei, Shicheng Yuan, Yida Zhou, Yipu Xu, Xianglong Meng, Longgang Tao, Shutao Xu, Hailing Guo, Svetlana Mintova   +9 more
wiley   +1 more source