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New trends in biodiesel production: Chemical interesterification of sunflower oil with methyl acetate

Biomass and Bioenergy, 2011
Abstract In this study, the chemical interesterification of oil with methyl acetate using potassium hydroxide, methoxide and polyethylene glycolate as catalysts was investigated. The reactions were performed at 50 °C using the range methyl acetate 12 mol mol −1 of refined sunflower oil to a value of 100 mol mol −1 and the range of potassium ...
Abraham Casas   +2 more
exaly   +2 more sources

Chemical and Enzymatic Interesterification for Food Lipid Production

Springer Briefs in Molecular Science
Gabriela Alves Macedo
exaly   +2 more sources

Chemical interesterification with regioselectivity for edible oils

Journal of the American Oil Chemists' Society, 1993
Chemical interesterification reaction conditions that provide regioselectivity regarding fatty acid positions in triacylglycerol have been investigated. Sodium methoxide‐catalyzed ester interchange between soybean oil and methyl stearate was performed in hexane at low reaction temperature,i.e., 30 to 60°C.
Hiroaki Konishi   +2 more
openaire   +1 more source

Distinction between enzymically and chemically catalyzed interesterification

Journal of the American Oil Chemists' Society, 1993
AbstractThe 1,3‐specific lipase‐catalyzed interesterified fats were distinguished from chemically catalyzed products by the fatty acids in the 2‐position. The fatty acid contents in the 2‐position of the 1,3‐lipase‐catalyzed and the original triglycerides were similar but different from that of chemically interesterified fat.
S. Sil Roy, D. K. Bhattacharyya
openaire   +1 more source

Chemical interesterification of olive oil‐tristearin blends for margarines

International Journal of Food Science & Technology, 1991
SummaryRefined olive oil–glycerol tristearate blends were interesterified using sodium methoxide as catalyst. The glyceride structure of the randomized fats was studied and the relationship between the structure and physical properties was examined.
V. GAVRIILIDOU, D. BOSKOU
openaire   +1 more source

Interesterification, chemical or enzymatic catalysis

Lipid Technology, 2015
The interesterification process is one of the oil modification processes the refiner can use to alter the physical properties of oils and fats, The reaction requires a catalyst to proceed. This can be a base or a lipase enzyme. In the currently accepted mechanism of the base‐catalysed interesterification reaction, two anionic intermediates are involved:
openaire   +1 more source

Restructuring butterfat through blending and chemical interesterification. 3. Rheology

Journal of the American Oil Chemists' Society, 1996
AbstractInteresterified and noninteresterified butterfat‐canola oil blends, ranging from 100% butterfat to 60∶40 butterfat‐canola oil (w/w) in 10% increments, were evaluated for hardness index (HI), dropping point, viscosity, and viscoelastic properties at small deformation.
Dérick Rousseau   +2 more
openaire   +1 more source

Chemical and enzymatic interesterification of a beef tallow and rapeseed oil equal‐weight blend

European Journal of Lipid Science and Technology, 2004
AbstractA mixture of beef tallow and rapeseed oil (1:1, wt/wt) was interesterified using sodium methoxide or immobilized lipases from Rhizomucor miehei (Lipozyme IM) and Candida antarctica (Novozym 435) as catalysts. Chemical interesterifications were carried out at 60 and 90 °C for 0.5 and 1.5 h using 0.4, 0.6 and 1.0 wt‐% CH3ONa.
Bolesław Kowalski   +3 more
openaire   +1 more source

Restructuring butterfat through blending and chemical interesterification. 2. Microstructure and polymorphism

Journal of the American Oil Chemists' Society, 1996
AbstractBlending of butterfat with canola oil and subsequent chemical interesterification modified the crystal morphology and X‐ray diffraction patterns of butterfat, 90∶10 (w/w), and 80∶20 (w/w) blends of butterfat‐canola oil. The morphology of 50∶50 (w/w) was also greatly influenced by interesterification.Polarized light microscopy revealed that ...
Dérick Rousseau   +2 more
openaire   +1 more source

Chemical and enzymatic interesterification of tristearin/triolein‐rich blends: Microstructure and polymorphism

European Journal of Lipid Science and Technology, 2008
AbstractMixtures of fully hydrogenated canola oil and high‐oleic sunflower oil were interesterified chemically and enzymatically with sodium methoxide and Candida antarctica lipase, respectively. Polymorphic behavior and crystal morphology of the10–100% blends before and after interesterification were studied using powder X‐ray diffraction spectroscopy
Latifeh Ahmadi   +2 more
openaire   +1 more source

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