Results 71 to 80 of about 10,800 (238)

Catalytic Asymmetric Transfer Hydrogenation of Imines: Recent Advances [PDF]

open access: yes, 2015
In this review article recent developments in the asymmetric transfer hydrogenation of imines from 2008 up to today are presented. The main methodology involves either metal-catalyzed procedures in the presence of a chiral ligand or organocatalyzed ...
Foubelo, Francisco, Yus, Miguel
core   +2 more sources

An ATP‐Mediated Antibiotic β‐Peptide Nanofiber That Kills Multidrug‐Resistant Bacteria via a Multistage Mechanism

open access: yesAdvanced Science, EarlyView.
The 3K‐AP system forms infinite supramolecular fibrils that undergo controlled degradation into shorter fragments upon enzymatic hydrolysis. Multitechnique imaging reveals a stepwise bacteriolytic mechanism involving bacterial entrapment, disassembly into lethal constructs, and associated extracellular vesicle release, highlighting the dynamic ...
Sohini Chakraborty   +21 more
wiley   +1 more source

Enantioselective Prins cyclization: BINOL-derived phosphoric acid and CuCl synergistic catalysis.

open access: yes, 2014
International audienceThe first catalytic enantioselective Prins cyclization is disclosed. The reaction is catalyzed by the combination of a chiral BINOL-derived bis-phosphoric acid and CuCl.
Lalli, Claudia, Van De Weghe, Pierre
core   +3 more sources

Recent advances in the catalytic asymmetric 1,3-dipolar cycloaddition of azomethine ylides [PDF]

open access: yes, 2014
Catalytic asymmetric 1,3-dipolar cycloadditions of azomethine ylides have turned out to be one of the most efficient methods for the preparation of enantioenriched pyrrolidines.
Adrio, Javier, Carretero, Juan C.
core   +2 more sources

Spatial Control Over Tether‐Tunable Coordination on Palladium for Divergent Synthesis of Bicyclo[n.1.0]alkanes via Oxidative Cyclopropanation of Enynes

open access: yesAdvanced Science, EarlyView.
We have developed a Pd‐catalyzed oxidative cyclopropanation of 1,n‐enynes employing cyclic diacyl peroxides as bifunctional reagents that serve as both tether‐tunable oxidants and spatially controlled dicarboxylate anions. ABSTRACT Bicyclo[n.1.0]alkanes are highly valuable scaffolds in drug discovery and synthetic chemistry.
Ting Yuan, Lei Shi
wiley   +1 more source

A combined continuous microflow photochemistry and asymmetric organocatalysis approach for the enantioselective synthesis of tetrahydroquinolines

open access: yesBeilstein Journal of Organic Chemistry, 2013
A continuous-flow asymmetric organocatalytic photocyclization–transfer hydrogenation cascade reaction has been developed. The new protocol allows the synthesis of tetrahydroquinolines from readily available 2-aminochalcones using a combination of ...
Erli Sugiono, Magnus Rueping
doaj   +1 more source

Development and application of asymmetric organocatalytic Mukaiyama and vinylogous Mukaiyama-type reactions [PDF]

open access: yes, 2018
This is the peer reviewed version of the following article: "Development and application of asymmetric organocatalytic Mukaiyama and vinylogous Mukaiyama-type reactions", Chemistry - A European Journal 24.43 (2018): 10906-10933 ,which has been published ...
Alemán, José   +6 more
core   +1 more source

Bandgap‐Dependent Doping of Semiconducting Carbon Nanotube Networks by Proton‐Coupled Electron Transfer for Stable Thermoelectrics

open access: yesAdvanced Electronic Materials, EarlyView.
Proton‐coupled electron transfer doping with benzoquinone is applied to p‐dope dense films of semiconducting single‐walled carbon nanotubes. The doping efficiency depends on the pH of the doping solution and the bandgap of the nanotubes. The highest conductivities and power factors are achieved for small‐bandgap nanotubes, remaining stable for over 120
Angus Hawkey   +5 more
wiley   +1 more source

“Dial Up and Lock In”: Asymmetric organo-Brønsted acid catalysis incorporating stable isotopes [PDF]

open access: yes, 2016
An operationally simple organo-Brønsted-acid-catalyzed asymmetric and regioselective “dial up and lock in” of one or more stable isotopes into organic compounds is unknown.
Bachera, Dominika U.   +7 more
core   +1 more source

Chiral Bronsted Acid-Catalyzed Enantioselective alpha-Amidoalkylation Reactions: A Joint Experimental and Predictive Study, [PDF]

open access: yes, 2016
Enamides with a free NH group have been evaluated as nucleophiles in chiral Bronsted acid-catalyzed enantioselective alpha-amidoalkylation reactions of bicyclic hydroxylactams for the generation of quaternary stereocenters.
Aranzamendi Uruburu, Eider   +4 more
core   +3 more sources

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