Results 121 to 130 of about 14,574 (240)

Diastereoselective synthesis of spiro[2.<i>n</i>]alkanes <i>via</i> intramolecular carbolithiation. [PDF]

Chem Sci
Teschers CS, Barra C, Scherübl M, Zuber J, Marek I.   +4 more
europepmc   +1 more source

The tryptophan prenyltransferase ComQ from Bacillus subtilis 168 can prenylate daptomycin at Trp1

The FEBS Journal, EarlyView.
ComQ168 from Bacillus subtilis 168 catalyzes C‐terminal tryptophan farnesylation of ComX to generate a competence‐inducing pheromone. Recombinant ComQ168 also modifies cyclic peptides, including Daptomycin, likely at the N‐terminal tryptophan. Structural modeling highlights a C‐terminal binding region, supporting substrate promiscuity and establishing ...
Yanli Xu, Maximilian J. L. J. Fürst, Oscar P. Kuipers   +2 more
wiley   +1 more source

Stereocontrolled entry to borylated piperidines <i>via</i> stepwise dearomative carboboration of pyridines. [PDF]

Chem Sci
Khalse LD, DeSnoo W, Lou YP, Tantillo DJ, Nairoukh Z.   +4 more
europepmc   +1 more source

Supramolecular Behaviour of Heterochiral Dipeptides With Ile

Journal of Peptide Science, Volume 32, Issue 10, October 2026.
This study describes the supramolecular behaviour and gelation of heterochiral, aliphatic dipeptides d‐Ile‐l‐Xaa (Xaa = Ala, Val, Leu or Ile) in various solvents and buffered water at neutral pH. Metastable gels rapidly crystallised. X‐ray diffraction analysis was conducted to unveil the dipeptides' packing modes in amphipathic layers.
Erica Scarel, Paola Alletto, Simone Adorinni, Fabio Fazio, Giovanni Pierri, Consiglia Tedesco, Silvia Marchesan   +6 more
wiley   +1 more source

Chirality Transfer and Thiazolidine or Thiazine Formation in Reactions of L and D Enantiomers of β- or γ-Sulfhydryl Amino Acids with Imidazole Carboxaldehydes and Nickel(II). [PDF]

Molecules
Brewer CT, Brewer G, Butcher RJ.
europepmc   +1 more source

Photocatalytic Synthesis and Palladium‐Catalyzed Functionalizations of Hydrofluoroolefin (HFO‐1234ze)‐Based Vinyl Iodides

Advanced Synthesis &Catalysis, Volume 368, Issue 18, 19 September 2026.
An inexpensive industrial refrigerant, HFO‐1234ze, is transformed into a versatile fluoroalkyl building block via a scalable, solvent‐free protocol. Utilizing the metal‐free photocatalyst 4CzIPN, efficient visible‐light‐induced radical addition to alkynes reveals distinct, substrate‐dependent stereoselectivities.
Bálint Varga, Péter Szalai, Klára Aradi, Bálint Nagy, András Kotschy, Zoltán Novák   +5 more
wiley   +1 more source

Modular Synthesis of a Lignin Oligomer Library. [PDF]

ChemSusChem
Abdelraheem E, Ewing TA, van Erven G, Miloserdov FM.   +3 more
europepmc   +1 more source

Isochromane-3,4-diones in Direct Vinylogous Aldol Reaction: Scope and Limitations. [PDF]

Molecules
Arshad SG, Mousavi MS, Tedesco C, Massa A.   +3 more
europepmc   +1 more source

Unified Synthesis of Unconventional α‐Polyhalogenated Amines Through Hydroaminoalkylation

Angewandte Chemie International Edition, Volume 65, Issue 38, 14 September 2026.
A unified, redox‐neutral method that transforms alkenes and alkynes into α‐polyhalomethyl amines using stable hemiaminal reagents is reported. This approach enables access to CF3, CF2H, CF2Cl, and CFClH motifs, expanding halogenated amine space with broad substrate scope, functional group tolerance, and applicability to late‐stage modification of drug ...
Angela K. Hofmeister, Giulia Iannelli, Péter Angyal, Augustin Malandain, Daniel Kaiser, Boris Maryasin, Hanspeter Kählig, Matteo Barel, Gaia Novarino, Nuno Maulide   +9 more
wiley   +1 more source

Clarifying Stereochemical Outcomes in Radical-Initiated Vinyl Cyclopropane Cycloadditions within the Beckwith-Houk Framework. [PDF]

Org Chem Front
Agee CO, Vyas H, Portela BS, Bains AK, Song KL, Médebielle M, Paton RS, Sharma A, Merad J, Miyake GM, Williamson RT.   +10 more
europepmc   +1 more source