Results 51 to 60 of about 23,776 (268)
Synthesis of (3R,5R)-harzialactone A and its (3R,5S)-isomer
Beilstein Journal of Organic Chemistry, 2010 The total synthesis of (3R,5R)-harzialactone A (1) and its (3R,5S)-isomer (2) is described. Epoxide opening with thioacetal and diastereoselective reductions are used as key reactions.
Gowravaram Sabitha +3 more
doaj +1 more source
Diastereoselective Hydroboration of Isopropenylcyclopropanes
, 2016 Diastereoselective Hydroboration of ...
Céline Hamel (3047295) +3 more
core +1 more source
SynOpen, 2022 A concise and diastereoselective total synthesis of tetraketide and euscapholide is described in ten steps in 10.6% overall yield from acetaldehyde and (S)-pent-4-ene-1,2-diol.
Dhanraj O. Biradar +2 more
doaj +1 more source
Nature Communications, 2020 Enzyme-catalyzed desymmetric glycosylations are often found in nature, however the corresponding chemical methods are lacking. Here, the authors report a highly diastereoselective desymmetric 1,2-cis-glycosylation of meso-diols found in myo-inositol 1,3 ...
Masamichi Tanaka +7 more
doaj +1 more source
Recent developments in the asymmetric Reformatsky-type reaction
Beilstein Journal of Organic Chemistry, 2018 This review collects the most important developments in asymmetric Reformatsky-type reactions published since the beginning of 2013, including both diastereoselective methodologies based on the use of chiral substrates and enantioselective catalytic ...
Hélène Pellissier
doaj +1 more source
Catalytic Diastereoselective Petasis Reactions [PDF]
Angewandte Chemie, 2011 Multicomponent Petasis reactions: the first diastereoselective Petasis reaction catalyzed by chiral biphenols that enables the synthesis of syn and anti β-amino alcohols in pure form has been developed. The reaction exploits a multicomponent approach that involves boronates, α-hydroxy aldehydes, and amines.
Giovanni, Muncipinto +3 more
openaire +2 more sources
Synthesis and properties of new chiral heterocyclic peptide mimetics
, 2008 The synthesis of tetrahydrofuran C(alpha)-tetrasubstituted amino acids (TAAs) and their effect on the conformation in small peptides are reported. The synthesis starts from the protein amino acid methionine, which is protected at the C and N terminus and
Maity, Prantik
core +1 more source
Beilstein Journal of Organic Chemistry, 2019 A diastereoselective approach to axially chiral imidazopyridine-containing biaryls has been developed. The reactions proceed through a radical cyclization cascade to construct the biaryls with good to excellent central-to-axial chirality transfer.
Hong Yan +4 more
doaj +1 more source
Stereoselective gridization and polygridization with centrosymmetric molecular packing
Nature Communications, 2020 Gridarenes with well-defined edges and vertices represent versatile nanoscale building blocks for installating frameworks but suffer from lack of stereoselective control during their synthesis. Here, the authors report a diastereoselective gridization of
Dongqing Lin +11 more
doaj +1 more source
Diastereoselective Synthesis of Trisubstituted Cyclopropylstannanes
, 2016 Diastereoselective Synthesis of Trisubstituted ...
Seok-In Kim (3046293) +2 more
core +1 more source