Phosphosulfonic acid, an efficient solid acid catalyst for the one-pot preparation of 14-aryl-14H-dibenzo[a,j]xanthenes and 1,8-dioxo-octahydro-xanthenes under solvent-free conditions [PDF]
An expeditious procedure for the synthesis of 14- aryl-14H-dibenzo[a,j]xanthenes and 1,8-dioxo-octahydro-xanthenes through one-pot pseudo three component condensation of β-naphthol or dimedone with various aryl aldehydes is described.
Kiasat Reza Ali +2 more
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In the acridinedione moiety of the title compound, C32H37NO4, the central dihydropyridine ring adopts a flattened-boat conformation, with the N atom and the methine C atom displaced from the mean plane of the other four atoms by 0.0513 (14) and 0.1828 ...
N. Sureshbabu, V. Sughanya
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A convenient and facile CuCl2·2H2O catalyzed one-pot synthetic strategy was designed for the conversion of readily available dimedone into highly functionalized N-arylhydrazinecarbothioamide based indazole derivatives. The product yields were found to be
Rafaila Rafique +5 more
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Can dimedone be used to study selenoproteins? An investigation into the reactivity of dimedone toward oxidized forms of selenocysteine [PDF]
AbstractDimedone is a widely used reagent to assess the redox state of cysteine‐containing proteins as it will alkylate sulfenic acid residues, but not sulfinic acid residues. While it has been reported that dimedone can label selenenic acid residues in selenoproteins, we investigated the stability, and reversibility of this label in a model peptide ...
N Connor, Payne +3 more
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Synthesis of xanthene derivatives based on α, αâ²-bis (substituted-benzylidene) cycloalkanones using tangstophosphoric acid under solvent-free conditions [PDF]
Tangstophosphoric acid (H3PW12O40) as an acidic catalyst has been used for facile synthesis of xanthene derivatives by the reaction of α,αâ²-bis (substituted-benzylidene) cycloalkanones and dimedone in solvent-free conditions.
الهام تبریزیان +1 more
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The use of tristimulus colorimetry for the determination of hydrogen cyanide in air by a modified König method [PDF]
A simple visual and tristimulus colorimetric method (three-dimensional system CIE-L*a*b*) for the determination of trace amounts of hydrogen cyanide in air has been developed.
VLADIMÍR PITSCHMANN +3 more
doaj
Multicomponent synthesis of novel azo-linked 9-Aryl-1H-xanthene-1,8(2H)-diones using ionic liquid [BDBDMIm]HSO4 [PDF]
The synthesis of ten novel azo dyes derived from 9-Aryl-1H-xanthene-1,8(2H)-dione derivatives from one equivalent of azo-linked salicylaldehydes and two equivalent of dimedone in the presence of 3,3'-(butane-1,4-diyl)bis(1,2-dimethyl-1H-imidazol-3-ium ...
mohammad nikpassand, leila Zare Fekri
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2,2′-[(4-Butoxyphenyl)methylene]bis(3-hydroxy-5,5-dimethylcyclohex-2-en-1-one)
In the title compound, C27H36O5, the dihedral angles between the planes of the benzene ring and the cyclohexenone rings are 60.87 (10) and 65.04 (10)°, while the dihedral angle between the mean planes of the two cyclohexenone rings is 39.33 (10)°.
N. Suresh Babu +4 more
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Microwave-assisted Synthesis of Acridine-1,8(2H,5H)-diones via a One-pot, Three Component Reaction [PDF]
A new and improved protocol for the synthesis, in good to excellent yields, of acridine-1,8(2H,5H)-diones is described, involving a one-pot, three component reaction of dimedone, arylglyoxals, and ammonium acetate in water under microwave irradiation.
Ahmad Poursattar Marjani +3 more
doaj
Hyperproduction of aldehydes – carbonyl stress, is resulted from lipid peroxidation and/or glycosylation. We suggest that endogenous aldehydes can affect some oxidative stress parameters development. The aim of this research is to distinguish the role of
K. O. Tokarchuk +3 more
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