Results 161 to 170 of about 83,738 (273)

Isothiourea‐Catalyzed Functionalization of Pyrrolyl‐ and Indolylacetic Acid: Enantioselective Synthesis of Dihydropyridinones and One‐pot Synthesis of Pyridinones [PDF]

open access: hybrid, 2020
Shuyue Zhang   +6 more
openalex   +1 more source

Synthesis of α‐Pentafluorosulfanylated‐β2,3‐Amino Esters

open access: yesChemistryEurope, EarlyView.
De novo α‐SF5‐β2,3‐amino esters are now accessible through a straightforward aza‐Michael reaction using a series of newly developed (E)‐α‐SF5‐α,β‐unsaturated esters. Two new, highly functionalized, contiguous tertiary stereocenters are formed with diastereodivergence governed by the choice of solvent and/or base.
Thi Mo Nguyen   +5 more
wiley   +1 more source

Properties of epoxide hydrolase from the yeast Rhodotorula glutinis [PDF]

open access: yes
Epoxide hydrolases are ubiquitous enzymes that can be found in nearly all living organisms. Some of the enzymes play an important role in detoxifying xenobiotic and metabolic compounds.
Ariës-Kronenburg, N.A.E.
core   +1 more source

Imidazoline‐Proline and Imidazoline‐Prolinate Ligands for Copper‐Catalyzed Asymmetric Exo‐Selective [3 + 2] Cycloaddition of Iminoesters with Nitroalkenes

open access: yesChemistryEurope, EarlyView.
From a modular synthesis of nonphosphine chiral nitrogen‐based chiral imidazoline–amino acid ligands, two new chiral imidazoline–proline‐copper catalysts are developed for targeting exo‐selective [3 + 2] cycloaddition reaction. Density functional theory studies rationalize the observed stereoselectivity and the distinct chiral pockets of the two ...
Yan Yu   +4 more
wiley   +1 more source

Catalytic enantioselective synthesis of alkylidenecyclopropanes. [PDF]

open access: yesNature
Golec JC   +6 more
europepmc   +1 more source

Well‐Defined Rhodium and Iridium Complexes Containing Chiral Cyclic(Alkyl)(Amino)Carbenes for Asymmetric Hydrogenation

open access: yesChemistryEurope, EarlyView.
A set of fourteen well‐defined rhodium and iridium complexes containing various enantiopure cyclic(alkyl)(amino)carbene (ChiCAAC) ligands (>96% ee to > 99.5% ee) has been synthesized and fully characterized. While no enantioselectivity is observed with chiral Rh‐CAAC, the Ir‐CAAC counterparts demonstrated good performances in the asymmetric ...
Fanny Morvan   +7 more
wiley   +1 more source

Enantioselective Synthesis of Oasomycin A, Part I: Synthesis of the C1–C12 and C13–C28 Subunits [PDF]

open access: bronze, 2006
David A. Evans   +6 more
openalex   +1 more source

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