Low-Cost Mechanism-Informed Features Enable Transferable Enantioselectivity Predictions from Sparse Data [PDF]
Simone Gallarati +3 more
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A photoinduced, regio‐ and chemoselective γ‐alkylation of 2‐silyloxyfurans with a‐bromoketones was achieved by exploiting a photoredox catalytic process promoted by blue light. This approach provides practical and efficient access to chiral, ε‐ketobutenolides, in one step and high yields.
Debora Guazzetti +9 more
wiley +1 more source
Lessons in Strain and Stability: Enantioselective Synthesis of (+)‐[5]‐Ladderanoic Acid
Erin N. Hancock +3 more
openalex +2 more sources
Discovery of Inhibitors of the Wnt and Hedgehog Signaling Pathways through the Catalytic Enantioselective Synthesis of an Iridoid‐Inspired Compound Collection [PDF]
Hiroshi Takayama +7 more
openalex +1 more source
Catalytic Amyloids: Turning Fibrils Into Biocatalysts
Amyloids, traditionally associated with diseases, have emerged as versatile catalytic scaffolds. From natural amyloid sequences to bioinspired and de novo designs, we highlight strategies to construct catalytic active sites and anchor enzymes onto fibrils, creating versatile nanomaterials with tunable activities. ABSTRACT Amyloids have been regarded as
Alessandra Esposito +3 more
wiley +1 more source
Asymmetric Carbonium Ion Catalysis: The Intramolecular Hydroalkoxylation of Cyclopropanes. [PDF]
Shi F +6 more
europepmc +1 more source
Enantioselective Total Synthesis of Tricyclic Myrmicarin Alkaloids
Mohammad Movassaghi, Alison E. Ondrus
openalex +1 more source
Enantioselective Metallophosphite-Catalyzed C-Acylation of Nitrones
Mary Robert Garrett +2 more
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Iridium‐Catalyzed Regio‐ and Enantioselective Allylic Substitution of Silyl Dienolates Derived from Dioxinones [PDF]
Ming Chen, John F. Hartwig
openalex +1 more source
We report the synthesis bis(arylethynyl)naphtho‐ and anthraquinones via Rh(I)‐catalyzed [2 + 2 + 2] cycloaddition reactions. The substrate scope of both quinones and linked bis‐diynes was explored. Microwave irradiation remarkably enhanced yields.
Luana A. Machado +16 more
wiley +1 more source

