Results 231 to 240 of about 149,811 (326)

Ferrocenyl chiral bisphosphorus ligands for highly enantioselective asymmetric hydrogenation via noncovalent ion pair interaction

, 2016
Caiyou Chen, Heng Wang, Zhefan Zhang, Shicheng Jin, Songwei Wen, Jianjian Ji, Lung Wa Chung, Xiu‐Qin Dong, Xumu Zhang   +8 more
openalex   +2 more sources

Catalytic Asymmetric 1,2-Migration/Allylation of Alkynyl Boronate Complexes: A Modular Route to Enantioenriched Skipped 1,4-Dienes. [PDF]

J Am Chem Soc
Wei L, Guo Z, Tyler JL, Aggarwal VK.
europepmc   +1 more source

Deciphering Asymmetric Induction in Photoredox Catalysis by Chiral Counteranions. [PDF]

ACS Catal
Baldinelli L, Lerda S, Kayal R, Neese F, De Angelis F, Bistoni G.   +5 more
europepmc   +1 more source

On the Origin of Substrate Specificity of Enzymes from the Amidohydrolase Superfamily

Angewandte Chemie International Edition, Volume 65, Issue 4, 22 January 2026.
Comprehensive analyses of two enzyme classes from the amidohydrolase superfamily (AHS) revealed that catalysis proceeds either via 1,4 or 1,6 nucleophilic conjugate addition and that this property defines substrate specificity. Moreover, although all substrates and products are entirely achiral, this mechanistic difference results in an inverted ...
Lukas Drexler, Torben F. Fürtges, Till Rudack, Reinhard Sterner   +3 more
wiley   +1 more source

Cu-catalyzed enantioconvergent oxygen-centered radical cyclization. [PDF]

Chem Sci
Li ZY, Huang CD, Guan CY, Guo HM, Liu LM, Xiao X, Gao B, Ni SF, Mei GJ.   +8 more
europepmc   +1 more source

Enantioselective Syntheses of Secondary Alkylboronates via Asymmetric Regioselective Reduction of 1,3‐Dienylboronates

Angewandte Chemie, Volume 138, Issue 3, 16 January 2026.
We report herein the development of catalytic asymmetric synthesis of secondary alkyl boronates. Under the optimal conditions, Cu‐catalyzed semi‐reduction of 1‐alkyl‐ or 1,3‐dialkyl‐substituted 1‐boryl‐1,3‐butadienes forms secondary alkyl boronates with excellent regioselectivities and enantioselectivities.
Wen‐Bin Cao, Lingfei Hu, Jiaming Liu, George Chen, Gang Lu, Ming Chen   +5 more
wiley   +2 more sources

Influence of ionic liquids on enzymatic asymmetric carboligations. [PDF]

Comput Struct Biotechnol J
Gerhards T, Harrar TE, Klein AS, Lieres EV, Paul CE, Lavandera I, Gotor-Fernández V, Pietruszka J, Pohl M, Gohlke H, Rother D.   +10 more
europepmc   +1 more source

Asymmetric Catalytic Hydrogenation toward a Value‐Added Chiral Building Block: Optically Active γ‐Butyrolactone Scaffold from Renewable and Synthetic Derived Feedstocks

European Journal of Organic Chemistry, Volume 29, Issue 3, January 22, 2026.
This brief compendium summarizes the most successful asymmetric hydrogenation strategies for the preparation of chiral monocyclic γ‐lactone derivatives from keto acids and keto esters, with emphasis on their relevance for large‐scale production and high enatioselectivities. This article provides a brief compendium on the production of chiral monocyclic
Marta Feliz, Maria J. Sabater
wiley   +1 more source

Solvation Entropy as a Lever for Steering the Macroscopic Properties of a Functional Supramolecular Helical Polymer

Angewandte Chemie, Volume 138, Issue 3, 16 January 2026.
The structural transition between the two fully‐characterized states of a supramolecular helical hydrogen‐bonded polymer (represented as blue and light pink stacks) can be predictably varied over 85 K by changing the nature and amount of cosolvent; entropy of solvation (schematized as solvents of different sizes) is the main lever to tune the ...
Huanjun Kong, Mayte A. Martínez‐Aguirre, Yan Li, Tomoyuki Ikai, Eiji Yashima, Gangamallaiah Velpula, Steven De Feyter, Pierre‐Antoine Albouy, Komivi Akpo, Patrick Brocorens, Roberto Lazzaroni, Laurent Bouteiller, Matthieu Raynal   +12 more
wiley   +2 more sources