Results 41 to 50 of about 149,811 (326)

Homochiral Metal-Organic Framework Based Mixed Matrix Membrane for Chiral Resolution

open access: yesMembranes, 2022
Efficient separation of enantiomers is critical in the chemical, pharmaceutical, and food industries. However, conventional separation methods, such as chromatography, crystallization, and enzymatic kinetic resolution, require high energy costs and ...
Hwa-Jin Choi, Dong-Yeun Koh
doaj   +1 more source

Electrosynthesis of Bioactive Chemicals, From Ions to Pharmaceuticals

open access: yesAdvanced Functional Materials, EarlyView.
This review discusses recent advances in electrosynthesis for biomedical and pharmaceutical applications. It covers key electrochemical materials enabling precise delivery of ions and small molecules for cellular modulation and disease treatment, alongside catalytic systems for pharmaceutical synthesis.
Gwangbin Lee   +4 more
wiley   +1 more source

Synthetic Cathinones: Recent Developments, Enantioselectivity Studies and Enantioseparation Methods

open access: yesMolecules, 2022
New psychoactive substances represent a public health threat since they are not controlled by international conventions, are easily accessible online and are sold as a legal alternative to illicit drugs. Among them, synthetic cathinones are widely abused
Ana Sofia Almeida   +4 more
doaj   +1 more source

Enantioselective Growth of Chiral Serine‐Induced β‐Ag2Se Crystals from an Organoselenium Compound

open access: yesAdvanced Functional Materials, EarlyView.
Chiral amino acids direct the enantioselective crystallization of β‐Ag2Se nanocrystals from an organoselenium precursor. L‐ and D‐serine induce distinct morphologies and opposite homochiral adsorption preferences, transferring molecular handedness into the inorganic lattice.
Matan Oliel   +5 more
wiley   +1 more source

Enantioselective Extraction of Ofloxacin Enantiomers Using Ester Alcohol L-Tartarate as Chiral Selector [PDF]

open access: yesIranian Journal of Chemistry & Chemical Engineering, 2009
The distribution behavior of ofloxacin enantiomers was examined in the aqueous and organic solvent of a two-phase system containing chiral selector L-tartarate.
Xiaoqing Chen Feipeng Jiao, Xinyu Jiang
doaj  

Carbohydrate-Based Azacrown Ethers in Asymmetric Syntheses

open access: yesChemistry, 2021
Carbohydrate-based crown ethers represent a special group of chiral phase transfer catalysts. Several derivatives of these macrocycles have been synthesized in our research group.
István Orbán, Péter Bakó, Zsolt Rapi
doaj   +1 more source

Chiral SURMOFs for Vibrational Circular Dichroism: Multiscale Modeling and Experimental Insights

open access: yesAdvanced Functional Materials, EarlyView.
The use of solid‐state vibrational circular dichroism (VCD) for MOFs is still somewhat unexplored, and in this work, it is shown that chiral surface‐anchored MOFs (SURMOFs) grown on CaF2 provide an excellent platform for VCD. Experimental results are validated through multiscale modeling, showing strong agreement across multiple spectroscopic ...
Ana C. Fingolo   +9 more
wiley   +1 more source

Oligomerization of optically active N-(4-hydroxyphenyl)mandelamide in the presence of β-cyclodextrin and the minor role of chirality

open access: yesBeilstein Journal of Organic Chemistry, 2014
The oxidative oligomerization of a chiral mandelamide derivative (N-(4-hydroxyphenyl)mandelamide, 1) was performed in the presence of horseradish peroxidase, laccase and N,N'-bis(salicylidene)ethylenediamine-iron(II) to obtain chiral oligophenols 2.
Helmut Ritter   +2 more
doaj   +1 more source

Research Progress on the Selectivity and Biomagnification of Chiral Hexabromocyclododecanes Pollutants in Food Chain Transfer

open access: yesYankuang ceshi, 2016
Hexabromocyclododecanes (HBCDs) are globally produced brominated flame retardant (BFR) and are used primarily as an additive FR in thermal insulation building materials, upholstery textiles, and electronics.
TIAN Qin   +5 more
doaj   +1 more source

Semi-Preparative Separation, Absolute Configuration, Stereochemical Stability and Effects on Human Neuronal Cells of MDPV Enantiomers

open access: yesMolecules, 2023
Synthetic cathinones, such as 3,4-methylenedioxypyrovalerone (MDPV), are widely abused due to their psychostimulant effects. As they are chiral molecules, studies of their stereochemical stability (racemization can occur in certain temperatures and ...
Ana Sofia Almeida   +5 more
doaj   +1 more source

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