Results 61 to 70 of about 39,817 (294)

ChemInform Abstract: Enantioselective Tsuji Allylations [PDF]

open access: yesChemInform, 2007
AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
Mohr, Justin T., Stoltz, Brian M.
openaire   +6 more sources

Quantitative Prediction on the Enantioselectivity of Multiple Chiral Iodoarene Scaffolds Based on Whole Geometry [PDF]

open access: yesarXiv, 2021
The mechanistic underpinnings of asymmetric catalysis at atomic levels provide shortcuts for developing the potential value of chiral catalysts beyond the current state-of-the-art. In the enantioselective redox transformations, the present intuition-driven studies require a systematic approach to support their intuitive idea.
arxiv  

Evolving P450pyr Monooxygenase for Regio- and Stereoselective Hydroxylations

open access: yesCHIMIA, 2015
P450pyr monooxygenase from Sphingomonas sp. HXN-200 catalysed the regio- and stereoselective hydroxylation at a non-activated carbon atom, a useful but challenging reaction in classic chemistry, with unique substrate specificity for a number of ...
Yi Yang, Zhi Li
doaj   +1 more source

Homochiral Metal-Organic Framework Based Mixed Matrix Membrane for Chiral Resolution

open access: yesMembranes, 2022
Efficient separation of enantiomers is critical in the chemical, pharmaceutical, and food industries. However, conventional separation methods, such as chromatography, crystallization, and enzymatic kinetic resolution, require high energy costs and ...
Hwa-Jin Choi, Dong-Yeun Koh
doaj   +1 more source

Non-linear Effects in Asymmetric Catalysis: Whys and Wherefores [PDF]

open access: yes, 2012
It is argued that the titled non-linear effects (NLE) may arise whenever the order of the reaction in the chiral catalyst in greater than 1. In a fundamental departure from previous approaches, this is mathematically elaborated for the second order case.
Sosale Chandrasekhar
core   +2 more sources

Synthetic Cathinones: Recent Developments, Enantioselectivity Studies and Enantioseparation Methods

open access: yesMolecules, 2022
New psychoactive substances represent a public health threat since they are not controlled by international conventions, are easily accessible online and are sold as a legal alternative to illicit drugs. Among them, synthetic cathinones are widely abused
Ana Sofia Almeida   +4 more
doaj   +1 more source

State‐of‐the‐Art, Insights, and Perspectives for MOFs‐Nanocomposites and MOF‐Derived (Nano)Materials

open access: yesAdvanced Materials, EarlyView.
Different approaches to MOF‐NP composite formation, such as ship‐in‐a‐bottle, bottle‐around‐the‐ship and in situ one‐step synthesis, are used. Owing to synergistic effects, the advantageous features of the components of the composites are beneficially combined, and their individual drawbacks are mitigated.
Stefanos Mourdikoudis   +6 more
wiley   +1 more source

Enhanced stereodivergent evolution of carboxylesterase for efficient kinetic resolution of near-symmetric esters through machine learning

open access: yesNature Communications
Carboxylesterases serve as potent biocatalysts in the enantioselective synthesis of chiral carboxylic acids and esters. However, naturally occurring carboxylesterases exhibit limited enantioselectivity, particularly toward ethyl 3-cyclohexene-1 ...
Zhe Dou   +8 more
doaj   +1 more source

Bioresolution Production of (2R,3S)-Ethyl-3-phenylglycidate for Chemoenzymatic Synthesis of the Taxol C-13 Side Chain by Galactomyces geotrichum ZJUTZQ200, a New Epoxide-Hydrolase-Producing Strain

open access: yesMolecules, 2014
A newly isolated Galactomyces geotrichum ZJUTZQ200 strain containing an epoxide hydrolase was used to resolve racemic ethyl 3-phenylglycidate (rac-EPG) for producing (2R,3S)-ethyl-3-phenylglycidate ((2R,3S)-EPG). G.
Chun Wei   +3 more
doaj   +1 more source

Carbohydrate-Based Azacrown Ethers in Asymmetric Syntheses

open access: yesChemistry, 2021
Carbohydrate-based crown ethers represent a special group of chiral phase transfer catalysts. Several derivatives of these macrocycles have been synthesized in our research group.
István Orbán, Péter Bakó, Zsolt Rapi
doaj   +1 more source

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