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Synthesis of enniatin B

Experientia, 1963
Die Struktur von Enniatin B, eines antimikrobiellen Wirkstoffes aus Fusarienstammen (ETH, Zurich), wird durch Synthese als die eines Cyclohexapeptolids bewiesen (vgl. X).
Pl. A. Plattner   +4 more
openaire   +1 more source

Comparative Oral Bioavailability, Toxicokinetics, and Biotransformation of Enniatin B1 and Enniatin B in Broiler Chickens

Journal of Agricultural and Food Chemistry, 2016
A toxicokinetic study of the Fusarium mycotoxins enniatin B1 (ENN B1) and enniatin B (ENN B) was performed in broiler chickens. Each animal received ENN B1 or B orally via an intracrop bolus and intravenously at a dose of 0.2 mg/kg body weight. Both enniatins were poorly absorbed after oral administration, with absolute oral bioavailabilities of 0.05 ...
Sophie, Fraeyman   +5 more
openaire   +2 more sources

The structure of enniatins and related antibiotics

Tetrahedron, 1963
Abstract The synthesis of cyclotetradepsipeptides the structure of which has previously been assigned to antibiotics of the enniatin group is described. It was found that these antibiotics cannot be represented by the formulas (I)–(VI).
M M, Shemyakin   +3 more
openaire   +2 more sources

Über die Chemie des Enniatins

Experientia, 1947
Judging by the physical and chemical properties and “bacterial spectra”, the antibiotic substance, Enniatin, previously isolated from a strain ofFusarium by the authors, appears to be identical with that which was recently reported byCook et al. derived from another strain and designated by them as Lateritiin-I, although the reported empirical formulae
Pl. A. Plattner, U. Nager
openaire   +1 more source

Investigation of the electrophysiological properties of enniatins

Archives of Biochemistry and Biophysics, 2004
Enniatins are cyclohexadepsipeptides produced by various species of the genus Fusarium, and are known to have ionophoric, antibiotic, and in vitro hypolipidaemic properties. With the patch clamp technique in the inside-out mode it could be shown that enniatin easily incorporates into the cell membrane in which it forms cation-selective pores.
Kamyar, Majid-Reza   +4 more
openaire   +3 more sources

Structural studies on minor enniatins from Fusarium sp. VI 03441: Novel N-methyl-threonine containing enniatins

Toxicon, 2009
A strain of a yet unidentified Fusarium sp. produced in addition to enniatins A1, B and B1 a number of minor enniatins. The strain formed a well supported clade with strains identified as Fusarium acuminatum (Gibberella acuminata) in phylogenetic analyses using the TEF-1alpha gene sequences.
Silvio, Uhlig   +3 more
openaire   +2 more sources

Fate of enniatins and deoxynivalenol during pasta cooking

Food Chemistry, 2016
The fate of deoxynivalenol and enniatins was studied during cooking of commercially available dry pasta in the Netherlands in 2014. Five samples containing relatively high levels of deoxynivalenol and/or enniatins were selected for the cooking experiment.
de Nijs, Monique   +4 more
openaire   +3 more sources

Synthese von Stereoisomeren des Enniatins B

Chemische Berichte, 1968
AbstractAusgehend von der Synthese des Enniatins B wird der Aufbau seiner Stereoisomeren all‐L‐, all‐D‐Enniatin B und des Antipoden (Enantio‐Enniatin B¹) beschrieben.
Günter Losse, Hartmut Raue
openaire   +1 more source

The Crystal Structure of Enniatin B

Helvetica Chimica Acta, 1985
AbstractThe X‐ray crystal structure of enniatin B (trigonal (hexagonal axes), a = 14.626 Å, c = 16.309 Å, space group R3) is described and the conformation compared to results of other investigations.
Christoph Kratky, Max Dobler
openaire   +1 more source

Mechanism of depsipeptide formation catalyzed by enniatin synthetase

Biochemical and Biophysical Research Communications, 1983
Covalently bound intermediates of enniatin B synthesis could be isolated from enniatin synthetase by treatment with performic acid. By comparison with products of mild alkaline cleavage of authentic enniatin B they could be identified as the dipeptide D-2-hydroxyisovaleryl-N-methylvaline and the corresponding tetrapeptide.
R, Zocher, U, Keller, H, Kleinkauf
openaire   +2 more sources

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